相关论文: Nonadiabatic corrections to the wave function and …
We analyse a modified Dirac equation based on a noncommutative structure in phase space. The noncommutative structure induces generalised momenta and contributions to the energy levels of the standard Dirac equation. Using techniques of…
We use the so-called eikonal approximation, recently introduced in the context of cosmological perturbation theory, to compute power spectra for multi-component fluids. We demonstrate that, at any given order in standard perturbation…
We derive an accurate molecular orbital based expression for the coherent time evolution of a two-electron wave function in a quantum dot molecule where the electrons interact with each other, with external time dependent electromagnetic…
For a particular case of three-body scattering in two dimensions, and matching analytical expressions at a transition point, we obtain accurate solutions for the hyperspherical adiabatic basis and potential. We find analytical expressions…
The finite nuclear size correction to the bound-electron g factor in hydrogenlike atoms is investigated in the range Z=1-20. An analytical formula for this correction which includes the non-relativistic and dominant relativistic…
Far-off-resonant pulsed laser fields produce negligible excitation between two atomic states but may induce considerable phase shifts. The acquired phases are usually calculated by using the adiabatic-elimination approximation. We analyze…
We reveal a fundamental geometric structure of momentum space arising from the nonadiabatic evolution of Bloch electrons. By extending semiclassical wave packet theory to incorporate nonadiabatic effects, we introduce a momentum-space…
The quantum electrodynamic Araki-Sucher correction arising from the interaction between electrons and nuclei is calculated for rovibrational energy levels of the hydrogen molecule and its isotopologues. The corresponding expectation value…
For high energy processes ($M\gg \Lambda_{QCD}$) there are infrared safe hadronic shape variables that have a calculable perturbative expansion in $\alpha_s(M^2)$. However, nonperturbative power suppressed corrections to these variables are…
Modern density functional theory (DFT) calculations employ the Kohn-Sham (KS) system of non-interacting electrons as a reference, with all complications buried in the exchange-correlation energy (Exc). The adiabatic connection formula gives…
We investigate a specific set of two-loop self-energy corrections involving squared decay rates and point out that their interpretation is highly problematic. The corrections cannot be interpreted as radiative energy shifts in the usual…
Adiabatic approximations are a powerful tool for simplifying nonlinear quantum dynamics, and are applicable whenever a system exhibits a hierarchy of time scales. Current interest in small nonlinear quantum systems, such as few-mode…
In this paper, we discuss the compatibility between the rotating-wave and the adiabatic approximations for controlled quantum systems. Although the paper focuses on applications to two-level quantum systems, the main results apply in higher…
We study the adiabatic limit in the density matrix approach for a quantum system coupled to a weakly dissipative medium. The energy spectrum of the quantum model is supposed to be non-degenerate. In the absence of dissipation, the geometric…
Several misprints and small mistakes were in the initial version. They have been corrected. Following the recent experimental realization of synthetic gauge magnetic forces, Jean Dalibard adressed the question whether the adiabatic ansatz…
We restate the adiabatic elimination approximation as the first term in a singular perturbation expansion. We use the invariant manifold formalism for singular perturbations in dynamical systems to identify systematic improvements on…
Recently, we have demonstrated that the problems finding a suitable adiabatic approximation in time-dependent one-body reduced density matrix functional theory can be remedied by introducing an additional degree of freedom to describe the…
In coupled cluster methods, the electronic states are biorthonormal in the sense that the left states are orthonormal to the right states. Here we present an extension of this formalism to a left and right total molecular wave function.…
We substantiate the need for account of the proper electromagnetic field of the electron in the canonical problem of hydrogen in relativistic quantum mechanics. From mathematical viewpoint, the goal is equivalent to determination of the…
We study the gas-surface dynamics of O2 at Ag(111) with the particular objective to unravel whether electronic non-adiabatic effects are contributing to the experimentally established inertness of the surface with respect to oxygen uptake.…