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One of water's unsolved puzzles is the question of what determines the lowest temperature to which it can be cooled before freezing to ice. The supercooled liquid has been probed experimentally to near the homogeneous nucleation temperature…

软凝聚态物质 · 物理学 2011-12-08 Emily B. Moore , Valeria Molinero

When an ice crystal is born from liquid water two key changes occur: (i) the molecules order; and (ii) the mobility of the molecules drops as they adopt their lattice positions. Most research on ice nucleation (and crystallization in…

化学物理 · 物理学 2019-03-27 Martin Fitzner , Gabriele C. Sosso , Stephen J. Cox , Angelos Michaelides

Water freezing is ubiquitous on Earth, affecting many areas from biology to climate science and aviation technology. Probing the atomic structure in the homogeneous ice nucleation process from scratch is of great value but still…

材料科学 · 物理学 2023-04-27 Mingyi Chen , Lin Tan , Han Wang , Linfeng Zhang , Haiyang Niu

Liquids crystallize as they cool; however, when crystallization is avoided in some way, they supercool, maintaining their liquidity, and freezing into glass at low temperatures, as ubiquitously observed. These metastable states crystallize…

强关联电子 · 物理学 2022-01-14 Hideaki Murase , Shunto Arai , Tatsuo Hasegawa , Kazuya Miyagawa , Kazushi Kanoda

Water is one of the most abundant substances on Earth, and ice, i.e., solid water, has more than 18 known phases. Normally ice in nature exists only as Ice Ih, Ice Ic, or a stacking disordered mixture of both. Although many theoretical…

统计力学 · 物理学 2022-09-19 Maodong Li , Jun Zhang , Niu Haiyang , Yao Kun Lei , Xu Han , Lijiang Yang , Zhiqiang Ye , Yi Isaac Yang , Yi Qin Gao

Nanoparticle surface structural dynamics is believed to play a significant role in regulating functionalities such as diffusion, reactivity, and catalysis but the atomic-level processes are not well understood. Atomic resolution…

Ice nucleation is a process of great relevance in physics, chemistry, technology and environmental sciences, much theoretical and experimental efforts have been devoted to its understanding, but still it remains a topic of intense research.…

软凝聚态物质 · 物理学 2019-06-26 Haiyang Niu , Yi Isaac Yang , Michele Parrinello

We examine ice crystal growth from water vapor at temperatures near the melting point, when surface premelting creates a quasiliquid layer at the solid/vapor interface. Recent ice growth measurements as a function of vapor supersaturation…

材料科学 · 物理学 2014-07-04 Kenneth G. Libbrecht

Phase-contrast transmission electron microscopy (TEM) of hexagonal ice (Ih) along [0001] sometimes shows a honeycomb-like pattern, often interpreted as individual oxygen columns in single crystals. Here, we show that this pattern commonly…

Water has many anomalous properties compared to "simple" liquids, and these anomalies are typically enhanced in supercooled water. While numerous models have been proposed, including the liquid-liquid critical point, the singularity-free…

化学物理 · 物理学 2020-10-28 Loni Kringle , Wyatt A. Thornley , Bruce D. Kay , Greg A. Kimmel

Water (H2O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out,…

天体物理学 · 物理学 2009-11-06 Helen J. Fraser , Mark P. Collings , Martin R. S. McCoustra , David A. Williams

Water exhibits rich polymorphism, where more than 20 crystalline phases have been experimentally reported. Five of them are metastable and form at low temperatures by either heating amorphous ice or degassing clathrate hydrates. However,…

The structure and properties of water or ice are of great interest to researchers due to their importance in the biological, cryopreservation and environmental fields. Hexagonal ice (Ih) is a common ice phase in nature and has been…

Freezing in the vicinity of water-vapor interfaces is of considerable interest to a wide range of disciplines, most notably the atmospheric sciences. In this work, we use molecular dynamics and two advanced sampling techniques, forward flux…

统计力学 · 物理学 2014-11-04 Amir Haji-Akbari , Ryan S. DeFever , Sapna Sarupria , Pablo G. Debenedetti

Transmission electron microscopy has undergone a revolution in recent years with the possibility to perform routine cryo-imaging of biological materials and (bio)chemical systems, as well as the possibility to image liquids via dedicated…

The proneness of water to crystallize is a major obstacle to understanding its putative exotic behavior in the supercooled state. It also represents a strong practical limitation to cryopreservation of biological systems. Adding some…

Ice I has three forms depending on the stacking arrangements of its layers: hexagonal ice Ih, cubic ice Ic, and stacking disordered ice Isd. Below ~60 K, amorphous water becomes metastable, and the formation of any form of ice I is often…

介观与纳米尺度物理 · 物理学 2024-07-11 Reo Sato , So Taniguchi , Naoki Numadate , Tetsuya Hama

The paper discusses the features of supercooled water thin film of width $d=3.97$~nm contained by the perfect graphene layers and crystallizing under external stationary electric field. It was found that the electric field applied…

材料科学 · 物理学 2020-05-22 R. M. Khusnutdinoff , A. V. Mokshin

This monograph reviews our current understanding of the physical dynamics of ice crystal growth, focusing on the spontaneous formation of complex structures from water vapor (called snow crystals) as a function of temperature,…

材料科学 · 物理学 2021-12-10 Kenneth G. Libbrecht

The properties of some forms of water ice reserve still intriguing surprises. Besides the several stable or metastable phases of pure ice, solid mixtures of water with gases are precursors of other ices, since in some cases they may be…

其他凝聚态物理 · 物理学 2016-11-23 Leonardo del Rosso , Milva Celli , Lorenzo Ulivi
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