相关论文: A comparison between algebraic models of molecular…

The highly excited stretching vibrational energy levels and the intensities of infrared transitions in tetrahedral molecules are studied in a U(2) algebraic model. Its applications to silane and silicon tetrafluoride are presented with…

We present an extension of the Hamiltonian of the two dimensional limit of the vibron model encompassing all possible interactions up to four-body operators. We apply this Hamiltonian to the modeling of the experimental bending spectrum of…

Vibrational spectroscopy is a cornerstone technique for molecular characterization and offers an ideal target for the computational investigation of molecular materials. Building on previous comprehensive assessments of efficient methods…

We give a new reduction of a general diatomic molecular Hamiltonian, without modifying it near the collision set of nuclei. The resulting effective Hamiltonian is the sum of a smooth semiclassical pseudodifferential operator (the…

The Algebraic Cluster Model(ACM) is an interacting boson model that gives the relative motion of the cluster configurations in which all vibrational and rotational degrees of freedom are present from the outset. We schemed a solvable…

Algebraic contraction is proposed to realize mappings between models Hamiltonians. This transformation contracts the algebra of the degrees of freedom underlying the Hamiltonian. The rigorous mapping between the anisotropic $XXZ$ Heisenberg…

An algebraic model taking into account the influence of the molecular rotation on the wave functions of vibrational-rotational states of the diatomic molecule using the formalism of the ladder operators and an expansion in a small parameter…

In this work, we present a linear optical implementation for analog quantum simulation of molecular vibronic spectra, incorporating the non-Condon scattering operation with a quadratically small truncation error. Thus far, analog and…

We use a light cone harmonic oscillator model to study S wave meson spectra, namely the pseudoscalar and vector mesons. The model Hamiltonian is a mass squared operator consisting of a central potential (a harmonic oscillator potential)…

Methyl benzoate (MB) is studied as a model compound for the development of new IR pulse schemes with possible applicability to biomolecules. Anharmonic vibrational modes of MB are calculated on different level (MP2, SCS, CCSD(T) with…

With advanced fabrication techniques it is possible to make nanoscale electronic structures that have discrete energy levels. Such structures are called artificial atoms because of analogy with true atoms. Examples of such atoms are quantum…

We present a novel algebraic framework for computing hadron properties directly within the contact interaction model. Utilizing Fierz transformations, the method recasts the Bethe-Salpeter dynamics into equations for a minimal set of…

A new Hamiltonian model is introduced to study the spectrum of light hadrons. It combines relativistic field theory with elements of the constituent quark model. In addition to the standard linear confining and pseudoscalar meson exchange…

In this work we identify coherent electron-vibron interactions between near-resonant and non-resonant electronic levels that contribute beyond standard optomechanical models for off-resonant or resonance SERS. By developing an open-system…

We present a general, numerically motivated approach to the construction of symmetry adapted basis functions for solving ro-vibrational Schr\"{o}dinger equations. The approach is based on the property of the Hamiltonian operator to commute…

Explicit algebraic expressions for the expansion of the vibrational matrix elements in series of matrix elements on the wave functions of the ground vibrational state have been obtained for arbitrary sufficiently differentiable functions of…

We show that the recently developed {\it pseudoparticle operator algebra} which generates the low-energy Hamiltonian eigenstates of multicomponent integrable systems also provides a natural operator representation for the the Virasoro…

We extract the dynamics implicit in an algebraic fitted model Hamiltonian for the deuterium chromophore's vibrational motion in the molecule CDBrClF. The original model has 4 degrees of freedom, three positions and one representing…

The symmetries play important roles in physical systems. We study the symmetries of a Hamiltonian system by investigating the asymmetry of the Hamiltonian with respect to certain algebras. We define the asymmetry of an operator with respect…

We consider a one-dimensional optical lattice of three-dimensional Harmonic Oscillators which are loaded with neutral fermionic atoms trapped into two hyperfine states. By means of a standard variational coherent-state procedure, we derive…