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Clausius introduced, in the 1860s, a thermodynamical quantity which he named {\it entropy} $S$. This thermodynamically crucial quantity was proposed to be {\it extensive}, i.e., in contemporary terms, $S(N) \propto N$ in the thermodynamic…

统计力学 · 物理学 2011-06-21 Constantino Tsallis

Boltzmann-Gibbs statistical mechanics is based on the entropy $S_{BG}=-k \sum_{i=1}^W p_i \ln p_i$. It enables a successful thermal approach of ubiquitous systems, such as those involving short-range interactions, markovian processes, and,…

统计力学 · 物理学 2009-11-10 Constantino Tsallis , Edgardo Brigatti

Ergodicity, this is to say, dynamics whose time averages coincide with ensemble averages, naturally leads to Boltzmann-Gibbs (BG) statistical mechanics, hence to standard thermodynamics. This formalism has been at the basis of an enormous…

统计力学 · 物理学 2009-11-10 Constantino Tsallis , Celia Anteneodo , Lisa Borland , Roberto Osorio

In 1910 Einstein published a crucial aspect of his understanding of Boltzmann entropy. He essentially argued that the likelihood function of any system composed by two probabilistically independent subsystems {\it ought} to be factorizable…

统计力学 · 物理学 2015-05-22 Constantino Tsallis , Hans J. Haubold

It is by now well known that the Boltzmann-Gibbs (BG) entropy $S_{BG}=-k\sum_{i=1}^W p_i \ln p_i$ can be usefully generalized into the entropy $S_q=k (1-\sum_{i=1}^Wp_i^{q}) / (q-1)$ ($q\in \mathcal{R}; S_1=S_{BG}$). Microscopic dynamics…

统计力学 · 物理学 2009-11-10 Giorgos-Artemios Tsekouras , Constantino Tsallis

In this lecture we briefly review the definition, consequences and applications of an entropy, $S_q$, which generalizes the usual Boltzmann-Gibbs entropy $S_{BG}$ ($S_1=S_{BG}$), basis of the usual statistical mechanics, well known to be…

统计力学 · 物理学 2007-05-23 Constantino Tsallis , Fulvio Baldovin , Roberto Cerbino , Paolo Pierobon

The basic aspects of both Boltzmann-Gibbs (BG) and nonextensive statistical mechanics can be seen through three different stages. First, the proposal of an entropic functional ($S_{BG} =-k\sum_i p_i \ln p_i$ for the BG formalism) with the…

统计力学 · 物理学 2016-08-31 Constantino Tsallis , Andre M. C. Souza

The cornerstone of Boltzmann-Gibbs ($BG$) statistical mechanics is the Boltzmann-Gibbs-Jaynes-Shannon entropy $S_{BG} \equiv -k\int dx f(x)\ln f(x)$, where $k$ is a positive constant and $f(x)$ a probability density function. This theory…

物理与社会 · 物理学 2009-11-11 Silvio M. Duarte Queiros , Celia Anteneodo , Constantino Tsallis

The science of thermodynamics was put together in the Nineteenth Century to describe large systems in equilibrium. One part of thermodynamics defines entropy for equilibrium systems and demands an ever-increasing entropy for non-equilibrium…

统计力学 · 物理学 2014-03-26 Leo P. Kadanoff

Since its origin in the thermodynamics of the 19th century, the concept of entropy has also permeated other fields of physics and mathematics, such as Classical and Quantum Statistical Mechanics, Information Theory, Probability Theory,…

机器学习 · 统计学 2025-03-06 Salomé A. Sepúveda Fontaine , José M. Amigó

We generalize the usual exponential Boltzmann factor to any reasonable and potentially observable distribution function, $B(E)$. By defining generalized logarithms $\Lambda$ as inverses of these distribution functions, we are led to a…

统计力学 · 物理学 2007-05-23 Rudolf Hanel , Stefan Thurner

The foundations of the Boltzmann-Gibbs (BG) distributions for describing equilibrium statistical mechanics of systems are examined. Broadly, they fall into: (i) probabilistic paaroaches based on the principle of equal a priori probability…

统计力学 · 物理学 2009-11-10 A. K. Rajagopal , Sumiyoshi Abe

A plethora of natural, artificial and social complex systems exists which violate the basic hypothesis (e.g., ergodicity) of Boltzmann-Gibbs (BG) statistical mechanics. Many of such cases can be satisfactorily handled by introducing…

统计力学 · 物理学 2016-07-26 Constantino Tsallis

Many complex systems are characterized by non-Boltzmann distribution functions of their statistical variables. If one wants to -- justified or not -- hold on to the maximum entropy principle for complex statistical systems (non-Boltzmann)…

统计力学 · 物理学 2009-11-13 Stefan Thurner , Rudolf Hanel

Regardless of studies and debates over a century, the statistical origin of the second law of thermodynamics still remains illusive. One essential obstacle is the lack of a proper theoretical formalism for non-equilibrium entropy. Here I…

统计力学 · 物理学 2017-10-18 Xiangjun Xing

The possible distinction between inanimate and living matter has been of interest to humanity since thousands of years. Clearly, such a rich question can not be answered in a single manner, and a plethora of approaches naturally do exist.…

统计力学 · 物理学 2014-03-24 Constantino Tsallis

Boltzmann's struggle with a derivation of the Second Law of Thermodynamics is sketched. So is his first derivation of the connection between entropy and probability in 1877. Planck's derivation and quantum mechanical modifications of…

物理学史与哲学 · 物理学 2008-07-11 E. G. D. Cohen

In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann's analysis,…

统计力学 · 物理学 2007-05-23 Sheldon Goldstein

A statistical thermodynamic approach of moving particles forming an elastic body is presented which leads to reveal molecular-mechanical properties of classical and nonextensive dynamical systems. We derive the Boltzmann-Gibbs (BG) entropy…

统计力学 · 物理学 2009-11-10 Enrique Canessa

The Boltzmann-Gibbs celebrated entropy $S_{BG}=-k\sum_ip_i \ln p_i$ is {\it concave} (with regard to all probability distributions $\{p_i\}$) and {\it stable} (under arbitrarily small deformations of any given probability distribution). It…

统计力学 · 物理学 2015-06-24 A. M. C. Souza , C. Tsallis
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