相关论文: Barrierless Reactions in Solution: An Analytically…
A general approach to calculate the diabatic surfaces for electron-transfer reactions is presented, based on first-principles molecular dynamics of the active centers and their surrounding medium. The excitation energy corresponding to the…
In this paper we develop a hybrid version of the encounter-based approach to diffusion-mediated absorption at a reactive surface, which takes into account stochastic switching of a diffusing particle's conformational state. For simplicity,…
Reactio-nonlocal diffusion equations model nonlocal transport and anomalous diffusion by replacing the Laplacian with a fractional power, capturing diffusion mechanisms beyond Brownian motion. We primarily study the semilinear problem \[…
We present the model of a diffusion-absorption process in a system which consists of two media separated by a thin partially permeable membrane. The kind of diffusion as well as the parameters of the process may be different in both media.…
The Dirac equation in (1+1) dimensions with a non-local PT-symmetric potential of separable type is studied by means of the Green function method: properties of bound and scattering states are derived in full detail and numerical results…
We consider a reaction-diffusion system which may serve as a model for a ferment catalytic reaction in chemistry. The model consists of a system of reaction diffusion equations with unbounded time dependent coefficients and different…
We revise the encounter-based approach to imperfect diffusion-controlled reactions, which employs the statistics of encounters between a diffusing particle and the reactive region to implement surface reactions. We extend this approach to…
It has been shown by Yu.~Yaremko [Elect. J. Theor. Phys. {\bf 9}, 153 (2012)] within the classial electrodynamics that the hypothetical massless charged particle must generate an infinitely strong radiation reaction, thus not an external…
The kinetics of bimolecular reactions in solution depends, among other factors, on intermolecular forces such as steric repulsion or electrostatic interaction. Microscopically, a pair of molecules first has to meet by diffusion before the…
Stochastic chemical systems with diffusion are modeled with a reaction-diffusion master equation. On a macroscopic level, the governing equation is a reaction-diffusion equation for the averages of the chemical species. On a mesoscopic…
In this note we study the dynamics of a model recently introduced by one of us, that displays glassy phenomena in absence of energy barriers. Using an adiabatic hypothesis we derive an equation for the evolution of the energy as a function…
We consider reaction-diffusion systems where components diffuse inside the domain and react on the surface through mass transport type boundary conditions on an evolving domain. Using Lyapunov functional and duality arguments, we establish…
In this paper, the looping kinetics of a long polymer chain in solution has been investigated by using two state model, where one state represents open chain polymer molecule and the other represents closed chain polymer molecule. The…
The behavior of the single-species reaction process $A+A\to O$ is examined near an impenetrable boundary, representing the flask containing the reactants. Two types of dynamics are considered for the reactants: diffusive and ballistic…
In Boundary Element Method, Green's function with no boundary conditions is used for solving Laplace's equation with Dirichlet boundary condition. To determine the gradient of solution on the boundary, we need to solve the boundary integral…
This chapter aims at emphasizing the crucial role of partial reactivity of a catalytic surface or a target molecule in diffusion-controlled reactions. We discuss various microscopic mechanisms that lead to imperfect reactions, the Robin…
We establish the existence of solutions to a class of non-linear stochastic differential equation of reaction-diffusion type in an infinite-dimensional space, with diffusion corresponding to a given transition kernel. The solution obtained…
We consider holographic theories at finite temperature in which a continuous global symmetry in the bulk is spontaneously broken. We study the linear response of operators in a regime which is dual to time dependent, long wavelength…
The spatially-dependent mass Dirac equation is solved exactly for attractive scalar and repulsive vector Coulomb potentials including a tensor interaction potential under the spin and pseudospin (p-spin) symmetric limits by using the…
We consider the mixed Steklov-Neumann spectral problem for the modified Helmholtz equation in a bounded domain when the Steklov condition is imposed on a connected subset of the smooth boundary. In order to deduce the asymptotic behavior in…