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相关论文: Exact Density Functional for the Non-Relativistic …

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Based on the Schrodinger equation, exact expressions for the non-relativistic particle energy in the local external field and the external field potential are derived as inhomogeneous density functionals. On this basis, it is shown that,…

统计力学 · 物理学 2012-01-17 V. B. Bobrov , S. A. Trigger

It is shown that the Hohenberg-Kohn lemma and theorem are direct consequences of the statement that the ground state energy (or free energy) of a system of interacting particles in an external field is a unique functional of the potential…

统计力学 · 物理学 2010-08-17 V. B. Bobrov , S. A. Trigger , G. J. F. van Heijst

A rigorous derivation of the density functional in the Hohenberg-Kohn theory is presented. With no assumption regarding the magnitude of the electric coupling constant $e^2$ (or correlation), this work provides a firm basis for…

其他凝聚态物理 · 物理学 2010-09-20 Yi-Kuo Yu

We propose a density functional to find the ground state energy and density of interacting particles, where both the density and the pair density can adjust in the presence of an inhomogeneous potential. As a proof of principle we formulate…

强关联电子 · 物理学 2015-06-11 J. Lorenzana , Z. -J. Ying , V. Brosco

The Hohenberg-Kohn theorem and the Kohn-Sham equations, which are at the basis of the Density Functional Theory, are reformulated in terms of a particular many-body density, which is translational invariant and therefore is relevant for…

核理论 · 物理学 2021-09-29 A. Kievsky , G. Orlandini , M. Gattobigio

By introducing a phase field and solving the eigen-functional equation of particles, we obtain the exact expressions of the ground state energy as a functional of the particle density for interacting electron/boson systems, and a…

强关联电子 · 物理学 2007-05-23 Yu-Liang Liu

The Hohenberg-Kohn theorem, a cornerstone of electronic density functional theory, concerns uniqueness of external potentials yielding given ground densities of an ${\mathcal N}$-body system. The problem is rigorously explored in a universe…

其他凝聚态物理 · 物理学 2018-04-12 Paul E. Lammert

Accurate treatment of the electronic correlation in inhomogeneous electronic systems, combined with the ability to capture the correlation energy of the homogeneous electron gas, allows to reach high predictive power in the application of…

强关联电子 · 物理学 2010-06-22 E. Rasanen , S. Pittalis , C. R. Proetto

A generalization of the Kohn--Sham approach is derived where the correlation-energy functional depends on the one-particle density matrix of noninteracting states and on the external potential from the interacting target-state. The…

化学物理 · 物理学 2007-05-23 James P. Finley

The capability of density-functional theory to deal with the ground-state of strongly correlated low-dimensional systems, such as semiconductor quantum dots, depends on the accuracy of functionals developed for the exchange and correlation…

强关联电子 · 物理学 2009-02-25 S. Pittalis , E. Rasanen , C. Proetto , E. K. U. Gross

It is shown that in adiabatic approximation for nuclei the many-component Coulomb system cannot be described on the basis of the grand canonical ensemble. Using the variational Bogolyubov's procedure for the free energy, the Hohenberg-Kohn…

统计力学 · 物理学 2010-04-07 V. B. Bobrov , S. A. Trigger

The density functional theory originally developed by Hohenberg, Kohn and Sham provides a rigorous conceptual framework for dealing with inhomogeneous interacting Fermi systems. We extend this approach to deal with inhomogeneous interacting…

凝聚态物理 · 物理学 2015-06-25 A. Griffin

A rigorous derivation of the density functional via the effective action in the Hohenberg-Kohn theory is outlined. Using the auxiliary field method, in which the electric coupling constant $e^2$ need not be small, we show that the loop…

其他凝聚态物理 · 物理学 2009-09-22 Yi-Kuo Yu

The self consistent version of the density functional theory is presented, which allows to calculate the ground state and dynamic properties of finite multi-electron systems. An exact functional equation for the effective interaction, from…

材料科学 · 物理学 2017-08-23 M. Ya. Amusia , A. Z. Msezane , V. R. Shaginyan

We analyse the ground-state energy and correlation energy of the Heisenberg model as a function of spin, both in the ferromagnetic and in the antiferromagnetic case, and in one, two and three dimensions. First, we present a comparative…

材料科学 · 物理学 2009-11-10 Valter L. Libero , K. Capelle

There are different ways to obtain an exact one-electron theory for a many-electron system, and the exact electron factorization (EEF) is one of them. In the EEF, the Schr\"odinger equation for one electron in the environment of other…

化学物理 · 物理学 2022-04-06 Jakub Kocák , Eli Kraisler , Axel Schild

The State--Specific Kohn--Sham Density Functional Theory [arXiv:physics/0506037] is used to derive the Kohn-Sham exchange-correlation potential $\vxc$ and exchange-correlation energy $\Eco$ as explicit functionals of $v_s$ and $\phi_1$,…

化学物理 · 物理学 2025-01-31 James P. Finley

A recently developed quasi two-dimensional exact-exchange formalism within the framework of Density Functional Theory has been applied to a strongly inhomogeneous interacting electron gas, and the results were compared with state-of-the-art…

凝聚态物理 · 物理学 2009-11-07 S. Rigamonti , F. A. Reboredo , C. R. Proetto

Density functional theory is discussed in the context of one-particle systems. We show that the ground state density $\rho_0(x)$ and energy $E_0$ are simply related to a family of external potential energy functions with ground state wave…

量子物理 · 物理学 2009-11-10 H. L. Neal

A density-functional theory is developed based on the Maxwell--Schr\"odinger equation with an internal magnetic field in addition to the external electromagnetic potentials. The basic variables of this theory are the electron density and…

化学物理 · 物理学 2018-01-17 Erik Tellgren
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