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This work is devoted to the consistent modeling of a three-phase mixture of a gas, a liquid and its vapor. Since the gas and the vapor are mis-cible, the mixture is subjected to a non-symmetric constraint on the volume. Adopting the Gibbs…

偏微分方程分析 · 数学 2017-10-13 Hélène Mathis

In the Entropic Dynamics (ED) framework quantum theory is derived as an application of entropic methods of inference. The physics is introduced through appropriate choices of variables and of constraints that codify the relevant physical…

广义相对论与量子宇宙学 · 物理学 2019-10-04 Selman Ipek , Ariel Caticha

A new approach to non-extensive thermodynamical systems with non-additive energy and entropy is proposed. The main idea of the paper is based on the statistical matching of the thermodynamical systems with the additive multi-step Markov…

数据分析、统计与概率 · 物理学 2007-05-23 S. S. Apostolov , Z. A. Mayzelis , O. V. Usatenko , V. A. Yampol'skii

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

量子物理 · 物理学 2026-03-26 Gian Paolo Beretta

We formulate and prove in this report some sufficient conditions for exponential tightness (ET) of a family of independent identical distributed (i.i.d.) random fields (r.f.) (processes) in the space of continuous functions defined on…

概率论 · 数学 2014-04-01 E. Ostrovsky , L. Sirota

To investigate the consequences of component confinement such as at a glass transition and the well-known energy or enthalpy gap (between the glass and the perfect crystal at absolute zero, see text), we follow our previous approach [Phys.…

统计力学 · 物理学 2015-03-17 P. D. Gujrati

The maximum entropy principle determines the values of thermodynamic variables in thermally isolated equilibrium systems. This paper extends the principle to a variational principle that applies to liquid-gas coexistence in heat conduction.…

统计力学 · 物理学 2024-12-30 Naoko Nakagawa , Shin-ichi Sasa

Thermodynamic relations are derived from first principles of mechanics for non-equilibrium processes. Since the key role herein is played by the law of increase of entropy, the latter is analyzed at first. It is shown that its derivation…

chao-dyn · 物理学 2008-02-03 J. Kumicak , X. de Hemptinne

A generalization of the Gibbs entropy postulate is proposed based on the BBGKY hierarchy as the nonequilibrium entropy for a system of N interacting particles. This entropy satisfies the basic principles of thermodynamics in the sense that…

统计力学 · 物理学 2007-05-23 A. Perez-Madrid

This paper presents a nonequilibrium, first-principles, thermodynamic-ensemble based model for the relaxation process of interacting non-equilibrium systems. This model is formulated using steepest-entropy-ascent quantum thermodynamics…

统计力学 · 物理学 2018-10-10 Guanchen Li , Michael R. von Spakovsky

Research on the birth and evolution of life are reviewed with reference to the maximum entropy production principle (MEPP). It has been shown that this principle is essential for consistent understanding of the birth and evolution of life.…

生物物理 · 物理学 2025-04-22 Yasuji Sawada , Yasukazu Daigaku , Kenji Toma

We first discuss the geometrical construction and the main mathematical features of the maximum-entropy-production/steepest-entropy-ascent nonlinear evolution equation proposed long ago by this author in the framework of a fully quantum…

量子物理 · 物理学 2015-05-13 Gian Paolo Beretta

A theory for non-equilibrium systems is derived from a maximum entropy approach similar in spirit to the equilibrium theory given by Gibbs. Requiring Hamilton's principle of stationary action to be satisfied on average during a trajectory,…

统计力学 · 物理学 2019-02-04 David M. Rogers , Susan B. Rempe

We study the asymptotic properties of the trajectories of a discrete-time random dynamical system in an infinite-dimensional Hilbert space. Under some natural assumptions on the model, we establish a multiplica-tive ergodic theorem with an…

偏微分方程分析 · 数学 2020-01-22 Davit Martirosyan , Vahagn Nersesyan

Nonequilibrium thermodynamics (NET) investigates processes in systems out of global equilibrium. On a mesoscopic level, it provides a statistical dynamic description of various complex phenomena such as chemical reactions, ion transport,…

统计力学 · 物理学 2016-04-20 Hong Qian , Signe Kjelstrup , Anatoly B. Kolomeisky , Dick Bedeaux

Entropic dynamics (ED) is a framework that allows one to derive quantum theory as a Hamilton-Killing flow on the cotangent bundle of a statistical manifold. These flows are such that they preserve the symplectic and the (information) metric…

量子物理 · 物理学 2025-11-25 Ariel Caticha

This paper establishes the minimum entropy principle (MEP) for the relativistic Euler equations with a broad class of equations of state (EOSs) and addresses the challenge of preserving the local version of the discovered MEP in high-order…

数值分析 · 数学 2025-03-18 Shumo Cui , Kailiang Wu , Linfeng Xu

Entropy principles based on thermodynamic consistency requirements are widely used for constitutive modeling in continuum mechanics, providing physical constraints on a priori unknown constitutive functions. The well-known M\"uller-Liu…

数值分析 · 数学 2018-12-05 J. Heß , A. F. Cheviakov

Concepts of everyday use like energy, heat, and temperature have acquired a precise meaning after the development of thermodynamics. Thermodynamics provides the basis for understanding how heat and work are related and with the general…

统计力学 · 物理学 2007-05-23 D. Reguera , J. M. Rubi , J. M. G. Vilar

We introduce the entropic measure transform (EMT) problem for a general process and prove the existence of a unique optimal measure characterizing the solution. The density process of the optimal measure is characterized using a…

数理金融 · 定量金融 2019-02-22 Renjie Wang , Cody Hyndman , Anastasis Kratsios