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The Tb$_2$Ti$_2$O$_7$ pyrochlore magnetic material is attracting much attention for its {\em spin liquid} state, failing to develop long range order down to 50 mK despite a Curie-Weiss temperature $\theta_{\rm CW} \sim -14$ K. In this paper…

Statistical Mechanics · Physics 2007-05-23 Hamid R. Molavian , Michel J. P. Gingras , Benjamin Canals

We have identified TbOF as a unique frustrated and mixed-anion lattice, hosting unconventional magnetism. By means of magnetization, specific heat and neutron diffraction measurements down to 90 mK, as well as DFT calculations, we present a…

Neutron scattering measurements show the ferromagnetic XY pyrochlore Yb2Ti2O7 to display strong quasi-two dimensional (2D) spin correlations at low temperature, which give way to long range order (LRO) under the application of modest…

Strongly Correlated Electrons · Physics 2010-02-08 K. A. Ross , J. P. C. Ruff , C. P. Adams , J. S. Gardner , H. A. Dabkowska , Y. Qiu , J. R. D. Copley , B. D. Gaulin

In a recent letter [Phys. Rev. Lett. {\bf 82}, 1012 (1999)] it was found that the Tb$^{3+}$ magnetic moments in the Tb$_2$Ti$_2$O$_7$ pyrochlore lattice of corner-sharing tetrahedra remain in a {\it collective paramagnetic} state down to…

Disordered Systems and Neural Networks · Physics 2009-10-31 M. J. P. Gingras , B. C. den Hertog , M. Faucher , J. S. Gardner , L. J. Chang , B. D. Gaulin , N. P. Raju , J. E. Greedan

We report the synthesis and structural study of mixed oxides in the Ln2ScNbO7 series. New phases with Ln = Pr, Eu, Gd and Dy are obtained. All crystallize in the cubic pyrochlore structure type, space group F-d3m, with no Sc-Nb ordering on…

Materials Science · Physics 2008-12-16 Siwar Zouari , Rafik Ballou , Abdelwaheb Cheikh-Rouhou , Pierre Strobel

The spin ice system Dy$_{2}$Ti$_{2}$O$_{7}$ exhibits strong frequency-dependent spin-freezing at $\sim$ 16 K temperature. Although it has been a matter of discussion for years, the origin of this unusual spin freezing is still unknown. The…

Strongly Correlated Electrons · Physics 2022-04-06 Sheetal , C. S. Yadav

In this work we present a new chemical route to synthesize Tm2Mn2O7 pyrochlore, a compound which is thermodynamically unstable at ambient pressure. Differently from the reported in the past high pressure synthesis of the same compound…

The charge ordered structure of ions and vacancies characterizing rare-earth pyrochlore oxides serves as a model for the study of geometrically frustrated magnetism. The organization of magnetic ions into networks of corner-sharing…

Below $T_N = 1.1$K, the XY pyrochlore Er$_2$Ti$_2$O$_7$ orders into a $k=0$ non-collinear, antiferromagnetic structure referred to as the $\psi_2$ state. The magnetic order in Er$_2$Ti$_2$O$_7$ is known to obey conventional three…

Pyrochlore erbium titanate samples in the form of powders (with nominal compositions of Er2Ti2+xO7) and bulk single crystals were prepared to elucidate the effect of synthesis and growth conditions on their composition, structure, and…

Materials Science · Physics 2018-12-14 Q. Wang , A. Ghasemi , A. Scheie , S. M. Koohpayeh

We report an analysis of neutron diffraction from single crystals of the spin-liquid pyrochlore Tb2Ti2O7 under the application of magnetic fields along the crystallographic $[110]$ direction. Such a perturbation has been shown to destroy…

Strongly Correlated Electrons · Physics 2009-11-17 J. P. C. Ruff , B. D. Gaulin , K. C. Rule , J. S. Gardner

A2Ir2O7 iridates were proven to crystallise in the geometrically frustrated pyrochlore structure, which remains stable upon rare-earth cation substitution, temperature variation, and external pressure application. However, the change of…

Strongly Correlated Electrons · Physics 2024-08-05 Daniel Staško , Petr Proschek , Jiří Prchal , Milan Klicpera

Dy2Ti2O7 is a geometrically frustrated magnetic material with a strongly correlated spin ice regime that extends from 1 K down to as low as 60 mK. The diffuse elastic neutron scattering intensities in the spin ice regime can be remarkably…

Statistical Mechanics · Physics 2008-08-02 Taras Yavors'kii , Tom Fennell , Michel J. P. Gingras , Steven T. Bramwell

Pyrochlore dielectric materials such as (Bi$_{1.5}$Zn$_{0.5}$)(Nb$_{1.5}$Zn$_{0.5}$)O$_7$ (BZN) have generated interest because they combine high dielectric constants with small dielectric loss tangents and yet are cubic at all…

Materials Science · Physics 2007-05-23 Ram Seshadri

The lanthanide pyrochlore oxides Ln$_2$B$_2$O$_7$ are one of the most intensely studied classes of materials within condensed matter physics, firmly centered as one of the pillars of frustrated magnetism. The extensive chemical diversity of…

Strongly Correlated Electrons · Physics 2022-11-02 Brenden R. Ortiz , Paul M. Sarte , Ganesh Pokharel , Michael Garcia , Marcos Marmolejo , Stephen D. Wilson

We investigate displacive short-range order in pyrochlore Y2Nb2O7, which exhibits a nonmagnetic insulating state despite the presence of formally tetravalent Nb4+ (S = 1/2) ions on the pyrochlore network. Synchrotron x-ray diffraction on a…

Strongly Correlated Electrons · Physics 2026-05-22 Shota Nishida , Shunsuke Kitou , Shingo Toyoda , Yuiga Nakamura , Yusuke Tokunaga , Taka-hisa Arima

Muon spin rotation and relaxation experiments in the pyrochlore iridate Eu2Ir2O7 yield a well-defined muon spin precession frequency below the metal-insulator/antiferromagnetic transition temperature TM = 120 K, indicative of long-range…

Strongly Correlated Electrons · Physics 2015-03-19 Songrui Zhao. J. M. Mackie , D. E. MacLaughlin , O. O. Bernal , J. J. Ishikawa , Y. Ohta , S. Nakatsuji

Gd2GaSbO7 and Gd2InSbO7 pyrochlore compounds exhibit quantum fluctuations in a spin ice-like state. These compounds have not been adequately studied based on the concept of magnetic frustration. Here, we have synthesised and characterised…

Strongly Correlated Electrons · Physics 2024-08-06 S. Nallamuthu , Andrea Dzubinska , K. Arun , Vimaljith A. R , Marian Reiffers , R. Nagalakshmi , Ivan Curlik , Sergej Ilkovic

Tuning of spin-orbit coupling and electron correlation effects in pyrochlore iridates is considered for many interesting phenomena. We have investigated the temperature evolution of structural, magnetic and electronic properties in doped…

Strongly Correlated Electrons · Physics 2019-05-07 Harish Kumar , A. K. Pramanik

There are reasons to believe that the ground state of the magnetic rare earth pyrochlore Yb$_2$Ti$_2$O$_7$ is on the boundary between competing ground states. We have carried out $\mathrm{\textit{ab initio}}$ density functional calculations…

Strongly Correlated Electrons · Physics 2018-06-20 Soham S. Ghosh , Efstratios Manousakis