相关论文: Onsager model for a variable dielectric permittivi…

A statistical mechanics expression is derived for the space-dependent dielectric permittivity of a polar solvent near an interface. The asymptotic behaviour of this local permittivity is calculated in the low density limit, near a planar…

We develop an extended Onsager real-cavity framework to describe the Casimir-Polder interaction of small molecules dissolved in dielectric liquids near planar interfaces. By analytically resolving the geometry of the cavity opening, we…

We critically examine a broad class of explicitly polarisable soft solvent models aimed at applications in dissipative particle dynamics. We obtain the dielectric permittivity using the fluctuating box dipole method in linear response…

We generalize an idea in the works of Landauer and Bennett on computations, and Hill's in chemical kinetics, to emphasize the importance of kinetic cycles in mesoscopic nonequilibrium thermodynamics (NET). For continuous stochastic systems,…

The dielectric permittivity of liquid water is a fundamental property that underlies its distinctive behaviors in numerious physical, biological, and chemical processes. Within a machine learning framework, we present a unified approach to…

Within the Onsager theory we study free planar isotropic-nematic interfaces in binary mixtures of hard rods. For sufficiently different particle shapes the bulk phase diagrams of these mixtures exhibit a triple point, where an isotropic (I)…

We investigate dielectric saturation and increment in polar liquids under external fields. We couple a previously introduced dipolar solvent model to a uniform electric field and derive the electrostatic kernel of interacting dipoles. This…

We present extensive Molecular Dynamics simulation results for the structure, static and dynamical response of a droplet of 1000 soft spheres carrying extended dipoles and confined to spherical cavities of radii $R=2.5$, 3, and 4 nm…

Electric field produced inside a solute by a uniformly polarized liquid is strongly affected by dipolar polarization of the liquid at the interface. We show, by numerical simulations, that the electric "cavity" field inside a hydrated…

A two-dimensional binary composite system composed of ellipse inclusions and a host medium is considered. Dielectric permittivity of the system is calculated as a function of orientation angle, the volume fraction of the inclusions and…

The standard Maxwell formulation of the problem of polarized dielectrics suffers from a number of difficulties, both conceptual and practical. These difficulties are particularly significant in the case of liquid interfaces, where the…

Light-matter interaction processes are significantly affected by surrounding electromagnetic environment. Dielectric materials are usually introduced into an interaction picture via their classical properties, e.g. permittivity, appearing…

The decay rate and the classical radiation power of an excited molecule (atom) located in the center of a dispersive and absorbing dielectric sphere taken as a simple model of a cavity are calculated adopting the Onsager model for the local…

Nonequilibrium interfacial thermodynamics is formulated in the presence of surface reactions for the study of diffusiophoresis in isothermal systems. As a consequence of microreversibility and Onsager-Casimir reciprocal relations,…

An iterative method for calculating the polar component of the solvation Gibbs energy under a smooth change in dielectric permittivity, both between a substrate and a solvent and in a solvent is formulated on the basis of a previously…

The structure of polar liquids and electrolytic solutions, such as water and aqueous electrolytes, at interfaces underlies numerous phenomena in physics, chemistry, biology, and engineering. In this work, we develop a continuum theory that…

We study phase separation in two dimensions in the scaling limit below criticality. The general form of the magnetization profile as the volume goes to infinity is determined exactly within the field theoretical framework which explicitly…

The dielectric properties of molecules or nanostructures are usually modified in a complex manner, when assembled into a condensed phase. We propose a first-principles method to compute polarizabilities of sub-entities of solids and…

Accuracy in complex dielectric permittivity calculations in binary dielectric mixtures in two-dimensions are reported by taking into account the shape of the inclusion phase. The dielectric permittivity of the mixtures were calculated using…

We investigate surface modes in plasmonic Bragg fibers composed of nanostructured coaxial cylindrical metal-dielectric multilayers. We demonstrate that the existence of surface modes is determined by the sign of the spatially averaged…