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Molecular polaritons are hybrid states of photonic and molecular character that form when molecules strongly interact with light. Strong coupling tunes energy levels and importantly, can modify molecular properties (e.g. photoreaction…

化学物理 · 物理学 2023-02-14 Francesca Fassioli , Kyu Hyung Park , Sarah E. Bard , Gregory D. Scholes

Molecular polaritons have gained considerable attention due to their potential to control nanoscale molecular processes by harnessing electromagnetic coherence. Although recent experiments with liquid-phase vibrational polaritons have shown…

Light-matter interactions can occur when an ensemble of molecular resonators is placed in a confined electromagnetic field. In the strong coupling regime the rapid exchange of energy between the molecules and the electromagnetic field…

介观与纳米尺度物理 · 物理学 2020-08-10 Philip A. Thomas , Wai Jue Tan , Henry A. Fernandez , William L. Barnes

We investigate the many-body states of exciton-polaritons that can be observed by pump-probe spectroscopy. Here, a weak-probe `spin-down' polariton is introduced into a coherent state of `spin-up' polaritons created by a strong pump. We…

量子气体 · 物理学 2020-01-01 Jesper Levinsen , Francesca Maria Marchetti , Jonathan Keeling , Meera M. Parish

A full quantum theory beyond the mean-field regime is developed for an exciton polariton condensate, to gain a complete understanding of quantum fluctuations. We find analytical solution for the polariton density matrix, showing the…

介观与纳米尺度物理 · 物理学 2022-04-29 Zhedong Zhang , Shixuan Zhao , Dangyuan Lei

Molecular polaritons are the optical excitations which emerge when molecular transitions interact strongly with confined electromagnetic fields. Increasing interest in the hybrid molecular-photonic materials that host these excitations…

介观与纳米尺度物理 · 物理学 2018-02-26 Raphael F. Ribeiro , Luis A. Martínez-Martínez , Matthew Du , Jorge Campos-Gonzalez-Angulo , Joel Yuen-Zhou

This review outlines several linear optical effects featured by molecular polaritons arising in the collective strong light-matter coupling regime. Under weak laser irradiation and when the single-molecule light-matter coupling can be…

Strong light-matter coupling gives rise to polaritons - hybrid excitations whose mixed photonic and matter character enables control over optical, electronic and chemical properties. This Feature Article surveys the main architectures…

Organic polaritons resulting from the strong hybridisation between photons and matter excitations have arisen as a suitable platform to device light-matter technological interfaces at room temperature. Despite their inherent complexity,…

The polariton, a quasiparticle formed by strong coupling of a photon to a matter excitation, is a fundamental ingredient of emergent photonic quantum systems ranging from semiconductor nanophotonics to circuit quantum electrodynamics.…

量子气体 · 物理学 2024-03-21 Joonhyuk Kwon , Youngshin Kim , Alfonso Lanuza , Dominik Schneble

We introduce a theoretical framework that allows for the systematic and efficient description of the ultrafast nonlinear response of molecular polaritons, i.e., hybrid light-matter states, in the collective regime of large numbers of…

量子物理 · 物理学 2025-05-22 Michael Reitz , Arghadip Koner , Joel Yuen-Zhou

In a recent preprint (arXiv:1401.1128v1) Cilibrizzi and co-workers report experiments and simulations showing the scattering of polaritons against a localised obstacle in a semiconductor microcavity. The authors observe in the linear…

Exciton polaritons, arising from the interaction of electronic transitions with confined electromagnetic fields, have emerged as a powerful tool to manipulate the properties of organic materials. However, standard experimental and…

A light-matter hybrid quasiparticle, called a polariton, is formed when molecules are strongly coupled to an optical cavity. Recent experiments have shown that polariton chemistry can manipulate chemical reactions. Polariton chemistry is a…

化学物理 · 物理学 2024-01-11 Xinyang Li , Nicholas Lubbers , Sergei Tretiak , Kipton Barros , Yu Zhang

Exciton-polaritons in semiconductors are quasi-particles which have recently shown the capability to undergo phase transition into a coherent hybrid state of light and matter. The observation of such quasi-particles in organic microcavities…

We apply the Kubo-Anderson stochastic theory of molecular spectral lineshape to the case of polaritons formed in the collective strong coupling regime. We investigate both the fast and slow limits of the random frequency modulation of the…

化学物理 · 物理学 2023-10-24 Clàudia Climent , Joseph E. Subotnik , Abraham Nitzan

When the interaction between a molecular system and confined light modes in an optical or plasmonic cavity is strong enough to overcome the dissipative process, hybrid light-matter states (polaritons) become the fundamental excitations in…

介观与纳米尺度物理 · 物理学 2020-01-08 Yu Zhang , Tammie Nelson , Sergei Tretiak

Strong coupling between light and matter generates hybrid polariton modes. We present a continuum formalism that expresses the polariton modes in terms of light and matter densities of states (DOS). We derive exact expressions for the light…

材料科学 · 物理学 2024-12-03 Suman Gunasekaran , Ryan F. Pinard , Andrew J. Musser

Linear spectra of molecular polaritons formed by $N$ molecules coupled to a microcavity photon mode are usually well described by classical linear optics, raising the question of where the expected nonlinear effects in these strongly…

量子物理 · 物理学 2024-11-19 Arghadip Koner , Joel Yuen-Zhou

The regime of ultrastrong light-matter interaction has been investigated theoretically and experimentally, using zero-dimensional electromagnetic resonators coupled with an electronic transition between two confined states of a…

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