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Energy dissipation in water is very fast and more efficient than in many other liquids. This behavior is commonly attributed to the intermolecular interactions associated with hydrogen bonding. Here, we investigate the dynamic energy flow…

Highly intense, sub-picosecond terahertz (THz) pulses can be used to induce ultrafast temperature jumps (T-jumps) in liquid water. A supercritical state of gas-like water with liquid density is established, and the accompanying structural…

化学物理 · 物理学 2019-01-24 Caroline Arnold , Ludger Inhester , Sergio Carbajo , Ralph Welsch , Robin Santra

Ultrafast, time-resolved spectroscopies enable the direct observation of non-equilibrium processes in condensed-phase systems and have revealed key insights into energy transport, hydrogen-bond dynamics, and vibrational coupling. While ab…

化学物理 · 物理学 2025-09-01 Kit Joll , Philipp Schienbein

Molecular dynamics simulations of supercritical water reveal distinctly different distance-dependent modulations of dipolar response and correlations in particle motion compared to ambient conditions. The strongly perturbed H-bond network…

化学物理 · 物理学 2021-04-15 Maciej Śmiechowsk , Christoph Schran , Harald Forbert , Dominik Marx

The heating effect of terahertz pulse with various frequencies and intensities on the heavy water solution is investigated using the molecular dynamics simulation. Resonant absorptions are found for both heavy water and light water, but at…

化学物理 · 物理学 2017-01-23 Rong-Yao Yang , Zi-Qian Huang , Si-Na Wei , Qi-Lin Zhang , Wei-Zhou Jiang

The modern means of controlled irradiation by femtosecond lasers or swift heavy ion beams can transiently produce such energy densities in samples that reach collective electronic excitation levels of the warm dense matter state where the…

其他凝聚态物理 · 物理学 2023-02-17 Nikita Medvedev , Roman Voronkov , Alexander E. Volkov

Liquid water is one of the most studied substances, yet many of its properties are difficult to rationalize. The uniqueness of water is rooted in the dynamic network of hydrogen-bonded molecules with relaxation time constants of about one…

Dynamic structuring of water is a key player in a large class of processes underlying biochemical and technological developments today, the latter often involving electric fields. However, the anisotropic coupling between the water…

软凝聚态物质 · 物理学 2019-05-29 Andreas Baer , Zoran Miličević , David M. Smith , Ana-Sunčana Smith

The processing of energy by transfer and redistribution plays a key role in the evolution of dynamical systems. At the ultrasmall and ultrafast scale of nanosystems, quantum coherence could in principle also play a role and has been…

We perform molecular dynamics simulations using the extended simple point charge SPC/E water model in order to investigate the dynamical behavior of supercooled-stretched water. We focus on the behavior of the translational diffusion…

统计力学 · 物理学 2007-05-23 P. A. Netz , F. Starr , M. C. Barbosa , H. Eugene Stanley

The static and dynamical properties of heavy water have been studied at ambient conditions with extensive Car-Parrinello molecular-dynamics simulations in the canonical ensemble, with temperatures ranging between 325 K and 400 K.…

软凝聚态物质 · 物理学 2007-05-23 P. H-L. Sit , Nicola Marzari

Using molecular dynamics simulations we study the dynamics of a water-like TIP5P model of water in hydrophilic and hydrophobic confinement. We find that in case of extreme nanocofinement such that there is only one molecular layer of water…

软凝聚态物质 · 物理学 2010-05-14 Pradeep Kumar

The energy acquisition based on resonant excitations are of great importance in chemical and biological systems. Here, the intramolecular resonant absorption of polarized mid-infrared pulses by bulk water and surface water is investigated…

介观与纳米尺度物理 · 物理学 2022-02-16 Rong-Yao Yang , Wei-Zhou Jiang , Pei-Ying Huo

Heat dissipation is ubiquitous in living systems, which constantly convert distinct forms of energy into each other. The transport of thermal energy in liquids and even within proteins is well understood but kinetic energy transfer across a…

软凝聚态物质 · 物理学 2026-01-07 Brandon Neff , Matthias Heyden

In simulations of aqueous systems it is common to freeze the bond vibration and angle bending modes in water to allow for a longer time-step $\delta t$ for integrating the equations of motion. Thus $\delta t = 2$ fs is often used in…

软凝聚态物质 · 物理学 2023-08-17 Dilipkumar N. Asthagiri , Thomas L. Beck

Energy redistribution after a chemical reaction is one of the few mechanisms to explain the diffusion and desorption of molecules which require more energy than the thermal energy available in quiescent molecular clouds (10 K). This energy…

星系天体物理 · 物理学 2023-05-10 Germán Molpeceres , Viktor Zaverkin , Kenji Furuya , Yuri Aikawa , Johannes Kästner

Molecular dynamics simulations are performed to study the temperature-dependent dynamics and structures of the hydration shells of elastin-like and collagen-like peptides. For both model peptides, it is consistently observed that, upon…

软凝聚态物质 · 物理学 2009-02-23 Michael Vogel

The creation of well-thermalized, hot and dense plasmas is attractive for warm dense matter studies. We investigate collisionally induced energy absorption of an ultraintense and ultrashort laser pulse in a solid copper target using…

等离子体物理 · 物理学 2020-04-29 Andréas Sundström , Laurent Gremillet , Evangelos Siminos , István Pusztai

We determine conditions allowing to simplify the description of the impact of a short and arbitrarily intense laser pulse onto a cold plasma at rest. If both the initial plasma density and pulse profile have plane simmetry, then suitable…

等离子体物理 · 物理学 2023-05-10 Gaetano Fiore , Monica De Angelis , Renato Fedele , Gabriele Guerriero , Dusan Jovanović

The energy landscape approach has been useful to help understand the dynamic properties of supercooled liquids and the connection between these properties and thermodynamics. The analysis in numerical models of the inherent structure (IS)…

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