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The melanin is a group of biological pigments commonly found in living beings, it can be classified in three groups: eumelanin human beings, pheomelanins in animals, and allomelanins in the vegetal kingdom. There is a special interest in…
The melanins are a ubiquitous class of pigments found throughout nature from lower organisms to humans. It is one of the few biopolymers with fascinating functions in biology, medicine, chemistry, physics and engineering due to its relation…
We discuss recent progress towards the establishment of important structure-property-function relationships in eumelanins - key functional bio-macromolecular systems responsible for photo-protection and immune response in humans, and…
We report the results of an experimental and theoretical study of the electronic and structural properties of a key eumelanin precursor - 5,6,-dihydroxyindole-2-carboxylic acid (DHICA) and its dimeric forms. We have used optical…
Eumelanin is regarded to be an attractive candidate material for biomedical applications. Despite many theoretical studies exploring the structure of eumelanin, an exact mapping of the energetic landscape of the very large phase space of…
This study investigates optical and electrical properties of thin melanin films self-organized grown from water solutions of eumelanin extracted from edible plants. The melanin films exhibit the characteristics of a transparent low…
Melanin is a ubiquitous natural pigment that exhibits broadband absorption and high refractive index. Despite its widespread use in structural color production, how the absorbing material, melanin, affects the generated color is unknown.…
Recognition of iris based on Visible Light (VL) imaging is a difficult problem because of the light reflection from the cornea. Nonetheless, pigment melanin provides a rich feature source in VL, unavailable in Near-Infrared (NIR) imaging.…
Recent synthetic studies on the organic molecules tetracene and pentacene have found certain dimers and oligomers to exhibit an intense absorption in the visible region of the spectrum which is not present in the monomer or many…
We report first principles density functional calculations for hydroquinone (HQ), indolequinone (IQ) and semiquinone (SQ). These molecules are believed to be the basic building blocks of the eumelanins, a class of bio-macromolecules with…
Melanosomes are organelles found in a wide variety of tissues throughout the animal kingdom. They contain a variety of biological molecules, but the dominant constituent is the pigment melanin, and many functions ascribed to melanosomes,…
Structural colors are a result of the scattering of certain frequencies of the incident light on micro- or nanoscale features in a material. This is a quite different phenomenon from that of colors produced by absorption of different…
This work presents conclusive observations about the long lasting topic of eumelanins' electronic vs. ionic conduction, allowing to access unprecedented conductivity of this mammal pigment. Key strengths of the study include, the easy…
We present results from the theoretical INDO calculations of the electronic structure for stacked eumelanins' monomers. As basic indolic components of the eumelanin structure 5,6-dihydroxyindole (DHI or HQ) and its oxidized forms (SQ and…
The spontaneous oxidation of dopamine in slightly alkaline solutions was investigated on the basis of the work of Lee and others [Science, 318:426-430, 2007], and the reaction product was identified as dopamine-melanin. The ability of…
Infrared spectroscopy is the technique of choice for chemical identification of biomolecules through their vibrational fingerprints. However, infrared light interacts poorly with nanometric size molecules. Here, we exploit the unique…
We report methods for correcting the photoluminescence emission and excitation spectra of highly absorbing samples for re-absorption and inner filter effects. We derive the general form of the correction, and investigate various methods for…
Lamina-associated domains (LADs) cover a large part of the human genome and are thought to play a major role in shaping the nuclear architectural landscape. Here, we perform polymer simulations, microscopy and mass spectrometry to dissect…
Decomposition of skin pigment plays an important role in medical fields. Human skin can be decomposed into two primitive components, hemoglobin and melanin. It is our goal to apply these results for diagnosis of skin cancer. In this paper,…
Melanins are promising materials for organic bioelectronics devices like transistors, sensors and batteries. However, in general, melanin either natural or synthetic has low solubility in most solvents. In this study, the chemical…