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In this work, we reported uniform layer-by-layer sublimation of black phosphorus under heating below 600 K. The uniformity and crystallinity of BP samples after thermal thinning were confirmed by Raman spectra and 2D Raman imaging. A…

材料科学 · 物理学 2017-08-02 Weijun Luo , Rui Yang , Jialun Liu , Yunlong Zhao , Wenjuan Zhu , Guangrui , Xia

Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Though highly desirable, a…

介观与纳米尺度物理 · 物理学 2017-02-07 Guowei Zhang , Shenyang Huang , Andrey Chaves , Chaoyu Song , V. Ongun Özçelik , Tony Low , Hugen Yan

Two-dimensional crystals have emerged as a new class of materials with novel properties that may impact future technologies. Experimentally identifying and characterizing new functional two-dimensional materials in the vast material pool is…

材料科学 · 物理学 2015-06-18 Likai Li , Yijun Yu , Guo Jun Ye , Qingqin Ge , Xuedong Ou , Hua Wu , Donglai Feng , Xian Hui Chen , Yuanbo Zhang

Violet phosphorus (VP) has garnered attention for its appealing physical properties and potential applications in optoelectronics. We present a comprehensive investigation of the photo-degradation and thermal effects of exfoliated VP on…

Mid-infrared saturable absorber mirror is successfully fabricated by transferring the mechanically exfoliated black phosphorus onto the gold-coated mirror. With the as-prepared black phosphorus saturable absorber mirror, a continuous-wave…

光学 · 物理学 2015-09-23 Zhipeng Qin , Guoqiang Xie , Chujun Zhao , Shuangchun Wen , Peng Yuan , Liejia Qian

An experimental setup was developed for the measurement of the thermoelectric power (TEP, Seebeck coefficient) in the temperature range from 2 to 350 K and magnetic fields up to 140 kOe. The system was built to fit in a commercial cryostat…

仪器与探测器 · 物理学 2015-05-18 Eundeok Mun , Sergey L. Bud'ko , Milton S. Torikachvili , Paul C. Canfield

The attraction between electrons and holes in semiconductors forms excitons, which largely determine the optical properties of the hosting material, and hence the device performance, especially for low-dimensional systems. Mono- and…

介观与纳米尺度物理 · 物理学 2018-03-20 Guowei Zhang , Andrey Chaves , Shenyang Huang , Fanjie Wang , Qiaoxia Xing , Tony Low , Hugen Yan

Black phosphorus is a quasi-two-dimensional layered semiconductor with a narrow direct band gap of 0.3 eV. A giant surface Stark effect can be produced by the potassium doping of black phosphorus, leading to a semiconductor to semimetal…

材料科学 · 物理学 2021-07-21 G. Kremer , M. Rumo , C. Yue , A. Pulkkinen , C. W. Nicholson , T. Jaouen , F. O. von Rohr , P. Werner , C. Monney

The single-layer black phosphorus is characteristic for its puckered structure, which has leaded to highly anisotropy in its optical, electronic, and mechanical properties. We report, using the non-equilibrium Green's function approach and…

材料科学 · 物理学 2015-02-13 Jin-Wu Jiang

We have calculated numerically electron exchange, correlation energies and dynamical polarization function for newly discovered silicene, germanene and black phosphorus (BP), consisting of puckered layers of elemental phosphorus atoms,…

介观与纳米尺度物理 · 物理学 2016-05-30 Andrii Iurov , Godfrey Gumbs , Danhong Huang

The temperature dependence of the band gap is crucial to a semiconductor. Bulk black phosphorus (BP) is known to exhibit an anomalous behavior. Through optical spectroscopy, here we show that the temperature effect on BP band gap gradually…

We have fabricated black phosphorus photodetectors and characterized their full spectral responsivity. These devices, which are effectively in the bulk thin film limit, show broadband responsivity ranging from <400 nm to the ~3.8 $\mu$m…

We report record performance for black phosphorus p-MOSFETs. The devices have locally patterned back gates and 20-nm-thick HfO2 gate dielectrics. Devices with effective gate length, Leff = 1.0 um display extrinsic transconductance, gm, of…

介观与纳米尺度物理 · 物理学 2014-10-01 Nazila Haratipour , Matthew C. Robbins , Steven J. Koester

Semiconductor materials are the foundation of modern electronics, and their functionality is dictated by the interactions between fundamental excitations occurring on (sub-)picosecond timescales. Using time-resolved Raman spectroscopy and…

Black phosphorus, a newly emerged two-dimensional material, has attracted wide attention as novel photonic material. Here, multi-layer black phosphorus is successfully fabricated by liquid phase exfoliation method. By employing black…

The metal contacts on 2D black phosphorus field-effect transistor and photodetectors are studied. The metal work functions can significantly impact the Schottky barrier at the metal-semiconductor contact in black phosphorus devices. Higher…

材料科学 · 物理学 2015-03-26 Yexin Deng , Nathan J. Conrad , Zhe Luo , Han Liu , Xianfan Xu , Peide D. Ye

Phosphorene, a single atomic layer of black phosphorus, has recently emerged as a new twodimensional (2D) material that holds promise for electronic and photonic technology. Here we experimentally demonstrate that the electronic structure…

We ascertain the anisotropic thermal conductivity of alumina passivated black phosphorus (BP), a reactive 2D nanomaterial with strong in-plane anisotropy. We measure the room temperature thermal conductivity by time-domain thermoreflectance…

材料科学 · 物理学 2015-10-02 Hyejin Jang , Joshua D. Wood , Christopher R. Ryder , Mark C. Hersam , David G. Cahill

Fractoluminescence experiments are performed on two kinds of silicate glasses. All the light spectra collected during dynamic fracture reveal a black body radiator behaviour, which is interpreted as a crack velocity-dependent temperature…

We compute the transient dynamics of phonons in contact with high energy "hot" charge carriers in 12 polar and non-polar semiconductors, using a first-principles Boltzmann transport framework. For most materials, we find that the decay in…

介观与纳米尺度物理 · 物理学 2017-10-03 Sridhar Sadasivam , Maria K. Y. Chan , Pierre Darancet