相关论文: Synthesis and characterization of a $\pi$-extended…

In certain configurations, the aromatic properties of benzene ring structured molecules allow for unpaired, reactive valence electrons (known as radicals). Clar's goblets are such molecules. With an even number of unpaired radicals, these…

The Clar covering polynomial (also called Zhang-Zhang polynomial in some chemical literature) of a hexagonal system is a counting polynomial for some types of resonant structures called Clar covers, which can be used to determine Kekul\'e…

Catacondensed benzenoids (those benzenoids having no carbon atom belonging to three hexagonal rings) form the simplest class of polycyclic aromatic hydrocarbons (PAH). They have a long history of study and are of wide chemical importance.…

Integration of individual two-dimensional materials into heterostructures is a crucial step which enables development of new and technologically interesting functional systems of reduced dimensionality. Here, well-defined lateral…

We report a closed-form formula for the Zhang-Zhang polynomial (aka ZZ polynomial or Clar covering polynomial) of an important class of elementary pericondensed benzenoids $Rb\left(n_{1},n_{2},m_{1},m_{2}\right)$ usually referred to as…

We report the on-surface synthesis of a non-benzenoid triradical through dehydrogenation of truxene (C27H18) on coinage metal and insulator surfaces. Voltage pulses applied via the tip of a combined scanning tunneling microscope/atomic…

Beginning with the early work of Clar et al. in 1955, zethrenes and their laterally-extended homologues, super-zethrenes, have been intensively studied in the solution phase, and are widely investigated as optical and charge transport…

Fusion of three benzene rings in a triangular fashion gives rise to the smallest open-shell graphene fragment, the phenalenyl radical, whose ${\pi}$-extension leads to an entire family of non-Kekul\'e triangular nanographenes with high-spin…

Shell-shaped Bose-Einstein condensate (BEC) is a typical quantum system in curved geometry. Here we propose a new type of shell-shaped BEC with self-bound character, thereby liberating it from stringent conditions such as microgravity or…

The combination of piezoelectricity with nontrivial topological insulating phase in two-dimensional (2D) systems, namely piezoelectric quantum spin Hall insulator (PQSHI), is intriguing for exploring novel topological states toward the…

A large number of recent works point to the emergence of intriguing analogs of fractional quantum Hall states in lattice models due to effective interactions in nearly flat bands with Chern number C=1. Here, we provide an intuitive and…

A variety of planar {\pi}-conjugated hydrocarbons such as heptauthrene, Clar's goblet and, recently synthesized, triangulene have two electrons occupying two degenerate molecular orbitals. The resulting spin of the interacting ground state…

Quantum spin liquids (QSL) have generated considerable excitement as phases of matter with emergent gauge structures and fractionalized excitations. In this context, phase transitions out of QSLs have been widely discussed as Higgs…

We present an operational method to determine the 'locally preferred structure'' of model liquids, a notion often put forward to explain supercooling of a liquid and glass formation. The method relies on finding the global minimum in the…

Polycyclic aromatic hydrocarbons (PAHs) have been proposed as potential carriers of the unidentified infrared bands (UIRs) and the diffuse interstellar bands (DIBs). PAHs are not likely to form by gas-phase or solid-state interstellar…

A harmonically trapped Bose-Einstein condensate (BEC) leads to topologically trivial compact states. Because of the long-range nonlocal dipole-dipole interaction, a strongly dipolar BEC revealed many novel phenomena. Here we show that in a…

In order to construct a dielectric analog of spaser, we study theoretically and experimentally several configurations of cluster-based unit cells for an all-dielectric metasurface characterized by resonant conditions of the trapped mode…

Lattice models forming bands with higher Chern number offer an intriguing possibility for new phases of matter with no analogue in continuum Landau levels. Here, we establish the existence of a number of new bulk insulating states at…

Clusters of polycyclic aromatic hydrocarbon (PAH) molecules are modelled using explicit all-atom potentials using a rigid body approximation. The PAH's considered range from pyrene (C10H8) to circumcoronene (C54H18), and clusters containing…

The lowest energy configurations of Cn(n =< 55) clusters are obtained using the energy mini- mization technique with the conjugate gradient (CG) method where a modified Brenner potential is invoked to describe the carbon and hydrocarbon…