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相关论文: Hubbard-$U$ corrected Hamiltonians for non-self-co…

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The fully self-consistent Random Phase Approximation (RPA) is constructed within the Unitary Correlation Operator Method (UCOM), which describes the dominant interaction-induced short-range central and tensor correlations by a unitary…

核理论 · 物理学 2009-11-11 N. Paar , P. Papakonstantinou , R. Roth , H. Hergert

We use a spin-rotational invariant Gutzwiller energy functional to compute random-phase-approximation-like (RPA) fluctuations on top of the Gutzwiller approximation (GA). The method can be viewed as an extension of the previously developed…

强关联电子 · 物理学 2008-06-16 G. Seibold , F. Becca , P. Rubin , J. Lorenzana

The Hubbard model is the simplest model that is believed to exhibit superconductivity arising from purely repulsive interactions, and has been extensively applied to explore a variety of unconventional superconducting systems. Here we study…

We present a method to approximate post-Hartree-Fock correlation energies by using approximate natural orbitals obtained by the random phase approximation (RPA). We demonstrate the method by applying it to the helium atom, the hydrogen and…

化学物理 · 物理学 2021-03-22 Benjamin Ramberger , Zoran Sukurma , Tobias Schäfer , Georg Kresse

The self-consistent random phase approximation (RPA) based on a correlated realistic nucleon-nucleon interaction is used to evaluate correlation energies in closed-shell nuclei beyond the Hartree-Fock level. The relevance of contributions…

核理论 · 物理学 2007-05-23 C. Barbieri , N. Paar , R. Roth , P. Papakonstantinou

Self-consistent correlation potentials for H$_2$ and LiH for various inter-atomic separations are obtained within the random phase approximation (RPA) of density functional theory. The RPA correlation potential shows a peak at the bond…

化学物理 · 物理学 2015-05-30 M. Hellgren , D. R. Rohr , E. K. U. Gross

We explore a separable resolution-of-the-identity formalism built on quadratures over limited sets of real-space points designed for all-electron calculations. Our implementation preserves in particular the use of common atomic orbitals and…

化学物理 · 物理学 2019-05-22 Ivan Duchemin , Xavier Blase

An analytical expression for the self-energy of the infinite-dimensional Hubbard model is proposed that interpolates between different exactly solvable limits. We profit by the combination of two recent approaches that are based on the…

强关联电子 · 物理学 2009-10-31 M. Potthoff , T. Herrmann , W. Nolting

We present a first-principles study of the low-temperature rhombohedral phase of BaTiO$_3$ using Hubbard-corrected density-functional theory. By employing density-functional perturbation theory, we compute the onsite Hubbard $U$ for…

材料科学 · 物理学 2023-12-29 G. Gebreyesus , Lorenzo Bastonero , Michele Kotiuga , Nicola Marzari , Iurii Timrov

We use the random phase approximation (RPA) method with the singles correlation energy contributions to calculate lattice energies of ten molecular solids. While RPA gives too weak binding, underestimating the reference data by $13.7$\% on…

化学物理 · 物理学 2016-09-21 Jiří Klimeš

Hubbard-corrected density functional theory, denoted by DFT+U method, was developed to enable correct prediction of insulating properties for strongly-correlated electron systems. UO$_2$ is an example having O-$2p$, U-$6d$, and U-$5f$…

强关联电子 · 物理学 2023-02-28 Mahmoud Payami

We propose a self-consistent site-dependent Hubbard $U$ approach for DFT+$U$ calculations of defects in complex transition-metal oxides, using Hubbard parameters computed via linear-response theory. The formation of a defect locally…

材料科学 · 物理学 2019-04-04 Chiara Ricca , Iurii Timrov , Matteo Cococcioni , Nicola Marzari , Ulrich Aschauer

In wavefunction-based $\textit{ab-initio}$ quantum mechanical calculations, achieving absolute convergence with respect to the one-electron basis set is a long-standing challenge. In this work, using the random phase approximation (RPA)…

材料科学 · 物理学 2025-10-17 Hao Peng , Xinguo Ren

An essential ingredient in many model Hamiltonians, such as the Hubbard model, is the effective electron-electron interaction $U$, which enters as matrix elements in some localized basis. These matrix elements provide the necessary…

强关联电子 · 物理学 2019-05-29 Tor Jonas Sjöstrand , Fredrik Nilsson , Christoph Friedrich , Ferdi Aryasetiawan

Transition-metal centers are the active sites for many biological and inorganic chemical reactions. Notwithstanding this central importance, density-functional theory calculations based on generalized-gradient approximations often fail to…

软凝聚态物质 · 物理学 2009-11-11 Heather J. Kulik , Matteo Cococcioni , Damian A. Scherlis , Nicola Marzari

The Hubbard model on a semi-infinite three-dimensional lattice is considered to investigate electron-correlation effects at single-crystal surfaces. The standard second-order perturbation theory in the interaction U is used to calculate the…

强关联电子 · 物理学 2009-10-30 M. Potthoff , W. Nolting

Ab-initio, self-consistent electronic energy bands of rutile TiO2 are reported within the local density functional approximation (LDA). Our first principle, non-relativistic and ground state calculations employed a local density functional…

材料科学 · 物理学 2012-03-23 C. E. Ekuma , D. Bagayoko

In electronic structure methods based on the correction of approximate density-functional theory (DFT) for systematic inaccuracies, Hubbard $U$ parameters may be used to quantify and amend the self-interaction errors ascribed to selected…

强关联电子 · 物理学 2017-04-27 Glenn Moynihan , Gilberto Teobaldi , David D. O'Regan

Engineering effective electronic parameters is a major focus in condensed matter physics. Their dynamical modulation opens the possibility of creating and controlling physical properties in systems driven out of equilibrium. In this work,…

强关联电子 · 物理学 2018-09-12 Nicolas Tancogne-Dejean , Michael A. Sentef , Angel Rubio

The DCA$^+$ algortihm was recently introduced to extend the dynamic cluster approximation (DCA) with a continuous lattice self-energy in order to achieve better convergence with cluster size. Here we extend the DCA$^+$ algorithm to the…

强关联电子 · 物理学 2015-06-18 Peter Staar , Thomas Maier , Thomas Schulthess