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Methanol-water liquid mixtures have been investigated by high-energy synchrotron X-ray and neutron diffraction at low temperatures. We are thus able to report the first complete sets of both X-ray and neutron weighted total scattering…

The covalent-like characteristics of hydrogen bonds offer a new perspective on intermolecular interactions. Here, using density functional theory and post-Hartree-Fock methods, we reveal that there are two bonding molecular orbitals (MOs)…

原子与分子团簇 · 物理学 2015-07-09 Bo Wang , Wanrun Jiang , Xing Dai , Yang Gao , Zhigang Wang , Rui-Qin Zhang

Currently, the study of systems confined within various materials, such as graphene and graphene oxide, for diverse applications such as water desalination, metal separation from water, battery cells, and high-efficiency capacitors, is very…

统计力学 · 物理学 2024-05-24 Raúl Fuentes-Azcatl

We investigate the coupling between interstitial medium and granular particles by studying the hopper flow of dry and submerged system experimentally and numerically. In accordance with earlier studies, we find, that the dry hopper empties…

软凝聚态物质 · 物理学 2017-04-10 Juha Koivisto , Marko Korhonen , Mikko J. Alava , Carlos P. Ortiz , Douglas J. Durian , Antti Puisto

[ This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in The Journal of Chemical Physics, 157, 024504 (2022) and may be found at:…

化学物理 · 物理学 2022-07-14 Daniel Muñoz-Santiburcio

Understanding the rheology of granular assemblies is important for natural and engineering systems, but the relationship between inter-particle friction (or microscopic friction) and macroscopic friction is still not well understood. In…

软凝聚态物质 · 物理学 2022-05-31 Teng Man , Pei Zhang , Zhuan Ge , Sergio A. Galindo-Torres , Kimberly M. Hill

The main causes of energy dissipation in micro- and nano-scale wetting are viscosity and liquid-solid friction localized in the three-phase contact line region. Theoretical models predict the contactline friction coefficient to correlate…

流体动力学 · 物理学 2024-02-12 Michele Pellegrino , Berk Hess

Based on our recent study on physical origin of hydrophobic effects, this is applied to investigate the dependence of hydrophobic interactions on the solute size. As two same hydrophobic solutes are dissolved into water, the hydration free…

软凝聚态物质 · 物理学 2018-03-07 Qiang Sun

Within the quasichemical approach, the hydration free energy of an ion is decomposed into a chemical term accounting for ion specific ion-water interactions within the coordination sphere and nonspecific contributions accounting for packing…

生物物理 · 物理学 2011-06-03 Safir Merchant , D. Asthagiri

Based on the microscopic model, the friction coefficient for the relative motion of nuclei in deep-inelastic heavy-ion collisions is calculated. The radial dependence of the friction coefficient is studied and the results are compared with…

核理论 · 物理学 2008-11-26 G. G. Adamian , R. V. Jolos , A. K. Nasirov , A. I. Muminov

Friction coefficients for the fusion reaction $^{16}$O+$^{16}$O $\rightarrow$ $^{32}$S are extracted based on both the time-dependent Hartree-Fock and the time-dependent density matrix methods. The latter goes beyond the mean-field…

核理论 · 物理学 2018-07-11 Kai Wen , M. C. Barton , Arnau Rios , P. D. Stevenson

The description of hydrodynamic interactions between a particle and the surrounding liquid, down to the nanometer scale, is of primary importance since confined liquids are ubiquitous in many natural and technological situations. In this…

The relation between the frequency-dependent friction of a molecule in a liquid and the hydrodynamic properties of the liquid is fundamental for molecular dynamics. We investigate this connection for a water molecule moving in liquid water…

软凝聚态物质 · 物理学 2024-08-23 Henrik Kiefer , Domenico Vitali , Benjamin A. Dalton , Laura Scalfi , Roland R. Netz

When two phases of water are at equilibrium, the ratio of hydrogen isotopes in each is slightly altered due to their different phase affinities. This isotopic fractionation process can be utilized to analyze water's movement in the world's…

化学物理 · 物理学 2013-07-30 Thomas E. Markland , B. J. Berne

The effect of conformational fluctuations of modular macromolecules, such as enzymes, on their diffusion properties is addressed using a simple generic model of an asymmetric dumbbell made of two hydrodynamically coupled subunits. It is…

软凝聚态物质 · 物理学 2017-11-22 Pierre Illien , Tunrayo Adeleke-Larodo , Ramin Golestanian

This paper explores the friction forces encountered by droplets on non-wetting surfaces, specifically focusing on superhydrophobic and superheated substrates. Employing a combination of experimental techniques, including inclined plane…

流体动力学 · 物理学 2024-05-31 Abhijit Kumar Kushwaha , Sankara Arunachalam , Ville Jokinen , Dan Daniel , Tadd T. Truscott

\textbf{Background} Hydrogels are crosslinked polymer networks that can absorb and retain a large fraction of liquid. Near a critical sliding velocity, hydrogels pressed against smooth surfaces exhibit time-dependent frictional behavior…

软凝聚态物质 · 物理学 2021-01-13 Brady Wu , Joshua Méndez Harper , Justin C. Burton

Molecular dynamics simulations have been performed to study frictional slip and its influence on energy dissipation and momentum transfer at atomically smooth solid/water interfaces. By modifying surface chemistry, we investigate the…

流体动力学 · 物理学 2016-08-08 Kai Huang , Izabela Szlufarska

Hydrodynamic interactions in a suspension of spherical particles confined between two parallel planar walls are studied under creeping-flow conditions. The many-particle friction matrix in this system is evaluated using our novel numerical…

流体动力学 · 物理学 2009-11-11 S. Bhattacharya , J. Blawzdziewicz , E. Wajnryb

The friction coefficient of fluids may become a function of the velocity at increased external driving. This non-Newtonian behavior is of general theoretical interest as well as of great practical importance, e.g., for the design of…

软凝聚态物质 · 物理学 2022-05-03 Matthias Post , Steffen Wolf , Gerhard Stock