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We want to understand whether and to which extent the maximal (Carnot) efficiency for heat engines can be reached at a finite power. To this end we generalize the Carnot cycle so that it is not restricted to slow processes. We show that for…

It is common in many thermodynamic textbooks to illustrate the Carnot theorem through the usage of diverse state equations for gases, paramagnets, and other simple thermodynamic systems. As it is well-known, the universality of the Carnot…

The isotropic Maxwell-Boltzmann (M-B) velocity distribution is the accepted standard for a gas at thermal equilibrium, with the Doppler width considered to deliver a very precise measurement of the temperature. Nevertheless, the physical…

In this work we investigate the dynamical properties of a mixture of mutually interacting spherical molecules of different masses and sizes. From an analysis of the microscopic laws governing the motion of the molecules we derive a set of…

We study the coupled particle and energy transport in a prototype model of interacting one-dimensional system: the disordered hard-point gas, for which numerical data suggest that the thermoelectric figure of merit ZT diverges with the…

We suggest and discuss a simple model of an ideal gas under the piston to gain an insight into the workings of the Jarzynski identity connecting the average exponential of the work over the non-equilibrium trajectories with the equilibrium…

From the thermodynamic equilibrium properties of a two-level system with variable energy-level gap $\Delta$, and a careful distinction between the Gibbs relation $dE = T dS + (E/\Delta) d\Delta$ and the energy balance equation $dE = \delta…

We study the problem of thermoelectricity and propose a simple microscopic mechanism for the increase of thermoelectric efficiency. We consider the cross transport of particles and energy in open classical ergodic billiards. We show that,…

We prove approach to thermal equilibrium for the fully Hamiltonian dynamics of a dynamical Lorentz gas, by which we mean an ensemble of particles moving through a $d$-dimensional array of fixed soft scatterers that each possess an internal…

Recent advances in experimental control of colloidal systems have spurred a revolution in the production of mesoscale thermodynamic devices. Functional "textbook" engines, such as the Stirling and Carnot cycles, have been produced in…

Direct Monte Carlo simulations of the Enskog-Boltzmann equation for a spatially uniform system of smooth inelastic spheres are performed. In order to reach a steady state, the particles are assumed to be under the action of an external…

We consider a statistical mechanics and thermodynamics of a rotating ideal gas of classical relativistic particles with nonzero mass and spin. Applying the Gibbs theory of canonical ensembles for a system rotating with constant angular…

We propose a simple classical dynamical model of a thermoelectric (or thermochemical) heat engine based on a pair of ideal gas containers connected by two unequal scattering channels. The model is solved analytically and it is shown that a…

Carnot's four-part ideal-gas cycle includes both isothermal and adiabatic expansions and compressions. Analyzing this cycle provides the fundamental basis for statistical thermodynamics. We explore the cycle here from a pedagogical view in…

Whereas the original Boltzmann's $H$-theorem applies to elastic collisions, its rigorous generalization to the inelastic case is still lacking. Nonetheless, it has been conjectured in the literature that the relative entropy of the velocity…

There is intense effort into understanding the universal properties of finite-time models of thermal machines---at optimal performance---such as efficiency at maximum power, coefficient of performance at maximum cooling power, and other…

Even though irreversibility is one of the major hallmarks of any real life process, an actual understanding of irreversible processes remains still mostly semiempirical. In this paper we formulate a thermodynamic uncertainty principle for…

We present a simulation scheme for discrete-velocity gases based on {\em local thermodynamic equilibrium}. Exploiting the kinetic nature of discrete-velocity gases, in that context, results in a natural splitting of fluxes, and the…

We study the deterministic dynamics of non-interacting classical gas particles confined to a one-dimensional box as a pedagogical toy model for the relaxation of the Boltzmann distribution towards equilibrium. Hard container walls alone…

We employ the recently developed framework of the energetics of stochastic processes (called `stochastic energetics'), to re-analyze the Carnot cycle in detail, taking account of fluctuations, without taking the thermodynamic limit. We find…