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We propose thermodynamically consistent models for viscoelastic fluids with a stress diffusion term. In particular, we derive variants of compressible/incompressible Maxwell/Oldroyd-B models with a stress diffusion term in the evolution…

流体动力学 · 物理学 2018-03-14 Josef Málek , Vít Průša , Tomáš Skřivan , Endre Süli

Today, most application of time-dependent density functional theory (TDDFT) use adiabatic exchange-correlation (XC) potentials that do not take into account non-local temporal effects. Incorporating such "memory" terms into XC potentials is…

强关联电子 · 物理学 2007-05-23 Yair Kurzweil , Roi Baer

We train a neural network as the universal exchange-correlation functional of density-functional theory that simultaneously reproduces both the exact exchange-correlation energy and potential. This functional is extremely non-local, but…

计算物理 · 物理学 2019-10-10 Jonathan Schmidt , Carlos L. Benavides-Riveros , Miguel A. L. Marques

Starting from a general classical model of many interacting particles we present a well defined step by step procedure to derive the continuum-mechanics equations of nonlinear elasticity theory with fluctuations which describe the…

统计力学 · 物理学 2022-06-02 Rudolf Haussmann

Starting from the Boltzmann equation in the relaxation time approximation and employing a Chapman-Enskog like expansion for the distribution function close to equilibrium, we derive second-order evolution equations for the shear stress…

核理论 · 物理学 2015-11-18 Amaresh Jaiswal , Bengt Friman , Krzysztof Redlich

A diagrammatic kinetic theory of density fluctuations in simple dense liquids at long times, described in the preceding paper, is applied to a high density Lennard-Jones liquid to calculate various equilibrium time correlation functions.…

统计力学 · 物理学 2015-06-18 Kevin R. Pilkiewicz , Hans C. Andersen

Inspired by the work in Ref.[1], which considers the additional second-order contributions arising from nonlocal corrections due to two-point correlation functions of tensors of different ranks at distinct spacetime points, we similarly…

核理论 · 物理学 2025-05-15 Duan She , Yi-Wei Qiu , Ze-Fang Jiang , Defu Hou

The kinetic equation of nonlocal and non-instantaneous character unifies the achievements of the transport in dense quantum gases with the Landau theory of quasiclassical transport in Fermi systems. Large cancellations in the off-shell…

强关联电子 · 物理学 2018-05-25 K. Morawetz

In the current density functional theory of linear and nonlinear time-dependent phenomena, the treatment of exchange and correlation beyond the level of the adiabatic local density approximation is shown to lead to the appearance of…

凝聚态物理 · 物理学 2009-10-30 G. Vignale , C. A. Ullrich , S. Conti

Starting from the stochastic equation for the density operator, we formulate the exact (instantaneous) stress tensor for interacting Brownian particles, whose average value agrees with expressions derived previously. We analyze the relation…

软凝聚态物质 · 物理学 2018-04-04 M. Krüger , A. Solon , V. Démery , C. M. Rohwer , D. S. Dean

The exact static and time-dependent Kohn-Sham (KS) exchange-correlation (xc) potential is extremely challenging to approximate as it is a local multiplicative potential that depends on the electron density everywhere in the system. The KS…

强关联电子 · 物理学 2021-01-15 M. J. P. Hodgson , J. Wetherell

An exchange-correlation energy functional $ E_{\mathrm xc} $ and the resultant exchange-correlation potential $ v_{\mathrm xc}({\bf r}) $ in density-functional theory are proposed using orbital-dependent coupling-constant-averaged pair…

强关联电子 · 物理学 2007-05-23 Hiroshi Yasuhara , Masahiko Higuchi , Yoshiyuki Kawazoe

As an indicator of cooperative motion in a system of Brownian particles that models two-dimensional colloidal liquids, displacement correlation tensor is calculated analytically and compared with numerical results. The key idea for the…

统计力学 · 物理学 2016-08-22 T. Ooshida , S. Goto , T. Matsumoto , M. Otsuki

A semi-relativistic density-functional theory that includes spin-orbit couplings and Zeeman fields on equal footing with the electromagnetic potentials, is an appealing framework to develop a unified first-principles computational approach…

材料科学 · 物理学 2017-09-13 S. Pittalis , G. Vignale , F. G. Eich

We formulate equations of time-dependent density functional theory (TDDFT) in the co-moving Lagrangian reference frame. The main advantage of the Lagrangian description of many-body dynamics is that in the co-moving frame the current…

强关联电子 · 物理学 2009-11-10 I. V. Tokatly

Considering the growing interest of the astrophysicist community in the study of dissipative fluids with the aim of getting a more realistic description of the universe, we present in this paper a physical analysis of the energy-momentum…

广义相对论与量子宇宙学 · 物理学 2016-09-15 Oscar M. Pimentel , Guillermo A. González , F. D. Lora-Clavijo

We propose a machine learning based approach to develop the exchange-correlation potential of time dependent density functional theory (TDDFT). The neural network projection from the time-varying electron densities to the corresponding…

计算物理 · 物理学 2020-05-20 Yasumitsu Suzuki , Ryo Nagai , Jun Haruyama

Exchange-correlation potentials vxc and energy densities exc are derived for integer and fractional electron counts using an orbital-averaged Kohn-Sham inversion procedure. The reference densities for inversion come from full configuration…

化学物理 · 物理学 2025-04-30 Vaibhav Khanna , Bikash Kanungo , Jeffrey Hatch , Joshua Kammeraad , Paul M. Zimmerman

We propose a new approach to approximate the exchange and correlation (XC) functional in density functional theory. The XC potential is considered as an electrostatic potential, generated by a fictitious XC density, which is in turn a…

化学物理 · 物理学 2013-05-29 Xavier Andrade , Alán Aspuru-Guzik

We extend the density functional perturbation theory formalism to the case of non-collinear magnetism. The main problem comes with the exchange-correlation (XC) potential derivatives, which are the only ones that are affected by the…

计算物理 · 物理学 2019-05-15 Fabio Ricci , Sergei Prokhorenko , Marc Torrent , Matthieu J. Verstraete , Eric Bousquet