高分辨率二维电子光谱揭示孤立纳米颗粒中的均匀线型
化学物理
2022-06-14 v5
摘要
气相掺杂团簇为研究系统-环境相互作用提供了纳米限域的模型体系。为深入理解发色团与其环境间的相互作用机制，必须消除系综非均匀性并获取均匀线型。然而，在团簇束实验中，此类测量在低粒子密度与低信号水平下极具挑战。本文中，我们用酞菁分子掺杂低温稀有气体团簇，并应用作用探测二维电子光谱，以洞察固态与超流团簇物种的局部分子-团簇环境。高分辨率均匀线宽分析为结合构型的理论建模提供了基准，并展示了高分辨率分子二维光谱的一条可行路径。
引用
@article{arxiv.2112.05418,
title = {High-resolution two-dimensional electronic spectroscopy reveals homogeneous line profiles in isolated nanoparticles},
author = {Ulrich Bangert and Frank Stienkemeier and Lukas Bruder},
journal= {arXiv preprint arXiv:2112.05418},
year = {2022}
}
备注
Supplementary Inforamtion attached. Version 2 has not undergone peer review or any post-submission improvements or corrections. Version 4 of the article has been accepted for publication, after peer review but is not the Version of Record and does not reflect post-acceptance improvements, or any corrections