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Supercooled liquids exhibit spatial heterogeneity in the dynamics of their fluctuating atomic arrangements. The length and time scales of the heterogeneous dynamics are central to the glass transition and influence nucleation and growth of…

材料科学 · 物理学 2018-05-09 Pei Zhang , Jason J. Maldonis , Ze Liu , Jan Schroers , Paul M. Voyles

The origin of the dramatic changes in the behavior of liquids as they approach their vitreous state - increases of many orders of magnitude in transport properties and dynamic time scales - is a major unsolved problem in condensed matter.…

软凝聚态物质 · 物理学 2015-06-23 R. Casalini , D. Fragiadakis , C. M. Roland

The viscosity of glass-forming liquids increases by many orders of magnitude if their temperature is lowered by a mere factor of 2-3 [1,2]. Recent studies suggest that this widespread phenomenon is accompanied by spatially heterogeneous…

无序系统与神经网络 · 物理学 2015-05-28 Walter Kob , Sandalo Roldan-Vargas , Ludovic Berthier

A few years ago it was showed that some systems that have very similar local structure, as quantified by the pair correlation function, exhibit vastly different slowing down upon supercooling [L. Berthier and G. Tarjus, Phys. Rev. Lett.…

软凝聚态物质 · 物理学 2015-06-17 Elijah Flenner , Hannah Staley , Grzegorz Szamel

We discuss a novel approach, the point-to-set correlation functions, that allows to determine relevant static and dynamic length scales in glass-forming liquids. We find that static length scales increase monotonically when the temperature…

无序系统与神经网络 · 物理学 2013-07-04 Walter Kob , Sandalo Roldan-Vargas , Ludovic Berthier

The existence of heterogeneity in the dynamics of supercooled liquids is believed to be one of the hallmarks of the glass transition. Intense research has been carried out in the past to understand the origin of this heterogeneity in…

软凝聚态物质 · 物理学 2020-07-01 Indrajit Tah , Smarajit Karmakar

Recent work has demonstrated the strong qualitative differences between the dynamics near a glass transition driven by short-ranged repulsion and one governed by short-ranged attraction. Here, we study in detail the behavior of non-linear,…

统计力学 · 物理学 2010-04-16 P. Charbonneau , D. R. Reichman

We report an extensive and systematic investigation of the multi-point and multi-time correlation functions to reveal the spatio-temporal structures of dynamic heterogeneities in glass-forming liquids. Molecular dynamics simulations are…

软凝聚态物质 · 物理学 2013-01-04 Kang Kim , Shinji Saito

The super-cooled $N3$ model exhibits an increasingly slow dynamics as density approaches the model's random closest packing density. Here, we present a direct measurement of the dynamical correlation function $G_4(r,t)$, showing the…

统计力学 · 物理学 2010-12-21 Ziv Rotman , Eli Eisenberg

We use recently introduced three-point dynamic susceptibilities to obtain an experimental determination of the temperature evolution of the number of molecules, N_corr, that are dynamically correlated during the structural relaxation of…

Diverse material classes exhibit practically identical behavior when made viscous upon cooling toward the glass transition, suggesting a common theoretical basis. The first-principles scaling laws that have been proposed to describe the…

We have investigated dynamical heterogeneity in a highly supercooled liquid using molecular-dynamics simulations in three dimensions. Dynamical heterogeneity can be characterized by three quantities: correlation length $\xi_4$, intensity…

软凝聚态物质 · 物理学 2012-04-25 Hideyuki Mizuno , Ryoichi Yamamoto

We discuss the spatiotemporal behavior of local density and its relation to dynamical heterogeneity in a highly supercooled liquid by using molecular dynamics simulations of a binary mixture with different particle sizes in two dimensions.…

软凝聚态物质 · 物理学 2015-03-20 Hayato Shiba , Takeshi Kawasaki

While deeply supercooled liquids exhibit divergent viscosity and increasingly heterogeneous dynamics as the temperature drops, their structure shows only seemingly marginal changes. Understanding the nature of relaxation processes in this…

材料科学 · 物理学 2022-11-03 Matthias Lerbinger , Armand Barbot , Damien Vandembroucq , Sylvain Patinet

We study theoretically and numerically a family of multi-point dynamic susceptibilities that quantify the strength and characteristic lengthscales of dynamic heterogeneities in glass-forming materials. We use general theoretical arguments…

We investigate dynamical heterogeneities in the collective relaxation of a concentrated microgel system, for which the packing fraction can be conveniently varied by changing the temperature. The packing fraction dependent mechanical…

软凝聚态物质 · 物理学 2011-05-31 David A. Sessoms , Irmgard Bischofberger , Luca Cipelletti , Véronique Trappe

Glass-forming liquids grow dramatically sluggish upon cooling. This slowdown has long been thought to be accompanied by a growing correlation length. Characteristic dynamical and static length scales, however, have been observed to grow at…

无序系统与神经网络 · 物理学 2016-08-22 Patrick Charbonneau , Ethan Dyer , Jaehoon Lee , Sho Yaida

The dramatic dynamic slowing down associated with the glass transition is considered by many to be related to the existence of a static length scale that grows when temperature decreases. Defining, identifying and measuring such a length is…

统计力学 · 物理学 2014-05-29 Giulio Biroli , Smarajit Karmakar , Itamar Procaccia

The use of probe molecules to extract the local dynamical and structural properties of complex dynamical systems is an age-old technique both in simulations and experiments. A lot of important information which is not immediately accessible…

软凝聚态物质 · 物理学 2021-03-30 Anoop Mutneja , Smarajit Karmakar

We analyse, using Inhomogenous Mode-Coupling Theory, the critical scaling behaviour of the dynamical susceptibility at a distance epsilon from continuous second-order glass transitions. We find that the dynamical correlation length xi…

无序系统与神经网络 · 物理学 2014-12-17 Saroj Kumar Nandi , Giulio Biroli , Jean-Philippe Bouchaud , Kunimasa Miyazaki , David R. Reichman
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