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Nano-structured silicon anodes are attractive alternatives to graphite in Li-ion batteries. Despite recent remarkable progresses in numerous Si-C composites, the commercialisation with significance is still limited. One of the most critical…

At photoelectrosynthetic interfaces, an electrochemical reaction is driven by excited charge-carriers from a semiconducting photoabsorber. Structure and composition of this interface determine both the electronic and electrochemical…

化学物理 · 物理学 2022-05-30 Matthias M. May , Wolfram Jaegermann

As one of the most promising next-generation energy storage device, lithium metal batteries have been extensively investigated. However, the poor safety issue and undesired lithium dendrites growth hinder the development of lithium metal…

The solid electrolyte interphase SEI critically dictates the cyclability and Coulombic efficiency of sodium-metal batteries, yet its dynamic formation mechanisms and atomic-scale evolution during electrochemical cycling remain elusive due…

材料科学 · 物理学 2026-04-09 Zhoulin Liu , Ziliang Wang , Zherui Chen , Jianchun Sha , Fengzijun Pan , Pingyang Zhang , Yinghe Zhang

The lithium metal-solid-state electrolyte interface plays a critical role in the performance of solid-state batteries. However, operando characterization of the buried interface morphology in solid-state cells is particularly difficult…

Solid polymer electrolytes (SPE) have the potential to increase both the energy density and stability of lithium-based batteries, but low Li-ion conductivity remains a barrier to technological viability. SPEs are designed to maximize Li-ion…

化学物理 · 物理学 2017-01-24 Brett M. Savoie , Michael A. Webb , Thomas F. Miller

The existing solid electrolytes for lithium ion batteries suffer from low total ionic conductivity, which restricts its usefulness for the lithium-ion battery technology. Among them, the NASICON-based materials, such as…

化学物理 · 物理学 2020-08-03 K. Kwatek , W. Ślubowska , J. Trébosc , O. Lafon , J. L. Nowiński

Polymer electrolytes incorporating Li$_{10}$GeP$_{2}$S$_{12}$ (LGPS) nanoparticles show promise for solid-state lithium batteries owing to their enhanced ionic conductivity, though the governing mechanisms remain unclear. We combine…

The development of next-generation electrochemical energy storage requires devices that combine the high energy density of batteries with the power capability and long cycle life of supercapacitors. However, the interfacial phenomena…

化学物理 · 物理学 2025-12-01 Mehedi Hasan , Ishtiaq Murshed , Khayrul Islam , A. K. M. Masud

Fast lithium transport across the solid-state electrolyte (SSE)/lithium metal anode interface is critical for high-performance all-solid-state batteries. Uncovering the complex lithium dynamics governed by diverse local environments in the…

材料科学 · 物理学 2026-03-04 Qiye Guan , Yongqing Cai

Understanding and controlling the atomistic-level reactions governing the formation of the solid-electrolyte interphase (SEI) is crucial for the viability of next-generation solid state batteries. However, challenges persist due to…

材料科学 · 物理学 2025-06-13 Jingxuan Ding , Laura Zichi , Matteo Carli , Menghang Wang , Albert Musaelian , Yu Xie , Boris Kozinsky

As the design of single-component battery electrodes has matured, the battery industry has turned to hybrid electrodes with blends of two or more active materials to enhance battery performance. Leveraging the best properties of each…

材料科学 · 物理学 2023-05-26 Qiaohao Liang , Martin Z. Bazant

The large - scale commercialization of promising lithium - sulfur (Li - S) batteries remains limited by the polysulfide shuttle effect, which causes rapid capacity fading and poor cycle life. In this study, we present a scalable strategy to…

Semipermeable silica membranes are attractive as protective coatings for metal electrocatalysts such as platinum but their impact on the catalytic properties has not been fully understood. Here, we develop a first principles formalism to…

材料科学 · 物理学 2020-10-27 Jianzhou Qu , Alexander Urban

Electrolyte filling is a time-critical step during battery manufacturing that also affects the battery performance. The underlying physical phenomena during filling mainly occur on the pore scale and are hard to study experimentally. In…

Solid-ion conductors (SICs) comprising non-ionic plastic crystals and lithium salts often require compositing with polymers to render them processable for use in solid-state lithium-metal batteries. Here, we show that polymer-doped plastic…

Current advancements in battery technologies require electrodes to combine high-performance active material such as Silicon (Si) with two-dimensional materials such as transition metal carbides (MXenes) for prolonged cycle stability and…

应用物理 · 物理学 2023-07-14 Vidushi Sharma , Dibakar Datta

Distributions of potential and lithium content inside lithium ion batteries highly affects their performance and durability. An increased heterogeneity of the lithium distribution is expected in thick electrodes with high energy densities…

Magnetohydrodynamically induced interface instability in liquid metal batteries is analyzed. The batteries are represented by a simplified system in the form of a rectangular cell, in which strong vertical electric current flows through…

流体动力学 · 物理学 2018-04-12 Oleg Zikanov

Silicon anodes promise high energy densities of next-generation lithium-ion batteries, but suffer from shorter cycle life. The accelerated capacity fade stems from the repeated fracture and healing of the solid-electrolyte interphase (SEI)…

化学物理 · 物理学 2022-12-01 Lars von Kolzenberg , Arnulf Latz , Birger Horstmann