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Much recent attention has been devoted towards unravelling the microscopic optoelectronic properties of hybrid organic-inorganic perovskites (HOP). Here we investigate by coherent inelastic neutron scattering spectroscopy and Brillouin…

We study the complex ferroelastic/ferroelectric domain structure in the prototypical ferroelectric PbTiO3 epitaxially strained on (110)o-oriented DyScO3 substrates, using a combination of atomic force microscopy, laboratory and synchrotron…

Organic-inorganic perovskite solar cells have attracted tremendous attention because of their remarkably high power conversion efficiencies (PCEs). To further improve the device performance, however, it is imperative to obtain fundamental…

材料科学 · 物理学 2018-02-07 Zhaodong Chu , Mengjin Yang , Philip Schulz , Di Wu , Xin Ma , Edward Seifert , Liuyang Sun , Kai Zhu , Xiaoqin Li , Keji Lai

The transport properties of domain walls in oxygen deficient multiferroic YMnO3 single crystals have been probed using conductive atomic force microscopy and piezoresponse force microscopy. Domain walls exhibit significantly enhanced…

材料科学 · 物理学 2012-01-06 Y. Du , X. L. Wang , D. P. Chen , S. X. Dou , Z. X. Cheng , M. Higgins , G. Wallace , J. Y. Wang

All-inorganic halide perovskites have received a lot of attention as attractive alternatives to overcome the stability issues of hybrid halide perovskites that are commonly associated with organic cations. To find a compromise between the…

材料科学 · 物理学 2026-04-28 Mike Pols , Adri C. T. van Duin , Sofía Calero , Shuxia Tao

Ferroelectric domain nucleation and growth in multiferroic BiFeO3 films is observed directly by applying a local electric field with a conductive tip inside a scanning transmission electron microscope. The nucleation and growth of a…

Several families of layered perovskite oxide ferroelectrics exhibit a coupling between polarization and structural order parameters, such as octahedral rotation distortions. This coupling provides opportunities for novel electric…

材料科学 · 物理学 2023-03-08 Nabaraj Pokhrel , Elizabeth A. Nowadnick

We report the nanoscale electrical imaging results in hexagonal $Lu_{0.6}Sc_{0.4}FeO_3$ single crystals using conductive atomic force microscopy (C-AFM) and scanning microwave impedance microscopy (MIM). While the dc and ac response of the…

材料科学 · 物理学 2018-08-28 Xiaoyu Wu , Kai Du , Lu Zheng , Di Wu , Sang-Wook Cheong , Keji Lai

The performance of perovskite solar cells recently exceeded 15% solar-to-electricity conversion efficiency for small-area devices. The fundamental properties of the active absorber layers, hybrid organic-inorganic perovskites formed from…

材料科学 · 物理学 2013-10-11 Federico Brivio , Alison B. Walker , Aron Walsh

A heterophase containing both the optically active $\alpha$-CsPbI$_3$ and non-active $\delta$-CsPbI$_3$ has been demonstrated as an efficient white light emitter. This has challenged the conventional perspective that non-active phases of…

材料科学 · 物理学 2025-05-23 Yun Liu

Achieving control over the transport properties of charge-carriers is a crucial aspect of realizing high-performance electronic materials. In metal-halide perovskites, which offer convenient manufacturing traits and tunability for certain…

Ferroelectrics usually adopt a multi-domain state with domain walls separating domains with polarization axes oriented differently. It has long been recognized that domain walls can dramatically impact the properties of ferroelectric…

材料科学 · 物理学 2017-03-15 Shi Liu , R. E. Cohen

Under continuous light illumination, it is known that localized domains with segregated halide compositions form in semiconducting mixed-halide perovskites, thus severely limiting their optoelectronic applications due to the negative…

材料科学 · 物理学 2023-03-21 Shengnan Feng , Rentong Duan , Yu Ju , Shuyi Li , Chunfeng Zhang , Shuxia Tao , Min Xiao , Xiaoyong Wang

Tuning the thermal transport properties of hybrid halide perovskites is critical for their applications in optoelectronics, thermoelectrics, and photovoltaics. Here, we demonstrate an effective strategy to modulate the thermal transport…

材料科学 · 物理学 2024-01-02 Guang Wang , Hongzhao Fan , Zhongwei Chen , Yufei Gao , Zuankai Wang , Zhigang Li , Haipeng Lu , Yanguang Zhou

Halide perovskites are currently under intense investigation due to their potential applications in optoelectronics and solar cells. Among them several crystallize in low symmetry lattice structures like trigonal, hexagonal, orthorhombic…

材料科学 · 物理学 2017-11-15 A. Koliogiorgos , S. Baskoutas , I. Galanakis

We consider a typical heterostructure domain patterned ferroelectric film/ultra thin dielectric layer/ semiconductor, where the semiconductor can be an electrolyte, paraelectric or multi layered graphene. Unexpectedly we have found that the…

Bandgap tunability of lead mixed-halide perovskites makes them promising candidates for various applications in optoelectronics since they exhibit sharp optical absorption onsets despite the presence of disorder from halide alloying. Here…

Cesium based halide perovskites, such as CsPbI3 and CsSnI3, have emerged as exceptional candidates for next generation photovoltaic and optoelectronic technologies, but their practical application is limited by temperature dependent phase…

材料科学 · 物理学 2025-10-30 Atefe Ebrahimi , Franco Pellegrini , Stefano De Gironcoli

A common strategy for reducing thermal conductivity of polycrystalline systems is to increase the number of grain boundaries. Indeed, grain boundaries enhance the probability of phonon scattering events, which has been applied to control…

Ionic migration in organo-halide perovskites plays an important role in operation of perovskite based solar cells and light emitting diodes. Despite the ionic migration being a reversible process, it often leads to worsening of perovskite…