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Synthetic polymers have a distribution of chain lengths which can be characterized by dispersity, D. Macroscopic properties of polymers are influenced by chain mobility in the melt and manipulating D can significantly impact these…

化学物理 · 物理学 2024-09-30 Taofeek Tejuosho , Sohil Kollipara , Sumant Patankar , Janani Sampath

A prime example of non-equilibrium or active environment is a biological cell. In order to understand in-vivo functioning of biomolecules such as proteins, chromatins, a description beyond equilibrium is absolutely necessary. In this…

软凝聚态物质 · 物理学 2019-03-27 Subhasish Chaki , Rajarshi Chakrabarti

We study the stress distribution in a polymer brush material over a range of graft densities using molecular dynamics (MD) simulations and theory. Flexible polymer chains are treated as beads connected by nonlinear springs governed by a…

应用物理 · 物理学 2019-03-27 M. Manav , M. Ponga , A. Srikantha Phani

We study the adhesive contact between elastic solids with randomly rough, self affine fractal surfaces. We present molecular dynamics (MD) simulation results for the interfacial stress distribution and the wall-wall separation. We compare…

软凝聚态物质 · 物理学 2009-11-13 C. Yang , B. N. J. Persson , J. Israelachvili , K. Rosenberg

We use Monte Carlo simulations to study polymer melts consisting of fully flexible and moderately stiff chains in the bond fluctuation model at a volume fraction $0.5$. In order to reduce the local density fluctuations, we test a…

软凝聚态物质 · 物理学 2015-06-24 Hsiao-Ping Hsu

We performed molecular dynamics simulations to study equilibrium and flow properties of a liquid in a nano-channel with confining surfaces coated with a layer of grafted semiflexible polymers. The coverage spans a wide range of grafting…

计算物理 · 物理学 2015-09-30 Kevin Speyer , Claudio Pastorino

Using molecular dynamics simulation of a standard bead-spring model we investigate the density crossover scaling of strictly two-dimensional self-avoiding polymer chains focusing on properties related to the contact exponent set by the…

软凝聚态物质 · 物理学 2015-06-03 N. Schulmann , H. Meyer , J. P. Wittmer , A. Johner , J. Baschnagel

The self-consistent field (SCF) theory of dense polymer liquids assumes that short-range correlations are almost independent of how monomers are connected into polymers. Some limits of this idea are explored in the context of a perturbation…

软凝聚态物质 · 物理学 2015-05-13 David C. Morse , Jun Kyung Chung

We present a detailed study of the static and dynamic behavior of long semiflexible polymer chains in a melt. Starting from previously obtained fully equilibrated high molecular weight polymer melts [{\it Zhang et al.} ACS Macro Lett. 3,…

软凝聚态物质 · 物理学 2016-05-25 Hsiao-Ping Hsu , Kurt Kremer

Thermal conduction in polymer nanocomposites depends on several parameters including the thermal conductivity and geometrical features of the nanoparticles, the particle loading, their degree of dispersion and formation of a percolating…

应用物理 · 物理学 2021-01-25 Alessandro di Pierro , Alberto Fina

Chemical reactions inside cells are typically subject to the effects both of the cell's confining surfaces and of the viscoelastic behavior of its contents. In this paper, we show how the outcome of one particular reaction of relevance to…

软凝聚态物质 · 物理学 2015-06-04 Pinaki Bhattacharyya , Rati Sharma , Binny J. Cherayil

The interdiffusion of a solvent into a polymer melt has been studied using large scale molecular dynamics and Monte Carlo simulation techniques. The solvent concentration profile and weight gain by the polymer have been measured as a…

软凝聚态物质 · 物理学 2009-11-10 Mesfin Tsige , Gary S. Grest

The aim of this paper is to compare results from lattice-Boltzmann and Brownian dynamics simulations of linear chain molecules. We have systematically varied the parameters that may affect the accuracy of the lattice-Boltzmann simulations,…

计算物理 · 物理学 2015-05-13 Anthony J. C. Ladd , Rahul Kekre , Jason E. Butler

We present Monte Carlo simulations of semidilute solutions of long self-attracting chain polymers near their Ising type critical point. The polymers are modeled as monodisperse self-avoiding walks on the simple cubic lattice with attraction…

软凝聚态物质 · 物理学 2009-10-30 H. Frauenkron , P. Grassberger , HLRZ Juelich , Germany

Generalization of the Rouse model without any use of the postulates concerning the Gaussian distribution of the vector connecting the ends of segments is advanced. In the initial (in general, nonlinear) Langevin equations, self-averaging…

软凝聚态物质 · 物理学 2016-11-27 Nail Fatkullin

The short--time self diffusion coefficient of a sphere in a suspension of rigid rods is calculated in first order in the rod volume fraction. For low rod concentrations the correction to the Einstein diffusion constant of the sphere is a…

软凝聚态物质 · 物理学 2008-12-03 J. Guzowski , B. Cichocki , E. Wajnryb , G. C. Abade

By means of contact-density chain-growth simulations, we investigate a simple lattice model of a flexible polymer interacting with an attractive substrate. The contact density is a function of the numbers of monomer-substrate and…

统计力学 · 物理学 2011-07-04 Michael Bachmann

We consider nonparametric statistical inference on a periodic interaction potential $W$ from noisy discrete space-time measurements of solutions $\rho=\rho_W$ of the nonlinear McKean-Vlasov equation, describing the probability density of…

统计理论 · 数学 2025-01-15 Richard Nickl , Grigorios A. Pavliotis , Kolyan Ray

The collision frequency (also known as the inverse scattering lifetime) can be self-consistently calculated from the imaginary part of the zero-temperature elastic scattering cross-section in unconventional superconductors. We find these…

超导电性 · 物理学 2023-11-17 Pedro Contreras

We adapt Fluorescence Correlation spectroscopy (FCS) formalism to the studies of the dynamics of semi-flexible polymers and derive expressions relating FCS correlation function to the longitudinal and transverse mean square displacements of…

软凝聚态物质 · 物理学 2009-11-11 Anne Bernheim-Groswasser , Roman Shusterman , Oleg Krichevsky