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The self consistent version of the density functional theory is presented, which allows to calculate the ground state and dynamic properties of finite multi-electron systems. An exact functional equation for the effective interaction, from…

材料科学 · 物理学 2017-08-23 M. Ya. Amusia , A. Z. Msezane , V. R. Shaginyan

We present results for the electronic structure of plutonium by using a recently developed quasiparticle self-consistent $GW$ method (\qsgw). We consider a paramagnetic solution without spin-orbit interaction as a function of volume for the…

强关联电子 · 物理学 2009-07-23 A. N. Chantis , R. C. Albers , A. Svane , N. E. Christensen

Two electrons at the threshold of ionization represent a severe test case for electronic structure theory. A pseudospectral method yields a very accurate density of the two-electron ion with nuclear charge close to the critical value.…

化学物理 · 物理学 2014-08-12 Paul E. Grabowski , Kieron Burke

We propose a model intended to qualitatively capture the electron-electron interaction physics of two-dimensional electron gases formed near transition-metal oxide heterojunctions containing $t_{2g}$ electrons with a density much smaller…

强关联电子 · 物理学 2016-01-27 John R. Tolsma , Alessandro Principi , Reza Asgari , Marco Polini , Allan H. MacDonald

Quasiparticle interference (QPI) imaging is well established to study the low-energy electronic structure in strongly correlated electron materials with unrivalled energy resolution. Yet, being a surface-sensitive technique, the…

For semiconductors used in photovoltaic devices, the effective mass approximation allows calculation of important material properties from first-principles calculations, including optical properties (e.g. exciton binding energies), defect…

材料科学 · 物理学 2019-03-06 Lucy D. Whalley , Jarvist M. Frost , Benjamin J. Morgan , Aron Walsh

High-energy (h$\nu$ = 5.95 keV) synchrotron Photoemission spectroscopy (PES) is used to study bulk electronic structure of Na$_{0.35}$CoO$_{2}$.1.3H$_{2}$O, the layered superconductor. In contrast to 3-dimensional doped Co oxides, Co…

We used density functional and many-body perturbation theory to calculate the quasiparticle band structures and electronic transport parameters of p-type SnSe both for the low-temperature Pnma and high-temperature Cmcm phases. The Pnma…

材料科学 · 物理学 2015-06-19 Guangsha Shi , Emmanouil Kioupakis

Using the recently developed version of the GW method employing the one-site approximation and self-consistent quasiparticle basis set we calculated the electronic structure of 3d and 4d transition metals at experimental atomic volumes. The…

强关联电子 · 物理学 2007-08-16 K. D. Belashchenko , V. P. Antropov , N. E. Zein

We compute and track the impact of truly nonlocal-correlation effects on the quasi-particle (QP) band-structure of hexagonal boron-nitride (h-BN) systems. To that end, we start with the consistent-exchange vdW-DF-cx version [PRB 89, 035412…

材料科学 · 物理学 2025-11-24 Raul Quintero-Monsebaiz , Per Hyldgaard

A study is presented of the electronic band structure and optical absorption spectrum of monolayer WSe$_2$ using an all-electron quasiparticle self-consistent $GW$ approach, QS$G\hat W$, in which the screened Coulomb interaction $\hat W$ is…

材料科学 · 物理学 2024-02-29 Niloufar Dadkhah , Walter R. L. Lambrecht

Discrepancies in the low-energy quasiparticle dispersion extracted from angle resolved photoemission, scanning tunneling spectroscopy and quantum oscillation data are common and have long haunted the field of quantum matter physics. Here,…

强关联电子 · 物理学 2020-12-10 I. Battisti , W. O. Tromp , S. Riccò , R. S. Perry , A. P. Mackenzie , A. Tamai , F. Baumberger , M. P. Allan

Hedin's $GW$ approximation to the electronic self-energy has been impressively successful to calculate quasiparticle energies, such as ionization potentials, electron affinities, or electronic band structures. The success of this fairly…

化学物理 · 物理学 2024-10-31 Arno Förster , Fabien Bruneval

We present a systematic density functional theory study of the electronic structure of copper phthalocyanine (CuPc), using several different (semi)-local and hybrid functionals, and compare the results to experimental photoemission data. We…

材料科学 · 物理学 2009-11-13 Noa Marom , Oded Hod , Gustavo E. Scuseria , Leeor Kronik

Quantum-electrodynamical density-functional theory (QEDFT) provides a promising avenue for exploring complex light-matter interactions in optical cavities for real materials. Similar to conventional density-functional theory, the Kohn-Sham…

In this chapter, we provide a review of ground-state Kohn-Sham density-functional theory of electronic systems and some of its extensions, we present exact expressions and constraints for the exchange and correlation density functionals,…

化学物理 · 物理学 2022-09-12 Julien Toulouse

Using the one-loop functional renormalization group technique we evaluate the self-energy in the weak-coupling regime of the 2D t-t' Hubbard model. At van Hove (vH) band fillings and at low temperatures the quasiparticle weight along the…

强关联电子 · 物理学 2009-11-10 A. A. Katanin , A. P. Kampf

We report first-principles results on the electronic structure of various silicene structures. For planar and simply buckled silicenes, we confirm their zero-gap nature and show a significant renormalization of their Fermi velocity by…

介观与纳米尺度物理 · 物理学 2015-06-12 Shouting Huang , Wei Kang , Li Yang

A general method is presented to unfold band structures of first-principles super-cell calculations with proper spectral weight, allowing easier visualization of the electronic structure and the degree of broken translational symmetry. The…

材料科学 · 物理学 2010-06-29 Wei Ku , Tom Berlijn , Chi-Cheng Lee

The good performance of the GW approximation for band-structure calculations in solids was long taken as a sign that the sum of self-energy diagrams is converged and that all omitted terms are small. However, with modern computational…

材料科学 · 物理学 2007-05-23 Arno Schindlmayr