相关论文: The heat capacity of the restricted primitive mode…
Reassessment of the critical temperature and density of the restricted primitive model of an ionic fluid by Monte Carlo simulations performed for system sizes with linear dimension up to $L/\sigma=34$ and sampling of $\sim 10^9$ trial moves…
Making use of a simple approximation for the evolution of the radial distribution function, we calculate the temperature dependence of the heat capacity $C_v$ of Ar at constant density. $C_v$ decreases with temperature roughly according to…
The problem of successfully simulating ionic fluids at low temperature and low density states is well known in the simulation literature: using conventional methods, the system is not able to equilibrate rapidly due to the presence of…
The 1:1 equisized hard-sphere electrolyte or restricted primitive model has been simulated via grand-canonical fine-discretization Monte Carlo. Newly devised unbiased finite-size extrapolation methods using temperature-density, (T, rho),…
The negative nature of the heat capacity $C_V$ of thermodynamically isolated self-gravitating systems is rediscussed in the framework of a non-extensive kinetic theory. It is found that the dependence of $C_V$ on the non-extensive parameter…
Gas-liquid criticality in the ultrasoft restricted primitive model (URPM) of polyelectrolytes is studied using the collective variables-based theory. For the model, an effective Hamiltonian is derived and explicit expressions for all the…
Molecular dynamic simulations for systems with $D=2,3$ Lennard-Jones-like interactions are studied. In the model, we assume that, at long distances, the two-body attractive potential decays as $r^{-\alpha}$. Thermodynamic extensivity…
We investigate the liquid-vapor interface of the restricted primitive model (RPM) for an ionic fluid using a density-functional approximation based on correlation functions of the homogeneous fluid as obtained from the mean-spherical…
In the framework of extended thermodynamics, where the cosmological constant $\Lambda$ plays the role of a dynamical pressure $p$, its conjugate variable $V$ arises naturally. This makes it possible to define $C_p$ and $C_V$, the heat…
Linearly-sloped or `ramp' potentials belong to a class of core-softened models which possess a liquid-liquid critical point (LLCP) in addition to the usual liquid-gas critical point. Furthermore they exhibit thermodynamic anomalies in the…
Recent Monte Carlo simulations of the critical point of the restricted primitive model for ionic solutions are reported. Only the continuum version of the model is considered. A finite size scaling analysis based in the Bruce-Wilding…
We investigate the accuracy of the expression of Rosenfeld and Tarazona (RT) for the excess isochoric heat capacity, C_V^{ex} \propto T^{-2/5}, for eighteen model liquids. Previous investigations have reported no unifying features of…
We show that for any liquid or solid with strong correlation between its $NVT$ virial and potential-energy equilibrium fluctuations, the temperature is a product of a function of excess entropy per particle and a function of density,…
From experimental observations of limiting temperatures in heavy ion collisions we derive Tc, the critical temperature of infinite nuclear matter. The critical temperature is 16.6 +- 0.86 MeV. Theoretical model correlations between Tc, the…
We use Monte Carlo simulations to examine the simplest model of an ionic liquid, called the restricted primitive model, at a metal surface. We find that at moderately low temperatures the capacitance of the metal/ionic liquid interface is…
We have obtained by Monte Carlo NVT simulations the constant-volume excess heat capacity of square-well fluids for several temperatures, densities and potential widths. Heat capacity is a thermodynamic property much more sensitive to the…
We study the critical behavior of the systems dominated by Coulombic interaction. For this purpose we used the method of collective variables with a reference system. Starting from the Hamiltonian of the restricted primitive model (RPM),…
A new theoretical approach to 1:1 electrolytes at low temperature is developed, RPM and SAPM are studied with this approach, and their critical points of first order phase transition are calculated. The result is in very good agreement with…
We study the vapour-liquid phase behaviour of an ionic fluid confined in a random porous matrix formed by uncharged hard sphere particles. The ionic fluid is modelled as an equimolar binary mixture of oppositely charged equisized hard…
The original Rosenfeld-Tarazona (RT) scaling of the excess energy in simple dense fluids predicts a $\propto T^{3/5}$ thermal correction to the fluid Madelung energy. This implies that the excess isochoric heat capacity scales as $C_{\rm…