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Modeling and simulation studies using a high-order Landau-de Gennes type model for the direct isotropic/smectic-A liquid crystal transition are presented showing the existence of meta-stable nematic pre-ordering under certain conditions, in…

软凝聚态物质 · 物理学 2009-06-29 Nasser Mohieddin Abukhdeir , Alejandro D. Rey

Extensions of a previously presented Landau-de Gennes type liquid crystalline phase transition model for the direct isotropic/smectic-A (lamellar) a phase transition to the direct isotropic/smectic-C (tilted lamellar) transition are…

软凝聚态物质 · 物理学 2008-12-02 Nasser Mohieddin Abukhdeir , Alejandro D. Rey

In this work, we study the nematic-isotropic phase transition based on the dynamics of the Landau--De Gennes theory of liquid crystals. At the critical temperature, the Landau--De Gennes bulk potential favors the isotropic phase and nematic…

偏微分方程分析 · 数学 2021-07-28 Tim Laux , Yuning Liu

We mathematically model Smectic-A (SmA) phases with a modified Landau-de Gennes (mLdG) model. The orientational order of the SmA phase is described by a tensor-order parameter $\mathbf{Q}$, and the positional order is described by a real…

软凝聚态物质 · 物理学 2025-09-22 Baoming Shi , Yucen Han , Chengdi Ma , Apala Majumdar , Lei Zhang

We demonstrate that a first order isotropic-to-nematic phase transition in liquid crystals can be succesfully modeled within the generalized Landau-de Gennes theory by selecting an appropriate combination of elastic constants. The numerical…

软凝聚态物质 · 物理学 2019-02-19 Dmitry Golovaty , Young-Ki Kim , Oleg D. Lavrentovich , Michael Novack , Peter Sternberg

Experimental and modeling/simulation studies of phase equilibrium and growth morphologies of novel polymer-dispersed liquid crystal (PDLC) mixtures of PS (polystyrene) and liquid crystals that exhibit a direct isotropic/smectic-A (lamellar)…

软凝聚态物质 · 物理学 2015-05-13 Ezequiel R. Soule , Nasser Mohieddin Abukhdeir , Alejandro D. Rey

A computational study of morphological instabilities of a two-dimensional nematic front under directional growth was performed using a Landau-de Gennes type quadrupolar tensor order parameter model for the first-order isotropic/nematic…

软凝聚态物质 · 物理学 2009-08-20 Ezequiel R. Soulé , Nasser Mohieddin Abukhdeir. Alejandro D. Rey

A Landau-de Gennes model that integrates the nematic quadrupolar tensor order parameter and complex smectic-A order parameters is used to simulate the two-dimensional growth of an initially homogeneous smectic-A spherulite in an isotropic…

软凝聚态物质 · 物理学 2009-02-11 Nasser Mohieddin Abukhdeir , Alejandro D. Rey

A computational study of the growth of two-dimensional nematic spherulites in an isotropic phase was performed using a Landau-de Gennes type quadrupolar ensor order parameter model for the first-order isotropic/nematic transition of 5CB…

化学物理 · 物理学 2008-11-29 Nasser Mohieddin Abukhdeir , Ezequiel R. Soule , Alejandro D. Rey

We investigate the asymptotic behaviour of a correlation function associated with a nematic liquid crystal system undergoing an isotropic-nematic phase transition following an instantaneous change of temperature. Within the setting of…

偏微分方程分析 · 数学 2013-10-07 Eduard Kirr , Mark Wilkinson , Arghir Zarnescu

We introduce a new class of non-isothermal models describing the evolution of nematic liquid crystals and prove their consistency with the fundamental laws of classical Thermodynamics. The resulting system of equations captures all…

偏微分方程分析 · 数学 2015-05-27 E. Feireisl , M. Fre'mond , E. Rocca , G. Schimperna

We study the gradient flow model for the Landau-de Gennes energy functional for nematic liquid crystals at the nematic-isotropic transition temperature on prototype geometries. We study the dynamic model on a three-dimensional droplet and…

偏微分方程分析 · 数学 2016-03-29 Apala Majumdar , Paul A. Milewski , Amy Spicer

A comprehensive modeling and simulation study of the first-order isotropic/smectic-A transition is presented and applied to phase diagram computation and two-dimensional spherulite growth. An approach based on nonlinear optimization, that…

化学物理 · 物理学 2009-08-20 Nasser Mohieddin Abukhdeir , Alejandro D. Rey

In this paper, we derive the sharp interface model of the nematic-isotropic phase transition from the Landau-de Gennes theory by using the matched asymptotic expansion method. The model includes the evolution equation of the velocity and…

偏微分方程分析 · 数学 2014-11-04 Mingwen Fei , Wei Wang , Pingwen Zhang , Zhifei Zhang

We find in a model system of thermotropic liquid crystals that the translational diffusion coefficient parallel to the director $D_{\parallel}$ first increases and then decreases as temperature drops through the nematic phase, and this…

软凝聚态物质 · 物理学 2009-11-11 Dwaipayan Chakrabarti , Biman Bagchi

We report on strong pretransitional effects across the isotropic liquid-plastic crystal melting temperature in linear and nonlinear dielectric response. Studies were carried out for cyclooctanol (C8H16O) in the unprecedented range of…

软凝聚态物质 · 物理学 2019-12-10 A. Drozd-Rzoska , S. Starzonek , S. J. Rzoska , J. Łoś , Z. Kutnjak , S. Kralj

Recent experiments report that the long looked for thermotropic biaxial nematic phase has been finally detected in some thermotropic liquid crystalline systems. Inspired by these experimental observations we concentrate on some elementary…

软凝聚态物质 · 物理学 2008-09-24 David Allender , Lech Longa

Based on static and dynamical density functional theory, a phase-field-crystal model is derived which involves both the translational density and the orientational degree of ordering as well as a local director field. The model exhibits…

软凝聚态物质 · 物理学 2015-05-19 Hartmut Löwen

Using the Landau-de Gennes theory, the temperature, pressure and frequency dependence of the non-linear effect in the isotropic phase above the isotropic-cholesteric phase transition is calculated. The influence of pressure on the…

材料科学 · 物理学 2015-06-03 Prabir. K. Mukherjee , Sumanta Chakraborty , Sylwester J. Rzoska

The short-range order which remains when the isotropic to smectic-A transition is perturbed by a gel of silica nanoparticles (aerosils) has been studied using high-resolution synchrotron x-ray diffraction. The gels have been created…

软凝聚态物质 · 物理学 2009-11-10 M. K. Ramazanoglu , P. S. Clegg , R. J. Birgeneau , C. W. Garland , M. E. Neubert , J. M. Kim
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