相关论文: The ionization conjecture in Thomas-Fermi-Dirac-vo…
We consider the zero mass limit of a relativistic Thomas-Fermi-Weizsaecker model of atoms and molecules. We find bounds for the critical nuclear charges that ensure stability.
It is established within the Thomas -- Fermi model that a bound state of a proton with a heavy atom should exist. On the one hand, the electrons of the atom screen the proton's field. This decreases the repulsion force between the proton…
Recently, we have proposed the existence of a universal relation between the maximal electric charge and total mass of any weakly self-gravitating object: $Z\leq Z^*={\alpha}^{-1/3}A^{2/3}$, where $Z$ is the number of protons, $A$ is the…
As the nuclear charge Z is continuously decreased an N-electron atom undergoes a binding-unbinding transition at some critical Z_c. We investigate whether the electrons remain bound when Z=Z_c and whether the radius of the system stays…
We consider a large atom with nuclear charge $Z$ described by non-relativistic quantum mechanics with classical or quantized electromagnetic field. We prove that the absolute ground state energy, allowing for minimizing over all possible…
A Thomas-Fermi-Weizsaecker type theory is constructed, by means of which we are able to give a relatively simple proof of the stability of relativistic matter. Our procedure has the advantage over previous ones in that the critical value of…
By extrapolating the energies of non-relativistic atoms and their ions with up to 3000 electrons within Kohn-Sham density functional theory, we find that the ionization potential remains finite and increases across a row, even as…
We study {{\rm C}$_{60}$} with the use of Thomas-Fermi theory. A spherical shell model is invoked to treat the nuclear potential, where the nuclear and core charges are smeared out into a shell of constant surface charge density. The…
In this short note we argue that Thomas-Fermi Theory the simplest of all density functional theories, although failing to explain features such as binding or stability of negative ions, is surprisingly accurate in estimating sizes of atoms.…
We prove within the Hartree-Fock theory of pseudo-relativistic atoms that the maximal negative ionization charge and the ionization energy of an atom remain bounded independently of the nuclear charge Z and the fine structure constant…
Based on the Thomas-Fermi approach, we describe and distinguish the electron distributions around extended nuclear cores: (i) in the case that cores are neutral for electrons bound by protons inside cores and proton and electron numbers are…
While it is well-known experimentally that a neutral atom can bind at most one or two extra electrons, deriving this fact rigorously from first principles of quantum mechanics remains a very challenging problem, often referred to as the…
We show an atom of atomic number $Z$ described by the time-dependent Thomas-Fermi equation or the Vlasov equation cannot bind more than $4Z$ electrons.
The atomic nucleus, viewed as a system of bound quarks, should, in principle, be described within an effective theory of low-energy quantum chromodynamics. This paper provides an overview of recently developed models that embody essential…
The recently developed semiclassical variational Wigner-Kirkwood (VWK) approach is applied to finite nuclei using external potentials and self-consistent mean fields derived from Skyrme interactions and from relativistic mean field theory.…
We study the stability and universal behaviour of the ionization energy of N-electron atoms with nuclear charge Z in the anionic domain (Z<N), considering the nuclear charge Z as an arbitrary (non-integral) parameter. HF and CISD ground…
The uniform electron gas placed between two reservoirs is used as a model system for molecular junctions under an external bias. The energetics of the electron gas are calculated by generalizing the Thomas-Fermi-Dirac (TFD) model to…
A general approach to analyze the electrodynamics of nuclear matter in bulk is presented using the relativistic Thomas-Fermi equation generalizing to the case of $N \simeq (m_{\rm Planck}/m_n)^3$ nucleons of mass $m_n$ the approach well…
A relativistic version of the effective charge model for computation of observable characteristics of multi-electron atoms and ions is developed. A complete and orthogonal Dirac hydrogen basis set, depending on one parameter -- effective…
The strong Scott conjecture about the electron density at a distance 1/Z from an atomic nucleus of charge $Z$ and its generalization for molecules are proved. The density, suitably scaled, converges to an explicit limiting density as $Z \to…