扩散控制的三分子(催化)反应的表观速率常数
凝聚态物理
2009-10-28 v2
摘要
我们给出了三分子反应的表观反应速率常数的简单显式估计,这些反应在催化中很重要。对于小浓度和 ,表观反应速率常数仅取决于扩散系数和粒子的大小。对于小浓度和 ,它也是时间依赖的。对于大浓度,它获得了对浓度的依赖性。
引用
@article{arxiv.cond-mat/9607071,
title = {Apparent Rate Constant for Diffusion-Controlled Three molecular (catalytic) reaction},
author = {S. F. Burlatsky and M. Moreau},
journal= {arXiv preprint arXiv:cond-mat/9607071},
year = {2009}
}
备注
12 pages, LaTeX, Revised: missing ref. for important paper by G. Oshanin and A. Blumen was added and minor misprints corrected