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A fully ab initio scheme based on quantum chemical wavefunction methods is used to investigate the correlated multiorbital electronic structure of a 3d-metal compound, LaCoO3. The strong short-range electron correlations, involving both Co…

强关联电子 · 物理学 2009-11-13 L. Hozoi , U. Birkenheuer , H. Stoll , P. Fulde

Halide perovskites are known for their rich phase diagram and superior performance in diverse optoelectronics applications. The latter property is often attributed to the long electron-hole recombination time, whose underlying physical…

Electrical transport of a polar heterointerface between two insulating perovskites, KTaO3 and SrTiO3, is studied. It is formed between a thin KTaO3 film deposited on a top of TiO2- terminated (100) SrTiO3 substrate. The resulting…

材料科学 · 物理学 2007-05-23 A. Kalabukhov , R. Gunnarsson , T. Claeson , D. Winkler

Electron- and hole-doped La$_2$CoMnO$_6$(LCMO) are investigated using first principles DFT calculations. Hole and electron doping are achieved respectively by introducing Sr$^{2+}$ at La$^{3+}$ sites and by inducing O-site vacancies in…

材料科学 · 物理学 2021-09-02 Anasua Khan , Swastika Chatterjee , T. K. Nath , A. Taraphder

The dielectric properties of La$_{1-x}$Sr$_{1+x}$MnO$_4$ single crystals with x = 0, 0.125, 0.25, and 0.5 were studied by means of electron energy-loss spectroscopy as a function of temperature and momentum transfer. A clear signature of…

强关联电子 · 物理学 2015-05-27 R. Kraus , M. Schrade , R. Schuster , M. Knupfer , A. Revcolevschi , B. Büchner , J. Geck

The electronic and magnetic states in doped perovskite cobaltites, (La, Sr)CoO_3, are studied in the numerically exact diagonalization method on Co_2O_{11} clusters. For realistic parameter values, it is shown that a high spin state and an…

强关联电子 · 物理学 2009-10-31 K. Tsutsui , J. Inoue , S. Maekawa

Rare-earth nickelates R$^{3+}$Ni$^{3+}$O$_3$ (R=Lu-Pr, Y) show a striking metal-insulator transition in their bulk phase whose temperature can be tuned by the rare-earth radius. These compounds are also the parent phases of the newly…

材料科学 · 物理学 2021-07-21 Lucia Iglesias , Manuel Bibes , Julien Varignon

Electron and hole trapping was studied in the Ce3+ and Pr3+ doped Lu2Si2O7 scintillation single crystals (LPS:Ce and LPS:Pr) by Electron Paramagnetic Resonance (EPR). Detailed EPR measurements of the X-ray irradiated LPS crystals revealed…

材料科学 · 物理学 2020-04-29 V. Laguta , M. Buryi , Y. Wu , G. Ren , M. Nik

Resistivity under magnetic field, thermopower and Hall coefficient are systematically studied for [Bi$_2$Ba$_{1.3}$K$_{0.6}$Co$_{0.1}$]$^{RS}$[CoO$_2$]$_{1.97}$ single crystal. In-plane resistivity ($\rho_{ab}$(T)) shows metallic behavior…

强关联电子 · 物理学 2015-05-13 X. G. Luo , H. Chen , G. Y. Wang , G. Wu , T. Wu , L. Zhao , X. H. Chen

The evolution of electronic (spin and charge) excitations upon carrier doping is an extremely important issue in superconducting layered cuprates and the knowledge of its asymmetry between electron- and hole-dopings is still fragmentary.…

We present an extensive investigation (magnetic, electric and thermal measurements and X-ray absorption spectroscopy) of the Pr0.5Ca0.5CoO3 and (Pr1-yYy)0.7Ca0.3CoO3 (y=0.0625-0.15) perovskites, in which a peculiar metal-insulator (M-I)…

材料科学 · 物理学 2015-06-12 J. Hejtmanek , Z. Jirak , O. Kaman , K. Knizek , E. Santava , K. Nitta , T. Naito , H. Fujishiro

Low as well as high-temperature electron and x-ray diffraction studies have been carried out on a rare-earth free B-site disordered electron-doped manganite SrMn0.875.Mo0.125O3-{\delta} in the temperature range of 83K to 637K. These studies…

强关联电子 · 物理学 2015-03-23 Aga Shahee , N. P. Lalla

We performed a resonant inelastic X-ray scattering (RIXS) study of La$_{2-x}$Sr$_{x}$NiO$_{4+{\delta}}$ (LSNO) at the oxygen $K$ edge to investigate the nature of the doped holes with regard to charge excitations. Charge excitations of the…

The observed correlation of oxygen vacancies and room temperature ferromagnetic ordering in Co doped ZnO1-o nanoparticles reported earlier (Naeem et al Nanotechnology 17, 2675-2680) has been further explored by transport and optical…

材料科学 · 物理学 2007-12-10 M. Naeem , S. K. Hasanain , A. Mumtaz

The rhodium doping in the LaCo$_{1-x}$Rh$_{x}$O$_3$ perovskite series ($x=0.02-0.5$) has been studied by X-ray diffraction, electric transport and magnetization measurements, complemented by electronic structure GGA+U calculations in…

材料科学 · 物理学 2012-04-04 K. Knížek , J. Hejtmánek , M. Maryško , Z. Jirák , J. Buršík

A review of electronic properties of insulating-, boron- and phosphorus-doped diamond is given. The main goal is, to show data in a wider context, to reveal trends and limitations with respect to carrier mobilities, conductivities, p- and…

材料科学 · 物理学 2020-05-11 Christoph E. Nebel

The electrical resistivity, Hall coefficient, and thermopower as functions of temperature are reported for lightly electron-doped Ca(1-x)La(x)MnO(3)(0 <= x <= 0.10). Unlike the case of hole-doped ferromagnetic manganites, the magnitude and…

强关联电子 · 物理学 2009-11-11 J. L. Cohn , C. Chiorescu , J. J. Neumeier

We have investigated cobaltite relatives of the layered perovskite cuprates and nickelates, Pr$_{2-x}$Ca$_x$CoO$_4$ ($0.39 \leq x \leq 0.73$) and La$_{2-x}$Sr$_x$CoO$_4$ ($x = 0.61$), using elastic neutron scattering. We have discovered…

强关联电子 · 物理学 2010-07-28 N. Sakiyama , I. A. Zaliznyak , S. -H. Lee , Y. Mitsui , H. Yoshizawa

The emergence and the evolution of the metallic charge transport in the La_{2-x}Sr_{x}CuO_{4} system from lightly- to optimally-doped samples (x = 0.01 - 0.17) are studied. We demonstrate that in high-quality single crystals the in-plane…

超导电性 · 物理学 2009-11-07 Yoichi Ando , A. N. Lavrov , Seiki Komiya , Kouji Segawa , X. F. Sun

Measurements of dc magnetization ($M$) and electrical resistivity ($\rho$) have been carried out as a function of temperature ($T$) for layered oxide Li$_{\rm x}$CoO$_2$ (0.51$\leq$$x$$\leq$1.0) using single crystal specimens. After slow…

强关联电子 · 物理学 2018-11-14 Kiyotaka Miyoshi , Kentaro Manami , Ryo Sasai , Shijo Nishigori , Jun Takeuchi