相关论文: Theoretical Framework for Microscopic Osmotic Phen…
I develop simple thermodynamic relations for a collection of noninteracting classical particles confined in a harmonic trap. The volume of such a trap is not a good thermodynamic variable, so conventional expressions of the first law of…
Smoothed Particle Hydrodynamics (SPH) is a Lagrangian method for solving the fluid equations that is commonplace in astrophysics, prized for its natural adaptivity and stability. The choice of variable to smooth in SPH has been the topic of…
We define the pressure of a porous medium in terms of the grand potential, and compute its value in a nano-confined or nano-porous medium, meaning a medium where thermodynamic equations need be adjusted for smallness. On the nano-scale, the…
Incompressibility is established for three-dimensional and two-dimensional deformations of an anisotropic linearly elastic material, as conditions to be satisfied by the elastic compliances. These conditions make it straightforward to…
Regarding a recent dispute about the symmetry of the stress tensor of fluids, more considerations are presented. The usual proofs of this symmetry are reviewed, and contradictions between this symmetry and the mechanism of gas viscosity are…
We introduce axiomatically a complete thermodynamic formalism for a single macromolecule, either with or without detailed balance, in an isothermal ambient fluid based on its stochastic dynamics. With detailed balance, the novel theory…
Newton's force law $\frac{d {\bf P}}{dt} = {\bf F}$ is derived from the Schr\"odinger equation for isolated macroscopic bodies, composite states of e.g., $N\sim 10^{25}, 10^{51}, \ldots$ atoms and molecules, at finite body temperatures. We…
Matter agglomeration mesoscopic phenomena of irreversible type are well described by nonequilibrium thermodynamics formalism. The description assumes that the thermodynamic (internal) state variables are in local equilibrium, and uses the…
Mesoscopic density functional theory for inhomogeneous mixtures of sperical particles is developed in terms of mesoscopic volume fractions by a systematic coarse-graining procedure starting form microscopic theory. Approximate expressions…
We develop a theory of fluid--structure interaction (FSI) between an oscillatory Newtonian fluid flow and a compliant conduit. We consider the canonical geometries of a 2D channel with a deformable top wall and an axisymmetric deformable…
Onsager's phenomenological equations successfully describe irreversible thermodynamic processes. They assume a symmetric coupling matrix between thermodynamic fluxes and forces. It is easily shown that the antisymmetric part of a coupling…
We propose and analyze a mathematical model of the mechanics of gels, consisting of the laws of balance of mass and linear momentum. We consider a gel to be an immiscible and incompressible mixture of a nonlinearly elastic polymer and a…
We investigate the impact of an external pressure on the structure of self-gravitating polytropes for axially symmetric ellipsoids and rings. The confinement of the fluid by photons is accounted for through a boundary condition on the…
Recent work giving a classification of kinematic and vorticity conservation laws of compressible fluid flow for barotropic equations of state (where pressure is a function only of the fluid density) in $n>1$ spatial dimensions is extended…
In the present paper, we define the sheath by a monotone stationary solution to the nonisentropic Euler-Poisson system under a condition known as the Bohm criterion and consider a situation in which charged particles accumulate on the…
We consider the physical setup of a three-dimensional fluid-structure interaction problem. A viscous compressible gas or liquid interacts with a nonlinear, visco-elastic, three-dimensional bulk solid. The latter is described by a hyperbolic…
The generalized entropy theory is applied to assess the joint influence of the microscopic cohesive energy and chain stiffness on glass formation in polymer melts using a minimal model containing a single bending energy and a single…
In this work we investigate the dynamical properties of a mixture of mutually interacting spherical molecules of different masses and sizes. From an analysis of the microscopic laws governing the motion of the molecules we derive a set of…
We assess the validity of "microscopic" approaches of glass-forming liquids based on the sole k nowledge of the static pair density correlations. To do so we apply them to a benchmark provided by two liquid models that share very similar…
Observations have suggested substantial departures from pressure equilibrium in the interstellar medium (ISM) in the plane of the Galaxy, even on scales under 50 pc. Nevertheless, multi-phase models of the ISM assume at least locally…