相关论文: Interpretation of Pulsed-Field-Gradient NMR in Ter…
We report initial NMR studies of i) xenon gas diffusion in model heterogeneous porous media, and ii) continuous flow laser-polarized xenon gas. Both areas utilize the Pulsed Gradient Spin Echo techniques in the gas-phase, with the aim of…
Nuclear magnetic resonance (NMR) is a widely used nondestructive method to study random motion of spin-bearing particles in different systems. In the long-time limit the theoretical description of the NMR experiments is well developed and…
Nanomechanical resonators (NMRs), as the quantum mechanical sensing probers, have played the important roles for various high-precision quantum measurements. Differing from the previous emission spectral probes (i.e., the NMR modified the…
To make certain quantitative interpretations of spectra from NMR experiments carried out on heterogeneous samples, such as cells and tissues, we must be able to estimate the magnetic and electric fields experienced by the resonant nuclei of…
We propose a quantum interferometric protocol that leverages spin-dependent spatial displacements to enable high-precision parameter estimation beyond classical limits. By inducing a unitary coupling between a particles spin degree of…
The mean square displacement $\langle\left(x(t)-x(0)\right)^2\rangle$ of the position $x$ of a free particle of mass $m$ at thermal equilibrium is evaluated quantum mechanically. An analytical expression is obtained which shows an initial…
We evaluate critically the use of pulsed gradient spin-echo nuclear magnetic resonance (PGSE NMR) to measure molecular mobility during chemical reactions. With raw NMR spectra available in a public depository, we confirm boosted mobility…
We propose a method for obtaining the intrinsic, long time mean square displacement (MSD) of atoms and molecules in proteins from finite time molecular dynamics (MD) simulations. Typical data from simulations are limited to times of 1 to 10…
Nuclear Magnetic Resonance (NMR) is one of the main experimental tools to evaluate the production potential of porous rocks in oil wells. From the relative areas and mean values obtained from relaxation time distribution curves, information…
This paper is devoted to the multiple-quantum (MQ) NMR spectroscopy in nanopores filled by a gas of spin-carrying molecules (s=1/2) in a strong external magnetic field. It turned out that the high symmetry of the spin system in nanopores…
The nuclear magnetic resonance (NMR) spectrum of spin-3/2 nuclei in a static magnetic field aligned with one of the electric field gradient (EFG) principal axes is developed analytically, based on fictitious spin-1/2 formalism. Compact…
There have been increasing reports that the diffusion coefficient of macromolecules depends on time and fluctuates randomly. Here, a novel method to elucidate the fluctuating diffusivity from trajectory data is developed. The time-averaged…
Ion adsorption and dynamics in porous carbons is crucial for many technologies such as energy storage and desalination. Nuclear Magnetic Resonance (NMR) spectroscopy is a key method to investigate such systems thanks to the possibility to…
The mean square displacement per collision of a molecule immersed in a gas at equilibrium is given by its mean square displacement between two consecutive collisions (mean square free path) corrected by a prefactor in the form of a series.…
Observations of far-infrared (FIR) and submillimeter (SMM) polarized emission are used to study magnetic fields and dust grains in dense regions of the interstellar medium (ISM). These observations place constraints on models of molecular…
We present a simple $^1$H NMR approach for characterizing intermediate to fast regime molecular motions using $^1$H time-domain NMR at low magnetic field. The method is based on a Goldmann Shen dipolar filter (DF) followed by a Mixed Magic…
Anomalous diffusion is frequently described by scaled Brownian motion (SBM), a Gaussian process with a power-law time dependent diffusion coefficient. Its mean squared displacement is $\langle x^2(t)\rangle\simeq\mathscr{K}(t)t$ with…
The diffusion motion of spin-bearing molecules is considerably affected in confined environments. In Nuclear Magnetic Resonance (NMR) experiments, under the presence of magnetic field gradients, this movement can be encoded in spin phase…
The vibrated bed of powder, a vessel that mono disperse glass beads fill and a loud speaker shakes, is investigated numerically with the distinct element method, a kind of molecular dynamics. When the bed is heavily shaken, the displacement…
We describe a new approach to precision NMR with hyperpolarized gases designed to mitigate NMR frequency shifts due to the alkali spin exchange field. The electronic spin polarization of optically pumped alkali atoms is square-wave…