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We report a strong thickness dependence of the complex frequency-dependent optical dielectric function in epitaxial CaMnO3(001) thin films on SrTiO3(001), LaAlO3(001), and SrLaAlO4(001) substrates. A doubling of the peak value of the…

Thin films are a prerequisite for application of the emergent exotic ground states in iridates that result from the interplay of strong spin-orbit coupling and electronic correlations. We report on pulsed laser deposition of…

强关联电子 · 物理学 2015-02-26 Marcus Jenderka , Rüdiger Schmidt-Grund , Marius Grundmann , Michael Lorenz

We report on optical studies of the thin films of multiferroic hexagonal (P.G. 6mm) rare-earth orthoferrites RFeO3 (R=Ho, Er, Lu) grown epitaxially on a (111)-surface of ZrO2(Y2O3) substrate. The optical absorption study in the range of…

The results of fabrication and characterization of atomic structure of nanocrystalline thin layers of Y2O3 in cubic and monoclinic phases is reported. Experimental data demonstrate crystalline ordering in nanocrystalline films with average…

材料科学 · 物理学 2022-12-28 D. W. Boukhvalov , D. A. Zatsepin , Yu. A. Kuznetsova , N. V. Gavrilov , A. F. Zatsepin

We use a combined generalized spectroscopic ellipsometry and density functional theory approach to determine and analyze the anisotropic dielectric functions of an $\alpha$-Ga$_2$O$_3$ thin film. The sample is grown epitaxially by…

Multiferroic BiFeO3 epitaxial films with thickness ranging from 40 nm to 960 nm were grown by pulsed laser deposition on SrTiO3 (001) substrates with SrRuO3 bottom electrodes. X-ray characterization shows that the structure evolves from…

材料科学 · 物理学 2009-11-13 Dae Ho Kim , Ho Nyung Lee , Michael D. Biegalski , Hans M. Christen

We have studied the electronic structure of epitaxially grown thin films of La$_{1-x}$Sr$_x$FeO$_3$ by {\it in-situ} photoemission spectroscopy (PES) and x-ray absorption spectroscopy (XAS) measurements. The Fe 2$p$ and valence-band PES…

High-quality YTiO3 thin films were grown on LaAlO3 (110) substrates at low oxygen pressures (<10-8 Torr) using pulsed laser deposition. The in-plane asymmetric atomic arrangements at the substrate surface allowed us to grow epitaxial YTiO3…

材料科学 · 物理学 2009-11-11 S. C. Chae , Y. J. Chang , S. S. A. Seo , T. W. Noh , D. -W. Kim , C. U. Jung

Hexagonal LuFeO$_3$ films have been studied using x-ray absorption and optical spectroscopy. The crystal splittings of Fe$^{3+}$ are extracted as $E_{e'}-E_{e"}$=0.7 eV and $E_{a_1'}-E_{e'}$=0.9 eV and a 2.0 eV optical band gap is…

WO3 thin films were grown by atomic layer deposition and spectroscopic ellipsometry data gathered in the photon energy range of 0.72-8.5 eV and from multiple samples was utilized to determine the frequency dependent complex-valued isotropic…

The anisotropic optical properties of multiferroic BiFeO$_3$ thin films have been determined with Mueller matrix ellipsometry at room-temperature. The full dielectric tensors of tetragonal-like and rhombohedral-like BiFeO$_3$ phases…

材料科学 · 物理学 2015-08-26 Daniel Schmidt , Lu You , Xiao Chi , Junling Wang , Andrivo Rusydi

The complex dielectric functions of LiNbO$_2$ were determined using optical transmittance and reflectance spectroscopies at room temperature. The measured dielectric function spectra reveal distinct structures at several bandgap energies.…

材料科学 · 物理学 2023-10-30 T. Kurachi , T. Yamaguchi , E. Kobayashi , T. Soma , A. Ohtomo , T. Makino

There has been growing interest in perovskite BaSnO3 due to its desirable properties for oxide electronic devices including high electron mobility at room temperature and optical transparency. As these electronic and optical properties…

Optical spectra (absorption, emission, excitation, decay) and dielectric relaxation were measured for divalent europium (and partially for ytterbium) in lanthanum fluoride crystals. Absorption of Eu$^{2+}$ contains not only asymmetric…

材料科学 · 物理学 2015-11-03 E A Radzhabov , R Yu Shendrik

We report on the heteroepitaxial stabilization of YCrO3 ultra-thin films on LSAT (001) substrate. Using a combination of resonant X-ray absorption spectroscopy (XAS) and atomic multiplet cluster calculation, the electronic structure of…

We have investigated the crystal structure and the ferroelectric properties of BaTiO3 thin films with YBa2Cu3O7-d as the bottom and Au as the top electrode. Epitaxial heterostructures of YBa2Cu3O7-d and BaTiO3 were prepared by dc and rf…

材料科学 · 物理学 2009-10-31 Ch. Schwan , F. Martin , G. Jakob , J. C. Martinez , H. Adrian

We measure the remnant polarization of ferroelectric domains in BiFeO3 films down to 3.6 nm using low energy electron and photoelectron emission microscopy. The measured polarization decays strongly below a critical thickness of 5-7 nm…

We have investigated the electronic, vibrational, optical, thermal and piezoelectric properties of LiNbO$_3$, LiTaO$_3$ and Li$_2$NbTaO$_6$ using the first-principles calculation based on the density functional theory. It also shows…

材料科学 · 物理学 2025-03-28 Debidutta Pradhan , Rojalin Swain , Souvagya Kumar Biswal , Jagadish Kumar

Epitaxial Ba0.5Sr0.5TiO3 thin films grown on the (001) LaAlO3 substrates with the ferroelectric transition of about 250K have been investigated by TEM and off-axis electron holography. Cross-sectional TEM observations show that the…

材料科学 · 物理学 2009-11-10 H. F. Tian , H. C. Yu , X. H. Zhu , Y. G. Wang , D. N. Zheng , H. X. Yang , J. Q. Li

We report the epitaxial growth of BiFeO3 by pulsed electron deposition and the resulting crystal quality, magnetic and nanoscale switching properties. X-ray diffraction shows high quality single phase, epitaxial (001) oriented films grown…

材料科学 · 物理学 2015-06-12 Hongxue Liu , Ryan Comes , Yonghang Pei , Jiwei Lu , Stuart Wolf
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