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The relationships between reversible Carnot cycles, the absence of perpetual motion machines and the existence of a non-decreasing, globally unique entropy function forms the starting point of many textbook presentations of the foundations…

统计力学 · 物理学 2015-05-14 O. J. E. Maroney

In this paper, we develop a variational foundation for stochastic thermodynamics of finite-dimensional, continuous-time systems. Requiring the second law (non-negative average total entropy production) systematically yields a consistent…

It is shown that the structure of thermodynamics is "form invariant", when it is derived using maximum entropy principle for various choices of entropy and even beyond equilibrium. By the form invariance of thermodynamics, it is meant that…

量子物理 · 物理学 2015-11-12 Avijit Misra , Uttam Singh , Manabendra Nath Bera , A. K. Rajagopal

We present an argument which purports to show that the use of the standard Legendre transform in non-additive Statistical Mechanics is not appropriate. For concreteness, we use as paradigm, the case of systems which are conjecturally…

统计力学 · 物理学 2017-08-02 Nikolaos Kalogeropoulos

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

统计力学 · 物理学 2015-11-18 Robert H. Swendsen

Starting from a formulation for the $dS$ element that includes movement, and considering the variation of the entropy Lorentz invariant, we found the relativistic transformations for thermodynamic systems that satisfy the three laws of…

经典物理 · 物理学 2008-03-20 C. A. Farías , P. S. Moya , V. A. Pinto

We prove the Gibbs variational formula in terms of quantum relative entropy density that characterizes translation invariant thermal equilibrium states in quantum lattice systems. It is a natural quantum extension of the similar statement…

数学物理 · 物理学 2022-05-27 Hajime Moriya

The dynamical convergence of a system to the thermal distribution, or Gibbs state, is a standard assumption across all of the physical sciences. The Gibbs state is determined just by temperature and the system's energies alone. But at…

量子物理 · 物理学 2022-06-27 A. S. Trushechkin , M. Merkli , J. D. Cresser , J. Anders

We extend the recently developed non-gaussian thermodynamic formalism \cite{tre98} of a (presumably strongly turbulent) non-Markovian medium to its most general form that allows for the formulation of a consistent thermodynamic theory. All…

空间物理 · 物理学 2009-10-31 R. A. Treumann

Legendre invariant metrics have been introduced in Geometrothermodynamics to take into account the important fact that the thermodynamic properties of physical systems do not depend on the choice of thermodynamic potential from a geometric…

The grand partition function of a model of confined quarks is exactly calculated at arbitrary temperatures and quark chemical potentials. The model is inspired by a softly BRST-broken version of QCD and possesses a quark mass function…

高能物理 - 唯象学 · 物理学 2015-10-28 M. S. Guimaraes , B. W. Mintz , L. F. Palhares

Multidimensional consistency has emerged as a key integrability property for partial difference equations (P$\Delta$Es) defined on the "space-time" lattice. It has led, among other major insights, to a classification of scalar affine-linear…

可精确求解与可积系统 · 物理学 2015-05-19 Pavlos Xenitidis , Frank Nijhoff , Sarah Lobb

Stochastic field theories are often constructed phenomenologically, without a systematic assessment of thermodynamic consistency or local detailed balance. This may hinder a physical description of irreversibility at the field-theoretic…

The approach to a substantiation of thermodynamics is offered. A conservative system of interacting elements, which is not in equilibrium, is used as a model. This system is then split into small subsystems that are accepted as being in…

统计力学 · 物理学 2007-05-23 V. M. Somsikov

A statistical treatment of finite unbound systems in the presence of collective motions is presented and applied to a classical Lennard-Jones Hamiltonian, numerically simulated through molecular dynamics. In the ideal gas limit, the flow…

统计力学 · 物理学 2008-02-01 M. J. Ison , F. Gulminelli , C. Dorso

A variant of continuous nonequilibrium thermodynamic theory based on the postulate of the scale invariance of the local relation between generalized fluxes and forces has been proposed. This single postulate replaces the assumptions on…

统计力学 · 物理学 2015-06-05 Leonid M. Martyushev , V. D. Seleznev

We have connected the dynamic fragility, namely the rapidity of the relaxation time increase upon temperature reduction, to the excess entropy and heat capacity of a large number of glass-forming polymers. The connection was obtained in a…

软凝聚态物质 · 物理学 2009-11-11 D. Cangialosi , A. Alegria , J. Colmenero

Based on the properties of exponential distribution families we analyze the Fisher information of the Gibbs canonical ensemble to construct a new state function for simple systems with no mechanical work. Such a function possesses nice…

经典物理 · 物理学 2015-06-17 Amilcare Porporato

We study four distinct families of Gibbs canonical distributions defined on the standard complex, quaternionic, real and classical (nonquantum) two-level systems. The structure function or density of states for any two-level system is a…

量子物理 · 物理学 2008-02-03 Paul B. Slater

The formulas for the entropy of ideal gases mixture and the entropy change in mixing of ideal gases on the basis of the third law of thermodynamics were obtained. It is shown that when using these formulas, the Gibbs paradox within the…

物理学史与哲学 · 物理学 2013-06-26 V. Ihnatovych