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Ferroelectric field-effect doping has emerged as a powerful approach to manipulate the ground state of correlated oxides, opening the door to a new class of field-effect devices. However, this potential is not fully exploited so far, since…

Conventionally, dc fields are used for switching dipole orientations in ferroelectrics. Such fields tilt the potential surface experienced by domain walls and thereby lower activation energies for their movement: escape from tilted…

Since the first report of ferroelectricity in nanoscale HfO$_2$-based thin films in 2011, this silicon-compatible binary oxide has quickly garnered intense interest in academia and industry, and continues to do so. Despite its deceivingly…

材料科学 · 物理学 2024-08-27 Tianyuan Zhu , Liyang Ma , Shiqing Deng , Shi Liu

Ferroelectric HfO2 is a promising candidate for next-generation memory devices due to its CMOS compatibility and ability to retain polarization at nanometer scales. However, the polar orthorhombic phase (Pca2_1) responsible for…

材料科学 · 物理学 2026-03-27 Jian Huang , Gwan Yeong Jung , Pravan Omprakash , Guodong Ren , Xin Li , Du Li , Xiaoshan Xu , Li Yang , Rohan Mishra

Ferroelectric field-effect transistors integrated on 2D semiconducting platforms are extremely relevant for low power electronics. Here, we propose and demonstrate a novel phase-change ferroelectric field effect transistor (PCFE-FET) for…

应用物理 · 物理学 2024-11-05 Sooraj Sanjay , Jalaja M. A , Navakanta Bhat , Pavan Nukala

The ferroelectric properties of nanoscale silicon doped HfO$_2$ promise a multitude of applications ranging from ferroelectric memory to energy-related applications. The reason for the unexpected behavior has not been clearly proven and…

材料科学 · 物理学 2018-01-03 Christopher Künneth , Robin Materlik , Max Falkowski , Alfred Kersch

We investigated a switchable ferroelectric diode effect and its physical mechanism in Pt/BiFeO3/SrRuO3 thin-film capacitors. Our results of electrical measurements support that, near the Pt/BiFeO3 interface of as-grown samples, a defective…

材料科学 · 物理学 2011-09-12 Daesu Lee , S. H. Baek , T. H. Kim , J. -G. Yoon , C. M. Folkman , C. B. Eom , T. W. Noh

For forty years researchers on ferroelectric switching have used the Kay-Dunn theory to model the thickness-dependence of the coercive field; it works surprisingly well, despite the fact that it is based upon homogeneous nucleation and a…

材料科学 · 物理学 2007-05-23 P. Chandra , M. Dawber , P. B. Littlewood , J. F. Scott

Typical ferroelectrics possess a large spontaneous polarization Ps but simultaneously a large remnant polarization Pr as well, resulting in an inferior energy storage density.A mechanism that can reduce the Pr while maintain the Ps is…

材料科学 · 物理学 2021-03-24 Zhiyang Wang , Deqing Xue , Dezhen Xue , Yumei Zhou , Xiangdong Ding , Jun Sun

Ferroelectricity in binary oxides including hafnia and zirconia have riveted the attention of the scientific community due to highly unconventional physical mechanisms and the potential for integration of these materials into semiconductor…

HfO$_2$- and ZrO$_2$-based ferroelectric thin films have emerged as promising candidates for the gate oxides of next generation electronic devices. Recent work has experimentally demonstrated that a tetragonal/orthorhombic (t/o-) phase…

介观与纳米尺度物理 · 物理学 2024-03-11 Prabhat Kumar , Michael Hoffmann , Andrew Nonaka , Sayeef Salahuddin , Zhi Yao

Models of exchange-bias in thin films have been able to describe various aspects of this technologically relevant effect. Through appropriate choices of free parameters the modelled hysteresis loops adequately match experiment, and typical…

介观与纳米尺度物理 · 物理学 2014-04-02 Andrea Benassi , Miguel A. Marioni , Daniele Passerone , Hans J. Hug

In contrast to hafnia (HfO2) thin films, where the appearance of switchable ferroelectric polarization can be induced by strain or defect engineering, reliable methods for controlling ferroelectricity are absent in HfO2 nanoparticles.…

材料科学 · 物理学 2026-02-27 Anna N. Morozovska , Eugene A. Eliseev , Richard , Liu , Sergei V. Kalinin , Dean R. Evans

Hafnia ferroelectrics combine technological promise and unprecedented behaviors. Their peculiarity stems from the many active extrinsic mechanisms that contribute to their properties and from a continuously growing number of novel intrinsic…

材料科学 · 物理学 2023-11-15 Hugo Aramberri , Jorge Íñiguez

As the dielectric film thickness shrinks to ~10 nm, some traditional wurtzite piezoelectric materials demonstrate ferroelectricity through element doping. Among them, Sc doped AlN and Mg doped ZnO are the most famous examples. While it is…

材料科学 · 物理学 2025-01-08 Zijian Zhou , Kan-Hao Xue , Jinhai Huang , Heng Yu , Shengxin Yang , Shujuan Liu , Yiqun Wang , Xiangshui Miao

The successful theoretical prediction and experimental demonstration of hybrid improper ferroelectricity (HIF) provides a new pathway to couple octahedral rotations, ferroelectricity, and magnetism in complex materials. To enable…

材料科学 · 物理学 2020-08-04 Xianghan Xu , Yazhong Wang , Fei-Ting Huang , Kai Du , Elizabeth A. Nowadnick , Sang-Wook Cheong

We investigate the possible stabilization of ferroelectricity in bulk Y2O3-doped hafnia and zirconia. We use density functional theory (DFT) with large random supercells of hafnia and zirconia and study the relative phase stability of the…

材料科学 · 物理学 2025-09-03 Li Yin , Cong Liu , R. E. Cohen

Unique polar properties of nanoscale hafnia-zirconia oxides (Hf$_x$Zr$_{1-x}$O$_2$) are of great interest for condensed matter physics, nanophysics and advanced applications. These properties are connected (at least partially) to the…

材料科学 · 物理学 2025-01-22 Eugene A. Eliseev , Sergei V. Kalinin , Anna N. Morozovska

Ferroelectric HfO2-based materials hold great potential for widespread integration of ferroelectricity into modern electronics due to their robust ferroelectric properties at the nanoscale and compatibility with the existing Si technology.…

Intertwined ionic conduction and ferroelectric (FE) switching in HfO2 lead to extensive focuses. To describe its fundamental phenomena, we present a free-energy model describing the potential of ferroelectrics with successive FE switching…

材料科学 · 物理学 2023-11-06 Guo-Dong Zhao , Xingen Liu , Zhongshan Xu , Wei Ren , Xiaona Zhu , David Wei Zhang , Shaofeng Yu