相关论文: Possible canonical distributions for finite system…

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble, whereas canonical ones fail in the most interesting, mostly inhomogeneous, situations like phase separations or away from the thermodynamic…

The relationship between thermodynamics and statistical physics is valid in the thermodynamic limit - when the number of particles becomes very large. Here, we study thermodynamics in the opposite regime - at both the nano scale, and when…

The non extensive thermodynamics of an ideal gas composed by bosons and/or fermions is derived from its partition function for systems with finite chemical potentials. It is shown that the thermodynamical quantities derived in the present…

The equipartition theorem states that in equilibrium thermal energy is equally distributed among uncoupled degrees of freedom which appear quadratically in the system's Hamiltonian. However, for spatially coupled degrees of freedom --- such…

Stochastic thermodynamics as reviewed here systematically provides a framework for extending the notions of classical thermodynamics like work, heat and entropy production to the level of individual trajectories of well-defined…

We have considered a model of a small finite system with internal particles and surface degrees of freedom. All the main statistical distributions were explicitly obtained, on a pre thermodynamic limit basis. The concept of temperature or…

The paper discusses the physical groundlessness of the models used for the derivation of canonical distribution and provides the experimental data demonstrating the incompleteness of quantum mechanics. The possibility of using statistical…

Thermodynamic principles are often deceptively simple and yet surprisingly powerful. We show how a simple rule, such as the net flow of energy in and out of a moving atom under nonequilibrium steady state condition, can expose the…

In this paper, we derive a number of inequalities which express power-efficiency trade-offs that hold generally for thermodynamic machines operating in non-equilibrium stationary states. One of these inequalities concerns the output power,…

The non-extensive statistical mechanics has been used to describe a variety of complex systems. The maximization of entropy, often used to introduce the non-extensive statistical mechanics, is a formal procedure and does not easily leads to…

We set up a rigorous thermodynamic description of reaction-diffusion systems driven out of equilibrium by time-dependent space-distributed chemostats. Building on the assumption of local equilibrium, nonequilibrium thermodynamic potentials…

Traditional derivation of Gibbs canonical distribution and the justification of thermodynamics are based on the assumption concerning an isoenergetic ergodicity of a system of $n$ weakly interacting identical subsystems and passage to the…

Active matter generates order or patterns through nonequilibrium dynamics. An open research challenge is to determine how efficiently a nonequilibrium self-organising system can convert consumed energy into macroscopic order. We study an…

Schr\"odinger suggested that thermodynamical functions cannot be based on the gratuitous allegation that quantum-mechanical levels (typically the orthogonal eigenstates of the Hamiltonian operator) are the only allowed states for a quantum…

A new approach to non-extensive thermodynamical systems with non-additive energy and entropy is proposed. The main idea of the paper is based on the statistical matching of the thermodynamical systems with the additive multi-step Markov…

We show insurmountable contradictions which arise if statistical ensembles are considered a consequence of the influence of the environment of the physical systems. We regard the multiplicity of states with a definite energy value as a…

We develop a method using a coarse graining of the energy fluctuations of an equilibrium quantum system which produces simple parameterizations for the behaviour of the system. As an application, we use these methods to gain more…

We consider a class of mechanical particle systems interacting with thermostats. Particles move freely between collisions with disk-shaped thermostats arranged periodically on the torus. Upon collision, an energy exchange occurs, in which a…

In this chapter, we present a straightforward geometrical argument that in a certain way recalls us the equivalence between the canonical and the microcanonical ensembles in the thermodynamic limit for the particular context of physical…

Quantum decoherence is of primary importance for relaxation to an equilibrium distribution and, accordingly, for equilibrium processes. We demonstrate how coherence breaking implies evolution to a microcanonical distribution…