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The exchange interaction of polaronic carriers with localized spins leads to a ferromagnetic/paramagnetic transition in doped charge-transfer insulators with strong electron-phonon coupling. The relative strength of the exchange and…

强关联电子 · 物理学 2016-08-31 A. S. Alexandrov , A. M. Bratkovsky

We present a numerical treatment of a spin-orbital polaron model for Na_xCoO_2 at small hole concentration (0.7 < x < 1). We demonstrate how the polarons account for the peculiar magnetic properties of this layered compound: They explain…

强关联电子 · 物理学 2007-05-23 M. Daghofer , P. Horsch , G. Khaliullin

The La$_2$CoIr$_{1-x}$Ti$_x$O$_6$ double perovskite series serves as an effective platform for investigating the evolution of magnetic and electronic properties as a function of chemical pressure (doping) or hydrostatic pressure due to the…

Crystal and magnetic structures of the $x=0.2$ member of La$_{\rm 0.8-x}$Tb$_{\rm x}$Ca$_{0.2}$CoO$_3$ perovskite series have been determined from the powder neutron diffraction. Enhancement of the diffraction peaks due to ferromagnetic or…

材料科学 · 物理学 2017-09-26 K. Knížek , Z. Jirák , J. Hejtmánek , M. Veverka , O. Kaman , M. Maryško , E. Šantavá , G. André

The magnetic, electric and thermal properties of the ($Ln_{1-y}$Y$_{y}$)$_{0.7}$Ca$_{0.3}$CoO$_3$ perovskites ($Ln$~=~Pr, Nd) were investigated down to very low temperatures. The main attention was given to a peculiar metal-insulator…

强关联电子 · 物理学 2015-05-18 J. Hejtmánek , E. Šantavá , K. Knížek , M. Maryško , Z. Jirák T. Naito , H. Sasaki , H. Fujishiro

A new excitation is observed at 201 meV in the doped-hole ladder cuprate Sr$_{14}$Cu$_{24}$O$_{41}$, using ultraviolet resonance Raman scattering with incident light at 3.7 eV polarized along the direction of the rungs. The excitation is…

强关联电子 · 物理学 2015-05-18 A. Rusydi , W. Ku , B. Schulz , R. Rauer , I. Mahns , D. Qi , X. Gao , A. T. S. Wee , P. Abbamonte , H. Eisaki , Y. Fujimaki , S. Uchida , M. Ruebhausen

The structure, electronic, and magnetic properties of the Mo-doped perovskite La0.7Ca0.3Mn1-xMoxO3 (x < 0.1) have been studied. A significant increase in resistivity and lattice parameters were observed with Mo doping. A marginal decrease…

强关联电子 · 物理学 2007-05-23 G. Narsinga Rao , J. W. Chen

The structural and magnetic properties of two mixed-valence cobaltites with formal population of 0.30 Co$^{4+}$ ions per f.u., (Pr$_{1-y}$Y$_{y}$)$_{0.7}$Ca$_{0.3}$CoO$_3$ ($y=0$ and 0.15), have been studied down to very low temperatures by…

材料科学 · 物理学 2015-06-17 K. Knizek , J. Hejtmanek , M. Marysko , P. Novak , E. Santava , Z. Jirak , T. Naito , H. Fujishiro , C. R. dela Cruz

Polaronic features similar to those previously observed in the photoinduced spectra of cuprates have been detected in the reflectivity spectra of chemically doped parent compounds of high-critical-temperature superconductors, both $n$-type…

supr-con · 物理学 2009-10-28 P. Calvani , M. Capizzi , S. Lupi , P. Maselli , A. Paolone , P. Roy

We have investigated the electronic and magnetic properties of Co-doped Pr0.8Ca0.2MnO3 thin films using various spectroscopic techniques. X-ray absorption and hard x-ray photoemission spectroscopy revealed that the substituted Co ions are…

Fundamental and harmonic magneto-dielectricity studied for varied perovskite systems-- Pb0.98Gd0.02(Mg1/3Nb2/3)0.995O3 (A-site co-doped PGMN magneto-relaxor), La0.95Ca0.05CoO3 (A-site doped spin-state LCCO), and La2NiMnO6 (double-perovskite…

材料科学 · 物理学 2020-04-22 Pooja Sahlot , Suchita Pandey , Adityanarayan Pandey , A. M. Awasthi

An unusual temperature and concentration behavior of resistivity in $La_{0.7}Ca_{0.3}Mn_{1-x}Cu_xO_3$ has been observed at slight $Cu$ doping ($0\leq x \leq 0.05$). Namely, introduction of copper results in a splitting of the resistivity…

强关联电子 · 物理学 2009-10-31 S. Sergeenkov , M. Ausloos , H. Bougrine , A. Rulmont , R. Cloots

In polarizable materials, electronic charge carriers interact with the surrounding ions, leading to quasiparticle behaviour. The resulting polarons play a central role in many materials properties including electrical transport, optical…

Unrevealing local magnetic and electronic correlations in the vicinity of charge carriers is crucial in order to understand rich physical properties in correlated electron systems. Here, using high-energy optical conductivity (up to 35 eV)…

The iron-based superconductors (IBSs) of the recently discovered 1144 class, unlike many other IBSs, display superconductivity in their stoichiometric form and are intrinsically hole doped. The effects of chemical substitutions with…

The hole-doped manganite La0.7Ca0.3MnO3 and the electron-doped manganite La0.7Ce0.3MnO3 undergo an insulator to metal transition at around 250 K, above which both behave as a polaronic semiconductor. We have successfully fabricated an…

强关联电子 · 物理学 2009-11-07 C. Mitra , P. Raychaudhuri , G. Kobernik , K. Dorr , R. Pinto , K-H. Muller , L. Schultz

Acceptor-doped perovskite oxides like BaZrO$_3$ are showing great potential as materials for renewable energy technologies where hydrogen acts an energy carrier, such as solid oxide fuel cells and hydrogen separation membranes. While ionic…

材料科学 · 物理学 2016-08-24 Anders Lindman , Paul Erhart , Göran Wahnström

Inelastic neutron scattering (INS), electron spin (ESR) and nuclear magnetic resonance (NMR) measurements were employed to establish the origin of the strong magnetic signal in lightly hole-doped La_{1-x}Sr_xCoO_3, x=0.002. Both, INS and…

The effect of doping Mo for Mn on the magnetic and transport properties of the colossal magnetoresistance material, La0.67Ba0.33MnO3, has been studied. Compounds of the series La0.67Ba0.33Mn1-xMoxO3 (x=0.0 to 0.1) have been prepared and…

材料科学 · 物理学 2009-11-11 Darshan C. Kundaliya , Reeta Vij , R. G. Kulkarni , B. Varughese , A. K. Nigam , S. K. Malik

The magnetic moment induced by an external magnetic field of 5.8 T on the Co3+ ions in LaCoO3 has been measured by polarized neutron diffraction. Measurements were made at 100 K, near to the spin-state transition, at 1.5 K and at 285 K. The…

强关联电子 · 物理学 2015-06-25 V. P. Plakhty , P. J. Brown , B. Grenier , S. V. Shiryaev , S. N. Barilo , S. V. Gavrilov , E. Ressouche