相关论文: Multipole characteristics of the open-shell electr…
Any electron eigenstate |\Psi>of the paramagnetic ion open-shell is characterized by the three independent multipole asphericities A_{k}=<\Psi || C^(k)}||\Psi> for k=2,4 and 6 related to the second moments of the relevant crystal-field…
The physically correct parametrization of the energy levels of transition ions in crystals in terms of crystal-field (CF) Hamiltonians ${\cal H}_{\rm CF}=\sum_{k}\sum_{q}B_{kq}C_{q}^{(k)}$ has to be based on the CF parameters $B_{kq}$ that…
The relationship between the energy total splitting $\Delta E$ of the free-ion electron states in the axial crystal-fields and the second moment of that splitting $\sigma^{2}$ is thoroughly investigated. The non-Kramers and Kramers states…
A potential function is presented for describing a system of flexible H$_2$O molecules based on the single center multipole expansion (SCME) of the electrostatic interaction. The model, referred to as SCME/f, includes the variation of the…
The electromagnetic multipole moments of the open-flavor $Z_{\bar cq}$ states are investigated by assuming a diquark-antidiquark picture for their internal structure and quantum numbers $J^{PC} = 1^{+-}$ for their spin-parity. In…
The analysis of an angular distribution of the emission intensity of a two-level atom (dipole) in a photonic crystal reveals an enhancement of the emission rate in some observation directions. Such an enhancement is the result of the…
The macroscopic surface electric susceptibility determines the linear optical properties of an insulating single-layer two-dimensional atomic crystal, and can be expressed in terms of the microscopic polarizability of the atoms. We compute…
We discuss the peculiarities of the Seebeck effect in stabilized electrolytes containing the colloidal particles. Its unusual feature is the two-stage character, with the linear increase of differential thermopower as the function of…
The crystal-fields causing $|J>$ electron states splittings of the same second moment $\sigma^{2}$ can produce different total splittings $\Delta E$ magnitudes. Based on the numerical data on crystal-field splittings for the representative…
The heavy-fermion superconductor CeRh2As2 exhibits a non-superconducting phase transition that precedes the emergence of superconductivity. The nature of the corresponding order parameter remains under debate, with competing proposals…
Electric field, uniform within the slab, emerging due to Fermi level pinning at its both sides is analyzed using DFT simulations of the SiC surface slabs of different thickness. It is shown that for thicker slab the field is nonuniform and…
Natural optical activity is the paradigmatic example of an effect originating in the weak spatial inhomogeneity of the electromagnetic field on the atomic scale. In molecules, such effects are well described by the multipole theory of…
The fractional quantum Hall effect (FQHE) realized in two-dimensional electron systems is explained by the emergent composite fermions (CF) out of ordinary electrons. It is possible to write down explicit wavefunctions explaining many if…
Quasiparticle properties are explored in an effective theory of the $t-J$ model which includes two important components: spin-charge separation and unrenormalizable phase shift. We show that the phase shift effect indeed causes the system…
The article demonstrates the nontrivial manifestation of quantum shell effects in a compressed mesoscopic system. It is shown that there are two spatial scales in the distribution of degenerate electrons in a spherical well. The first scale…
Grand canonical Monte Carlo simulation results are reported for an electric double layer modelled by a planar charged hard wall, anisotropic shape cations, and spherical anions at different electrolyte concentrations and asymmetric…
A technique for obtaining efficient bulk second order susceptibility in non centro-symmetric Photonic Crystals (PC) made from centro-symmetric materials is discussed. The effect is based on the electric quadrupole effect, strong…
The existence of macroscopic shell structure of submicron metal clusters is known for several decades. Since the most studies provide theoretical analysis for clusters of spherical shape, the electron density inhomogeneities caused by shell…
A new measure of the crystal-field strength, complementary to the conventional one, is defined. It is based on the rotational invariants |B_{k0}|_{av} or |\sum_{k}B_{k0}|_{av}, k=2,4,6, of the crystal-(ligand)-field (CF) Hamiltonian H_{CF}…
When interacting two-dimensional electrons are placed in a large perpendicular magnetic field, to minimize their energy, they capture an even number of flux quanta and create new particles called composite fermions (CFs). These complex…