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We report the magnetic characterization of the frustrated transition metal pyrochlore NaCaCo$_2$F$_7$. This material has high spin Co$^{2+}$ in CoF$_6$ octahedra in a pyrochlore lattice, and disordered non-magnetic Na and Ca on the…

Materials Science · Physics 2015-06-19 J. W. Krizan , R. J. Cava

The pyrochlore material Yb2Ti2O7 displays unexpected quasi-two-dimensional (2D) magnetic correlations within a cubic lattice environment at low temperatures, before entering an exotic disordered ground state below T=265mK. We report neutron…

Strongly Correlated Electrons · Physics 2012-02-13 K. A. Ross , L. R. Yaraskavitch , M. Laver , J. S. Gardner , J. A. Quilliam , S. Meng , J. B. Kycia , D. K. Singh , H. A. Dabkowska , B. D. Gaulin

We report a resonant inelastic X-ray scattering study on a single crystal of a non-stoichiometric pyrochlore iridate Tb$_{2+x}$Ir$_{2-x}$O$_{7-y}$ ($x \simeq 0.25$) that magnetically orders at $T_{\rm{N}}\simeq 50$ K. We find that the…

Strongly Correlated Electrons · Physics 2024-09-18 Q. Faure , A. Toschi , J. R. Soh , E. Lhotel , B. Detlefs , D. Prabhakaran , D. F. McMorrow , C. J. Sahle

Geometrical frustration and spin-orbit coupling effect together play vital role to influence properties in pyrochlore based iridium oxides. Here we have investigated detailed structural, magnetic, thermodynamic and transport properties of…

Strongly Correlated Electrons · Physics 2017-02-06 Harish Kumar , A. K. Pramanik

Neutron scattering has been used to study the magnetic order and spin dynamics of the colossal magnetoresistive pyrochlore Tl_2Mn_2O_7. On cooling from the paramagnetic state, magnetic correlations develop and appear to diverge at T_C (123…

Strongly Correlated Electrons · Physics 2009-10-31 J. W. Lynn , L. Vasiliu-Doloc , M. A. Subramanian

The recent discoveries of proximate quantum spin-liquid compounds and their potential application in quantum computing informs the search for new candidate materials for quantum spin-ice and spin-liquid physics. While the majority of such…

Strongly Correlated Electrons · Physics 2019-01-16 K. M. Taddei , L. Sanjeewa , J. W. Kolis , A. S. Sefat , C. de la Cruz , D. M. Pajerowski

Geometric frustration inhibits magnetic systems from ordering, opening a window to unconventional phases of matter. The paradigmatic frustrated lattice in three dimensions to host a spin liquid is the pyrochlore, although there remain few…

We report the crystal structures, magnetic and thermodynamic properties of two magnetically frustrated $A$'$A$"$M_2$F$_7$-type antiferromagnets, NaCdNi$_2$F$_7$ and NaCdMn$_2$F$_7$. While NaCdNi$_2$F$_7$ forms a stable pyrochlore structure…

Strongly Correlated Electrons · Physics 2025-04-10 Andrej Kancko , Cinthia Antunes Corrêa , Ross Harvey Colman

We report the crystal growth, crystal structure and basic magnetic properties of a new cobalt-based pyrochlore, NaSrCo$_2$F$_7$. Na and Sr are completely disordered on the non-magnetic large atom A sites, while magnetic S=3/2 Co$^{2+}$…

Materials Science · Physics 2015-03-13 J. W. Krizan , R. J. Cava

Examples of materials where an "order by disorder" mechanism is at play to select a particular ground state are scarce. It has recently been proposed, however, that the antiferromagnetic XY pyrochlore Er2Ti2O7, reveals a most convincing…

Strongly Correlated Electrons · Physics 2015-06-23 S. Petit , J. Robert , S. Guitteny , P. Bonville , C. Decorse , J. Ollivier , H. Mutka , M. J. P. Gingras , I. Mirebeau

A new fcc oxygen defect pyrochlore structure system Lu2V2O_{7-x} with x = 0.40 to 0.65 was synthesized from the known fcc ferromagnetic semiconductor pyrochlore compound Lu2V2O7 which can be written as Lu2V2O6O' with two inequivalent oxygen…

Strongly Correlated Electrons · Physics 2010-11-12 G. T. Knoke , A. Niazi , J. M. Hill , D. C. Johnston

The ytterbium pyrochlore magnets, Yb2B2O7 (B = Sn, Ti, Ge) are well described by S_eff = 1/2 quantum spins decorating a network of corner-sharing tetrahedra and interacting via anisotropic exchange. Structurally, only the non-magnetic…

Strongly Correlated Electrons · Physics 2016-03-30 A. M. Hallas , J. Gaudet , N. P. Butch , M. Tachibana , R. S. Freitas , G. M. Luke , C. R. Wiebe , B. D. Gaulin

We make the first report that a metallic pyrochlore oxide \Cd2Re2O7, exhibits type II superconductivity at 1.1 K. The pyrochlore oxide is known to be a geometrical frustrated system, which includes the tetrahedral network of magnetic ions.…

Strongly Correlated Electrons · Physics 2016-08-16 H. Sakai , K. Yoshimura , H. Ohno , H. Kato , S. Kambe , R. E. Walstedt , T. D. Matsuda , Y. Haga , Y. Ōnuki

An adiabatic demagnetization process is studied in Gd2Ti2O7, a geometrically frustrated antiferromagnet on a pyrochlore lattice. In contrast to conventional paramagnetic salts, this compound can exhibit a temperature decrease by a factor of…

Strongly Correlated Electrons · Physics 2007-05-23 S. S. Sosin , L. A. Prozorova , A. I. Smirnov , A. I. Golov , I. B. Berkutov , O. A. Petrenko , G. Balakrishnan , M. E. Zhitomirsky

In frustrated magnetic systems, geometric constraints or the competition amongst interactions introduce extremely high degeneracy and prevent the system from readily selecting a low-temperature ground state. The most frustrated known spin…

Strongly Correlated Electrons · Physics 2016-11-23 Darren C. Peets , Hasung Sim , Maxim Avdeev , Je-Geun Park

Non-Fermi liquid behavior in some fermionic systems have attracted significant interest in last few decades. Certain pyrochlore iridates with stronger spin-orbit coupling strength have recently been added to the list. Here, we provide…

Strongly Correlated Electrons · Physics 2022-01-03 Md Salman Khan , Ilaria Carlomagno , Carlo Meneghini , P. K. Biswas , Fabrice Bert , Subham Majumdar , Sugata Ray

We present high-resolution single crystal time-of-flight neutron scattering measurements on the candidate quantum spin liquid pyrochlore Tb2Ti2O7 at low temperature and in a magnetic field. At ~70 mK and in zero field, Tb2Ti2O7 reveals…

Strongly Correlated Electrons · Physics 2013-04-16 K. Fritsch , K. A. Ross , Y. Qiu , J. R. D. Copley , T. Guidi , R. I. Bewley , H. A. Dabkowska , B. D. Gaulin

Effect of structural disorder is investigated for an $XY$ pyrochlore antiferromagnet with continuous degeneracy of classical ground states. Two types of disorder, vacancies and weakly fluctuating exchange bonds, lift degeneracy selecting…

Strongly Correlated Electrons · Physics 2014-09-26 V. S. Maryasin , M. E. Zhitomirsky

Cd2Os2O7 shows a peculiar metal-insulator transition at 227 K with magnetic ordering in a frustrated pyrochlore lattice, but its magnetic structure in the ordered state and the transition origin are yet uncovered. We observed a commensurate…

Strongly Correlated Electrons · Physics 2012-06-20 J. Yamaura , K. Ohgushi , H. Ohsumi , T. Hasegawa , I. Yamauchi , K. Sugimoto , S. Takeshita , A. Tokuda , M. Takata , M. Udagawa , M. Takigawa , H. Harima , T. Arima , Z. Hiroi

Geometrical frustration, as in pyrochlore lattices made of corner-sharing tetrahedra, precludes the onset of conventional magnetic ordering, enabling the stabilization of fluctuating spin states at low temperature. Disorder is a subtle…

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