相关论文: EPR and magnetization studies on single crystals o…
Electron paramagnetic resonance (EPR) study of MBE grown Mn doped GaAs is presented. The resolved fine structure allows us to evaluate the crystal field parameters of the spin Hamiltonian. The obtained cubic constant is a= -14.1 10^-4/cm.…
The results of studies of Y$_{2}$Ti$_2$O$_7$ single crystals doped with Er$^{3+}$ and Yb$^{3+}$ ions by means of electron paramagnetic resonance (EPR) and dc-magnetometry are reported. EPR signals of the trigonal centers with the…
A detailed multifrequency high field - high frequency EPR (95-285 GHz) study has been performed on the single-molecule magnet of formula [Fe8O2(OH)12(tacn)6]Br8 9H2O, where tacn=1,4,7-triazacyclononane. Polycrystalline powder spectra have…
The anisotropic magnetic properties of the antiferromagnetic compound CePd$_2$Ge$_2$, crystallizing in the tetragonal crystal structure have been investigated in detail on a single crystal grown by Czochralski method. From the electrical…
A high-frequency (95 GHz) EPR study is reported on single crystals of the planar tetranuclear complex Fe4(OCH3)6(dpm)6 (where Hdpm = dipivaloylmethane), which has been previously shown to present typical single-molecule magnet behaviour.…
Numerical and analytical methods are used to investigate the calculation of the zero field splitting |2D| and g(perp) parameters in EPR for octahedrally surrounded d3 spin systems (S = 3/2) in strong and moderate axial crystal fields…
The temperature dependence of the upper critical field ($H_{c2}$) in RbCr$% _{3}$As$_{3}$ single crystals ($T_{c}\approx $ 7.3 K) has been determined by means of magnetoresistance measurements with temperature down to 0.35 K in static…
Single crystals of $R$Mg$_{2}$Cu$_{9}$ ($R$=Y, Ce-Nd, Gd-Dy, Yb) were grown using a high-temperature solution growth technique and were characterized by measurements of room-temperature x-ray diffraction, temperature-dependent specific heat…
The magnetic behavior of single-crystal Ho$_2$PdSi$_3$, crystallizing in an AlB$_2$-derived hexagonal structure, is investigated by magnetic susceptibility ($\chi$) and electrical resistivity ($\rho$) measurements along two directions.…
EPR studies of a Ni4 single-molecule magnet yield the zero-field-splitting (zfs) parameters, D, B40 and B44, based on a giant spin approximation (GSA) with S = 4. Experiments on an isostructural Ni-doped Zn4 crystal establish the Ni(II) ion…
Single crystals of RPd${_2}$P${_2}$ (R=Y, La-Nd, Sm-Ho, Yb) were grown out of a high temperature solution rich in Pd and P and characterized by room-temperature powder X-ray diffraction, anisotropic temperature- and field-dependent…
W-band ({\nu} ca. 94 GHz) electron paramagnetic resonance (EPR) spectroscopy was used for a single-crystal study of a star-shaped Fe3Cr single-molecule magnet (SMM) with crystallographically imposed trigonal symmetry. The high resolution…
High-field electron paramagnetic resonance (HFEPR) spectra were collected at several frequencies for single crystal [Zn3.91Ni0.09(hmp)4(dmb)4Cl4] (1), where dmb is 3,3-dimethyl-1-butanol and hmp is the monoanion of 2-hydroxymethylpyridine.…
We study the correlated quantum magnet, YbCl$_3$, with neutron scattering, magnetic susceptibility, and heat capacity measurements. The crystal field Hamiltonian is determined through simultaneous refinements of the inelastic neutron…
Magnetic susceptibility, heat capacity, and electrical resistivity measurements have been carried out on single crystals of the intermediate valence compounds Yb2Rh3Ga9 and Yb2Ir3Ga9. These measurements reveal a large anisotropy due…
We have performed high-field magnetization and ESR measurements on Ba$_3$CoSb$_2$O$_9$ single crystals, as a representative two-dimensional spin-1/2 Heisenberg antiferromagnet on a uniform triangular lattice, and have determined all the…
Extensive measurements of the magnetization of superconducting single crystal samples of Ba0.6K0.4BiO3} have been made using SQUID and cantilever force magnetometry at temperatures ranging between 1.3 and 350 K and in magnetic fields from…
Single crystals of $R$Rh$_6$Ge$_4$ ($R$ = Pr, Nd, Sm, Gd - Er) were synthesized using a Bi flux and their physical properties were characterized by magnetization, resistivity, and specific heat measurements. These compounds crystallize in…
We present high-frequency angle-dependent EPR data for crystals of [NixZn1-x(hmp)(t-BuEtOH)Cl]4 (x = 1 and 0.02). The x = 1 complex behaves as a single-molecule magnet at low temperatures, displaying hysteresis and exceptionally fast…
Integrated magnetic sensors that allow simultaneous EPR and magnetization measurements have been developed to study single molecule magnets. A high frequency microstrip resonator has been integrated with a micro-Hall effect magnetometer.…