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Porous electrodes are widely used in electrochemical systems, where accurately determining electric potentials, particularly overpotentials, is essential for understanding electrode behavior. At the macroscopic scale, porous electrodes are…

数值分析 · 数学 2026-03-03 Yuhe Wang , Min Wang , Zhihang Xu

The direct ring coupled-cluster doubles (drCCD)-based random phase approximation (RPA) has provided an attractive framework for the development and application of RPA-related methods. However, a potential unphysical solution issue recently…

化学物理 · 物理学 2025-08-18 Ruiheng Song , Xiliang Gong , Hong-Zhou Ye

Unitary Coupled Cluster (UCC) theory is a promising variational method for electronic structure calculations, especially for strongly correlated systems and quantum computers. However, its practical application is limited by the steep…

化学物理 · 物理学 2026-02-05 Prateek Vaish , Brenda Rubenstein

A relativistic version of the coupled-cluster single-double (CCSD) method is developed for atoms with a single valence electron. In earlier work, a linearized version of the CCSD method (with extensions to include a dominant class of triple…

原子物理 · 物理学 2009-11-13 Rupsi Pal , M. S. Safronova , W. R. Johnson , Andrei Derevianko , Sergey G. Porsev

Explicit solutions for one completely-integrable system of Calogero-Moser type in external fields are found in case of three and four interacting particles. Relation between coupling constant, initial values of coordinates and time of…

高能物理 - 理论 · 物理学 2007-05-23 D. V. Meshcheryakov , T. D. Meshcheryakova

Coupled-cluster theory with single and double excitations (CCSD) is a promising ab initio method for the electronic structure of three-dimensional metals, for which second-order perturbation theory (MP2) diverges in the thermodynamic limit.…

材料科学 · 物理学 2021-06-16 James M. Callahan , Malte F. Lange , Timothy C. Berkelbach

Point polarizable molecules at fixed spatial positions have solvable electrostatic properties in classical approximation, the most familiar being the Clausius-Mossotti (CM) formula. This paper generalizes the model and imagines various…

材料科学 · 物理学 2009-11-10 Philip B. Allen

Recently developed pair coupled cluster doubles (pCCD) theory successfully reproduces doubly occupied configuration interaction (DOCI) with mean field cost. However, the projective nature of pCCD makes the method non-variational and thus…

化学物理 · 物理学 2016-08-19 Luning Zhao , Eric Neuscamman

We have studied electron correlations in the doped two-dimensional (2D) Hubbard model by using the coupled-cluster method (CCM) to investigate whether or not the method can be applied to correct the independent particle approximations…

强关联电子 · 物理学 2009-10-31 Yoshihiro Asai , Hideki Katagiri

Nano- to micro-sized particles with differently charged surface areas exhibit complex interaction patterns, characterized by both opposite-charge attraction and like-charge repulsion. While several successful models have been proposed in…

软凝聚态物质 · 物理学 2025-01-16 Daniele Notarmuzi , Silvano Ferrari , Emanuele Locatelli , Emanuela Bianchi

In the molecular quantum chemistry community, coupled-cluster (CC) methods are well-recognized for their systematic convergence and reliability. The extension of the theory to extended systems has been comparably recent, so that…

化学物理 · 物理学 2024-10-31 Andreas Grüneis , Evgeny Moerman , Matthias Scheffler , Tonghao Shen , Igor Ying Zhang

We combine the electron attachment (EA) and ionization potential (IP) equation-of-motion (EOM) coupled-cluster (CC) approaches with the CC($P$;$Q$) formalism. The resulting methodologies are used to describe the electronic states of several…

化学物理 · 物理学 2025-09-19 Karthik Gururangan , Stephen H. Yuwono , A. Eugene DePrince , Piotr Piecuch

The Coupled Cluster (CC) method is used to compute the electronic correlation energy in atoms and molecules and often leads to highly accurate results. However, due to its single-reference nature, standard CC in its projected form fails to…

Recent progress in the numerical solution of the nuclear many-body problem and in the development of nuclear Hamiltonians rooted in Quantum Chromodynamics, has opened the door to first-principle computations of nuclear reactions. In this…

核理论 · 物理学 2020-07-24 J. Rotureau

In single-reference coupled-cluster (CC) methods, one has to solve a set of non-linear polynomial equations in order to determine the so-called amplitudes which are then used to compute the energy and other properties. Although it is of…

化学物理 · 物理学 2021-09-10 Antoine Marie , Fábris Kossoski , Pierre-François Loos

Sufficiently dense intrinsically out-of-equilibrium suspensions, such as those observed in biological systems, can be modelled as active fluids characterised by their orientational symmetry. While mesoscale numerical approaches to active…

软凝聚态物质 · 物理学 2025-01-10 Oleksandr Baziei , Benjamín Loewe , Tyler N. Shendruk

The relative energies of different phases or polymorphs of molecular solids can be small, less than a kiloJoule/mol. Reliable description of such energy differences requires high quality treatment of electron correlations, typically beyond…

化学物理 · 物理学 2024-02-19 Khanh Ngoc Pham , Marcin Modrzejewski , Jiří Klimeš

An implementation of coupled-cluster (CC) theory to treat atoms and molecules in finite magnetic fields is presented. The main challenges stem from the magnetic-field dependence in the Hamiltonian, or, more precisely, the appearance of the…

化学物理 · 物理学 2015-09-02 Stella Stopkowicz , Jürgen Gauss , Kai K. Lange , Erik I. Tellgren , Trygve Helgaker

"Addition-by-subtraction" coupled cluster (CC) approaches provide a promising approach to treating the difficult strong correlation problem by simplifying the standard CC equations. In a separate vein, linearized CC methods have drawn…

强关联电子 · 物理学 2026-03-02 Sylvia J. Bintrim , Ella R. Ransford , Kevin Carter-Fenk

In this paper, we will prove the existence of infinitely many solutions to the following equation by utilizing the variational perturbation method \begin{equation*} -div(A(x,u)|\nabla u|^{p-2}\nabla u)+\frac{1}{p}A_{t}(x,u)|\nabla…

偏微分方程分析 · 数学 2025-09-09 Lin Zhang