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The definition of nonequilibrium entropy is provided for the general nonequilibrium processes by connecting thermodynamics with statistical physics, and the principle of entropy increment in the nonequilibrium processes is also proved in…

数据分析、统计与概率 · 物理学 2007-05-23 Xiaochun Mei

When at equilibrium, large-scale systems obey conventional thermodynamics because they belong to microscopic configurations (or states) that are typical. Crucially, the typical states usually represent only a small fraction of the total…

统计力学 · 物理学 2025-01-14 Bernat Corominas-Murtra , Rudolf Hanel , Petr Jizba

In a paper [8] the authors classify entropy into three categories, as a thermodynamics quantity, as a measure of information production, and as a means of statistical inference. An entropy measure introduced by Mathai falls into the second…

统计力学 · 物理学 2024-10-31 Hans J. Haubold

The universal bound on specific entropy was originally inferred from black hole thermodynamics. We here show from classical thermodynamics alone that for a system at fixed volume or fixed pressure, the ratio of entropy to nonrelativistic…

广义相对论与量子宇宙学 · 物理学 2014-05-29 Jacob D. Bekenstein

We consider the problem of defining free energy and other thermodynamic functions when the entropy is given as a general function of the probablity distribution, including that for non extensive forms. We find that the free energy, which is…

统计力学 · 物理学 2007-11-07 Fariel Shafee

We compute the entanglement entropy of a wide class of exactly solvable models which may be characterized as describing matter coupled to gauge fields. Our principle result is an entanglement sum rule which states that entropy of the full…

强关联电子 · 物理学 2013-09-11 Brian Swingle

This paper presents a thermodynamically consistent model for multicomponent electrolyte solutions. The first part of this paper derives the general governing equations for nonequilibrium systems within the theory of nonequilibrium…

偏微分方程分析 · 数学 2016-05-25 Matthias Herz , Peter Knabner

Thermodynamic extensivity is commonly introduced as a postulate -- the homogeneity of degree one in thermodynamic potentials. We provide a constructive derivation of this property from microscopic conditions on the pair potential, without…

统计力学 · 物理学 2026-05-19 Bob Osano

By replacing linear averaging in Shannon entropy with Kolmogorov-Nagumo average (KN-averages) or quasilinear mean and further imposing the additivity constraint, R\'{e}nyi proposed the first formal generalization of Shannon entropy. Using…

信息论 · 计算机科学 2007-07-13 Ambedkar Dukkipati , M. Narasimha Murty , Shalabh Bhatnagar

We present an example counter to the widely-accepted concept on equilibrium states that "Any thermodynamic equilibrium state of two component systems is determined by specifying 4 thermodynamic variables that include at least 1 extensive…

软凝聚态物质 · 物理学 2018-05-16 Yuki Norizoe , Toshihiro Kawakatsu

We present aspects of entropic functionals relatively recently introduced in Physics which are non-additive, in the conventional sense of the word, some of which have a power-law functional form. We use as an example among them, and to be…

广义相对论与量子宇宙学 · 物理学 2019-02-27 Nikos Kalogeropoulos

What is the best description that we can construct of a thermodynamic system that is not in equilibrium, given only one, or a few, extra parameters over and above those needed for a description of the same system at equilibrium? Here, we…

统计力学 · 物理学 2007-07-05 Gavin E. Crooks

Euler turbulence has been experimentally observed to relax to a metaequilibrium state that does not maximize the Boltzmann entropy, but rather seems to minimize enstrophy. We show that a recent generalization of thermodynamics and…

chao-dyn · 物理学 2016-08-31 Bruce M. Boghosian

The thermodynamic approach to non-equilibrium dynamics describes the state of macroscopic systems by means of a collection of intensities or intensive variables. The latter are by definition the differentials of the entropy with respect to…

chao-dyn · 物理学 2008-02-03 Z. Hens , X. de Hemptinne

Mutual equilibrium in long-range interacting systems which involve nonadditive energy, is effectively described in terms of entropy with a nonadditive composition rule. As an example, long range Ising model is considered. The generality of…

统计力学 · 物理学 2016-08-31 Ramandeep S. Johal

Within the Tsallis thermodynamics' framework, and using scaling properties of the entropy, we derive a generalization of the Gibbs-Duhem equation. The analysis suggests a transformation of variables that allows standard thermodynamics to be…

统计力学 · 物理学 2009-11-07 Eduard Vives , Antoni Planes

We develop the framework of classical Observational entropy, which is a mathematically rigorous and precise framework for non-equilibrium thermodynamics, explicitly defined in terms of a set of observables. Observational entropy can be seen…

统计力学 · 物理学 2020-09-09 Dominik Šafránek , Anthony Aguirre , J. M. Deutsch

The aim of the present paper is to present a careful and accessible discussion of the formal aspects of Boltzmann-Gibbs and Tsallis entropies. We begin with a brief overview of Boltzmann-Gibbs entropy, highlighting its main properties and…

统计力学 · 物理学 2025-10-23 Kelvin dos Santos Alves , Rogerio Teixeira Cavalcanti

Co-compact entropy is introduced as an invariant of topological conjugation for perfect mappings defined on any Hausdorff space(compactness and metrizability not necessarily required). This is achieved through the consideration of…

动力系统 · 数学 2015-06-12 Zheng Wei , Yangeng Wang , Guo Wei

We propose a new type of entropic descriptor that is able to quantify the statistical complexity (a measure of complex behaviour) by taking simultaneously into account the average departures of a system's entropy S from both its maximum…

统计力学 · 物理学 2015-05-13 R. Piasecki , A. Plastino