相关论文: Theoretical Framework for Microscopic Osmotic Phen…
We investigate the overall optomechanical force experienced by a macroscopic lossy object in free space under external quantum illumination. To this end, utilizing the Modified Langevin Noise Formalism (MLNF), we derive the time-averaged…
From glycosylated cell surfaces to sterically stabilized liposomes, polymers attached to membranes attract biological and therapeutic interest. Can the scaling laws of polymer "brushes" describe the physical properties of these coats? We…
We study the hyperbolic scaling limit for a chain of N coupled anharmonic oscillators. The chain is attached to a point on the left and there is a force (tension) $\tau$ acting on the right. In order to provide good ergodic properties to…
In this paper we investigate gravitationally bound, spherically symmetric equilibrium configurations consisting of ordinary (polytropic) matter nonminimally coupled to an external chameleon scalar field. We show that this system has static,…
We consider static charged fluid spheres with a cosmological constant. We assume a polytropic equation of state, $p \propto \rho^\Gamma$, and a power law charge distribution, $q\propto r^n$. Using this, we convert the generalised…
For static fluid spheres, the condition of hydrostatic equilibrium is given by the generalized Tolman--Oppenheimer--Volkoff (TOV) equation, a Riccati equation in the radial pressure. For a perfect fluid source, it is known that finding a…
Micromorphic theories became an established tool to model size effects in materials like dispersion, localization phenomena or (apparently) size dependent properties. However, the formulation of adequate constitutive relations with its…
The goal of the present paper is to study the weak--strong uniqueness problem for the compressible Navier--Stokes system with a general barotropic pressure law. Our results include the case of a hard sphere pressure of Van der Waals type…
We experimentally measure the osmotic pressures of linear polymers and three-, four-, and eight-arm star polymers in a good solvent via membrane osmometry. These results reveal that the osmotic equations of state in the star polymer…
We consider the theoretical description of a fluid adsorbed in a nanopore. Hysteresis and discontinuities in the isotherms in general hampers the determination of equilibrium thermodynamic properties, even in computer simulations. A…
We present an overview of the recent progress that has been made in understanding the origin of hydrophobic interactions. We discuss the different character of the solvation behavior of apolar solutes at small and large length scales. We…
We first highlight theoretically a microfluidic configuration that allows to measure two fundamental parameters describing mass transport through a membrane: the solute permeability coefficient $\mathcal{L}_D$, and the associated reflection…
Understanding interactions between membranes requires measurements on well-controlled systems close to natural conditions, in which fluctuations play an important role. We have determined, by grazing incidence X-ray scattering, the…
A generalized Van der Waals approach is developed for anisotropic fluids in disordered porous media. As the reference system a hard spherocylinder fluid in a disordered porous medium is considered and described in the framework of the…
We derive from kinetic theory, fluid mechanics, and thermodynamics the minimal continuum-level equations governing the flow of a binary, non-electrolytic mixture in an isotropic porous medium with osmotic effects. For dilute mixtures, these…
We determine the second, third, and fourth virial coefficients appearing in the density expansion of the osmotic pressure of a monodisperse polymer solution in good-solvent conditions. Using the expected large-concentration behavior, we…
The inherent instability of oscillatory flows presents a significant challenge in microfluidics, impairing performance in different applications from particle detachemnt to organs-on-a-chip. Trapped air inside a microfluidic system…
A multicomponent extension of our recent theory of simple fluids [ U.M.B. Marconi and S. Melchionna, Journal of Chemical Physics, 131, 014105 (2009) ] is proposed to describe miscible and immiscible liquid mixtures under inhomogeneous, non…
We study the vapour-liquid phase behaviour of an ionic fluid confined in a random porous matrix formed by uncharged hard sphere particles. The ionic fluid is modelled as an equimolar binary mixture of oppositely charged equisized hard…
A fluid in a pore can form diverse heterogeneous structures. We combine a capillary description with the cubic-plus-association equation of state to study the thermodynamic stability of droplets, bubbles and films of water at 358 K in a…