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Graphene, a monolayer of carbon atoms packed into a two-dimensional crystal structure, attracted intense attention owing to its unique structure and optical, electronic properties. Recent advances in chemical vapor deposition (CVD) have led…

材料科学 · 物理学 2020-10-23 Yu-Hao Deng

Growth of epitaxial graphene on the C-face of SiC has been investigated. Using a confinement controlled sublimation (CCS) method, we have achieved well controlled growth and been able to observe propagation of uniform monolayer graphene.…

材料科学 · 物理学 2012-11-29 Rui Zhang , Yunliang Dong , Wenjie Kong , Wenpeng Han , Pingheng Tan , Zhimin Liao , Xiaosong Wu , Dapeng Yu

Graphene is an intriguing material with properties that are distinct from those of other graphitic systems. The first samples of pristine graphene were obtained by peeling off and epitaxial growth. Recently, the chemical reduction of…

材料科学 · 物理学 2015-05-13 Xiaolin Li , Guangyu Zhang , Xuedong Bai , Xiaoming Sun , Xinran Wang , Enge Wang , Hongjie Dai

We demonstrate molecular beam growth of graphene on biotite mica substrates at temperatures below 1000{\deg}C. As indicated by optical and atomic force microscopy, evaporation of carbon from a high purity solid-state source onto biotite…

When epitaxial graphene layers are formed on SiC(0001), the first carbon layer (known as the "buffer layer"), while relatively easy to synthesize, does not have the desirable electrical properties of graphene. The conductivity is poor due…

材料科学 · 物理学 2015-05-18 S. Oida , F. R. McFeely , J. B. Hannon , R. M. Tromp , M. Copel , Z. Chen , Y. Sun , D. B. Farmer , J. Yurkas

Epitaxial graphene grown on metallic substrates presents, in several cases, a long-range periodic structure due to a lattice mismatch between the graphene and the substrate. For instance, graphene grown on Ir(111), displays a corrugated…

Nano-rippled graphene, a structurally modified graphene, presents a novel material with a large range of possible applications including sensors, electrodes, coatings, optoelectronics, spintronics and straintronics. In this work we have…

介观与纳米尺度物理 · 物理学 2015-11-20 Iva Šrut Rakić , Davor Čapeta , Milivoj Plodinec , Marko Kralj

We demonstrate that graphene coating can provide an efficient protection from oxidation by posing a high energy barrier to the path of oxygen atom, which could have penetrated from the top of graphene to the reactive surface underneath.…

介观与纳米尺度物理 · 物理学 2012-04-25 M. Topsakal , H. Şahin , S. Ciraci

The monolayer form of CVD graphene is imposing crucial challenges in characterization of the targeted covalent functionalization due to the low amount of grafting moieties on the surface, which in turn hampers drawing conclusions about…

材料科学 · 物理学 2021-07-20 Irena Matulková , Petr Kovaříček , Miroslav Šlouf , Ivan Němec , Martin Kalbáč

Since the discovery of graphene, its excellent physical properties has greatly improved the performance of many optoelectronic devices and brought important technological revolution to optical research and application. Here, we introduce…

光学 · 物理学 2021-09-07 Xianyou Wang , Yunqi Yuan , Xi Xie , Yuquan zhang , Changjun Min , Xiaocong Yuan

Techniques for mass-production of large area graphene using an industrial scale thin film deposition tool could be the key to the practical realization of a wide range of technological applications of this material. Here, we demonstrate the…

材料科学 · 物理学 2013-02-20 Genhua Pan , Mark Heath , David Horsell , M. Lesley Wears

We report on suspended single-layer graphene deposition by a transfer-printing approach based on polydimethylsiloxane stamps. The transfer printing method allows the exfoliation of graphite flakes from a bulk graphite sample and their…

介观与纳米尺度物理 · 物理学 2015-05-28 Sarah Goler , Vincenzo Piazza , Stefano Roddaro , Vittorio Pellegrini , Fabio Beltram , Pasqualantonio Pingue

The epitaxial growth of functional materials using a substrate with a graphene layer is a highly desirable method for improving structural quality and obtaining free-standing epitaxial nano-membranes for scientific study, applications, and…

Copper foil impurities are hampering scalable production of high-quality graphene by chemical vapor deposition (CVD). Here, we conduct a thorough study on the origin of these unavoidable contaminations at the surface of copper after the CVD…

材料科学 · 物理学 2023-09-27 N. Reckinger , B. Hackens

Angle-resolved photoemission and X-ray diffraction experiments show that multilayer epitaxial graphene grown on the SiC(000-1) surface is a new form of carbon that is composed of effectively isolated graphene sheets. The unique rotational…

Water dissociation is of fundamental importance in scientific fields and has drawn considerable interest in diverse technological applications. However, the high activation barrier of breaking the O-H bond within the water molecule has been…

材料科学 · 物理学 2023-03-15 Zhijing Huang , Zihan Yan , Guangdong Zhu , Xing Chen , Shuming Zeng , Xiuyun Zhang , Liang Zhao , Yusong Tu

Transfer of graphene, grown by Chemical Vapor Deposition (CVD), to a substrate of choice, typically involves deposition of a polymeric layer (typically, poly(methyl methacrylate, PMMA or polydimethylsiloxane, PDMS). These polymers are quite…

应用物理 · 物理学 2019-07-09 H. Grebel , L. Stan , A. V. Sumant , Y. Liu , D. Gosztola , L. Ocola , B. Fisher

A bottom-up chemical vapor deposition (CVD) process for the growth of graphene nanomesh films is demonstrated. The process relies on silicon nanospheres to block nucleation sites for graphene CVD on copper substrates. These spheres are…

材料科学 · 物理学 2016-09-16 Matthias König , Günther Ruhl , Joerg-Martin Batke , Max C. Lemme

We report the chemical reaction of single-layer graphene with hydrogen atoms, generated in situ by electron-induced dissociation of hydrogen silsesquioxane (HSQ). Hydrogenation, forming sp3 C-H functionality on the basal plane of graphene,…

Ni(OH)2 nanocrystals grown on graphene sheets with various degrees of oxidation are investigated as electrochemical pseudocapacitor materials for potential energy storage applications. Single-crystalline Ni(OH)2 hexagonal nanoplates…

材料科学 · 物理学 2010-05-07 Hailiang Wang , Hernan Sanchez Casalongue , Yongye Liang , Hongjie Dai