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The glass transition is considered within two toys models, a mean field spin glass and a directed polymer in a correlated random potential. In the spin glass model there occurs a dynamical transition, where the system condenses in a state…

无序系统与神经网络 · 物理学 2009-10-30 Th. M. Nieuwenhuizen

The glass transition, extensively studied in dense fluids, polymers, or colloids, corresponds to a dramatic evolution of equilibrium transport coefficients upon a modest change of control parameter, like temperature or pressure. A similar…

统计力学 · 物理学 2013-05-06 Ludovic Berthier , Jorge Kurchan

Aspects of the dynamical glass transition are considered within a mean field spin glass model. At the dynamical transition the the system condenses in a state of lower entropy. The difference, the information entropy or complexity, is…

凝聚态物理 · 物理学 2007-05-23 Th. M. Nieuwenhuizen

We re-examine the physical origin of the polymer glass transition from the point of view of marginal rigidity, which is achieved above a certain number of intermolecular contacts. In the case of polymer chains in a melt / poor solvent, each…

软凝聚态物质 · 物理学 2016-07-12 Anna Lappala , Alessio Zaccone , Eugene M. Terentjev

We show that a glass transition, signaled by a peak in the specific heat vs. temperature, can occur because a glassy system that shows no signs of aging progresses so slowly through the energy landscape that the time needed to obtain an…

无序系统与神经网络 · 物理学 2007-05-23 Clare C. Yu , Herve M. Carruzzo

Tackling the low-temperature fate of supercooled liquids is challenging due to the immense timescales involved, which prevent equilibration and lead to the operational glass transition. Relating glassy behaviour to an underlying,…

统计力学 · 物理学 2017-08-16 Francesco Turci , C. Patrick Royall , Thomas Speck

Stretched polymers with attractive interaction are studied in two and three dimensions. They are described by biased self-avoiding random walks with nearest neighbour attraction. The bias corresponds to opposite forces applied to the first…

统计力学 · 物理学 2009-11-07 Peter Grassberger , Hsiao-Ping Hsu

The dynamical glass transition is typically taken to be the temperature at which a glassy liquid is no longer able to equilibrate on experimental timescales. Consequently, the physical properties of these systems just above or below the…

软凝聚态物质 · 物理学 2017-03-08 Samuel S. Schoenholz , Ekin D. Cubuk , Efthimios Kaxiras , Andrea J. Liu

We have considered the dynamical evolution of cellular patterns controlled by a stochastic Glauber process determined by the deviations of local cell topology from that of a crystalline structure. Above a critical temperature evolution is…

无序系统与神经网络 · 物理学 2009-10-31 Tomaso Aste , David Sherrington

We consider the stationary state of a fluid comprised of inelastic hard spheres or disks under the influence of a random, momentum-conserving external force. Starting from the microscopic description of the dynamics, we derive a nonlinear…

统计力学 · 物理学 2013-02-25 W. T. Kranz , M. Sperl , A. Zippelius

The dynamics of structural relaxation in a model polymer glass subject to spatially-homogeneous, time-periodic shear deformation is investigated using molecular dynamics simulations. We study a coarse-grained bead-spring model of short…

软凝聚态物质 · 物理学 2014-01-10 Nikolai V. Priezjev

We introduce a new quantity to probe the glass transition. This quantity is a linear generalized compressibility which depends solely on the positions of the particles. We have performed a molecular dynamics simulation on a glass forming…

无序系统与神经网络 · 物理学 2009-11-07 Herve M. Carruzzo , Clare C. Yu

We investigate a reversible polymerization process in which individual polymers aggregate and fragment at a rate proportional to their molecular weight. We find a nonequilibrium phase transition despite the fact that the dynamics are…

统计力学 · 物理学 2008-06-24 E. Ben-Naim , P. L. Krapivsky

For the dynamical glassy transition in the $p$-spin mean field spin glass model a thermodynamic description is given. The often considered marginal states are not the relevant ones for this purpose. This leads to consider a cooling…

无序系统与神经网络 · 物理学 2009-10-30 Th. M. Nieuwenhuizen

The glass transition refers to the non-equilibrium process by which an equilibrium liquid is transformed to a non-equilibrium disordered solid, or vice versa. Associated response functions, such as heat capacities, are markedly different on…

软凝聚态物质 · 物理学 2013-03-26 Aaron S. Keys , Juan P. Garrahan , David Chandler

We present results of temperature dependent measurements of dynamics of micellar nanoparticle - polymer composites of fixed volume fraction and variable polymer chain grafting density. For nanoparticles with lower grafting density we…

软凝聚态物质 · 物理学 2008-09-12 A. K. Kandar , S. Srivastava , J. K. Basu , M. K. Mukhopadhyay , S. Seifert , S. Narayanan

We study at- and out-of-equilibrium dynamics of a single homopolymer chain at low temperature using molecular dynamics simulations. The main quantities of interest are the average root mean square displacement of the monomers below the…

软凝聚态物质 · 物理学 2009-11-07 Nikolay V. Dokholyan , Estelle Pitard , Sergey V. Buldyrev , H. Eugene Stanley

We study the dynamics of a glassy model with infinite range interactions externally driven by an oscillatory force. We find a well-defined transition in the (Temperature-Amplitude-Frequency) phase diagram between (i) a `glassy' state…

统计力学 · 物理学 2009-10-31 Ludovic Berthier , Leticia F. Cugliandolo , Jose Luis Iguain

We introduce a lattice model of glass transition in polymer globules. This model exhibits a novel scenario of ergodicity breaking in which the disjoint regions of phase space do not arise uniformly, but as small chambers whose number…

无序系统与神经网络 · 物理学 2009-10-31 Rose Du , Alexander Yu. Grosberg , Toyoichi Tanaka , Michael Rubinstein

We present a modified version of our "sliding model", where chain arcs, between two contacts at the surface, may move if all the barriers along the arc are weaker than a certain threshold.An important advance of the revised model is that…

软凝聚态物质 · 物理学 2007-05-23 Pierre-Gilles de Gennes
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