相关论文: Some Remarks About Extremum Principles Involving t…
We generalize to non equilibrium states Onsager's minimum dissipation principle. We also interpret this principle and some previous results in terms of optimal control theory. Entropy production plays the role of the cost necessary to drive…
The Minimum Rate of Dissipation Principle (MRDP) affirms that, for time-independent boundary conditions, a thermodynamic system evolves towards a steady-state with the least possible dissipation. In this note, examples of diffusion…
This study examines a new formulation of non-equilibrium thermodynamics, which gives a conditional derivation of the ``maximum entropy production'' (MEP) principle for flow and/or chemical reaction systems at steady state. The analysis uses…
The selection of an equilibrium state by maximising the entropy of a system, subject to certain constraints, is often powerfully motivated as an exercise in logical inference, a procedure where conclusions are reached on the basis of…
It is shown that Onsager's principle of the least dissipation of energy is equivalent to the maximum entropy production principle. It is known that solutions of the linearized Boltzmann equation make extrema of entropy production. It is…
A theory to predict the steady state position of a dissipative, flow-controlled system, as defined by a control volume, is developed based on the Maximum Entropy (MaxEnt) principle of Jaynes, involving minimisation of a generalised free…
The Boltzmann distribution connects the energetics of an equilibrium system with its statistical properties, and it is desirable to have a similar principle for non-equilibrium systems. Here, we derive a variational principle for the…
The phase space contraction and the entropy production rates of Hamiltonian systems in an external field, thermostatted to obtain a stationary state are considered. While for stationary states with a constant kinetic energy the two rates…
In an essential and quite general setup, based on networks, we identify Schnakenberg's observables as the constraints that prevent a system from relaxing to equilibrium, showing that, in the linear regime, steady states satisfy a minimum…
Entropy production rate (EPR) is often effective to describe how a structure is self-organized in a nonequilibrium thermodynamic system. The "minimum EPR principle" is widely applicable to characterizing self-organized structures, but is…
The minimum entropy production principle provides an approximative variational characterization of close-to-equilibrium stationary states, both for macroscopic systems and for stochastic models. Analyzing the fluctuations of the empirical…
We study the thermodynamics of open systems weakly driven out-of-equilibrium by nonconservative and time-dependent forces using the linear regime of stochastic thermodynamics. We make use of conservation laws to identify the potential and…
A solidification model based on the principle of maximum entropy production rate (MEPR) is considered for the study of pure metals. The approach leads to the development of a breakdown criterion which is able to account for the…
In the last few decades, some hypotheses for entropy production (EP) principles have been forwarded as possible candidates for organizational principles in non-linear non- equilibrium systems. Two important hypotheses will be studied: the…
In this article a classification of some proposed macroscopic entropy production (MEP) principles is given. With the help of simple electrical network models, at least six interesting and most used principles are distinguished: the least…
In a recent paper, Phys. Rev E 81, 041137 (2010), the author attempts to derive ten necessary conditions for stability of dissipative fluids and plasmas. Assuming the validity of the local equilibrium principle, these criteria have been…
In nature stationary nonequilibrium systems cannot exist on their own, rather they need to be driven from outside in order to keep them away from equilibrium. While the internal mean entropy of such stationary systems is constant, the…
The entropy production rate is a key quantity in irreversible thermodynamics. In this work, we concentrate on the realization of entropy production rate in chemical reaction systems in terms of the experimentally measurable reaction rate.…
Many have speculated whether nonequilibrium systems obey principles of maximum or minimum entropy production. In this work, we use stochastic thermodynamics to derive the condition for the minimum entropy production state (MEPS) for…
Far-from-equilibrium thermodynamics underpins the emergence of life, but how has been a long-outstanding puzzle. Best candidate theories based on the maximum entropy production principle could not be unequivocally proven, in part due to…