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There is a long-standing question of whether it is possible to extend the formalism of equilibrium thermodynamics to the case of non-equilibrium systems in steady states. We have made such an extension for an ideal gas in a heat flow…

统计力学 · 物理学 2023-01-31 Robert Hołyst , Karol Makuch , Konrad Giżyński , Anna Maciołek , Paweł J. Żuk

People are well aware that, inherently, certain small-scale nonchaotic particle movements are not governed by thermodynamics. Usually, such phenomena are studied by kinetic theory and their energy properties are considered "trivial". In…

统计力学 · 物理学 2025-08-05 Yu Qiao , Zhaoru Shang

It has long been known that, fundamentally different from a large body of rarefied gas, when a Knudsen gas is immersed in a thermal bath, it may never reach thermal equilibrium. The root cause is nonchaoticity: as the particle-particle…

统计力学 · 物理学 2024-11-15 Yu Qiao , Zhaoru Shang

There is a long-standing question as to whether and to what extent it is possible to describe nonequilibrium systems in stationary states in terms of global thermodynamic functions. The positive answers have been obtained only for…

统计力学 · 物理学 2022-11-30 Robert Hołyst , Karol Makuch , Anna Maciołek , Paweł J. Żuk

Equilibrium thermodynamics is grounded in the law of energy conservation, with a specific focus on how systems exchange energy with their environment during transitions between equilibrium states. These transitions are typically…

统计力学 · 物理学 2024-08-19 Karol Makuch

Equilibrium thermodynamics describes the energy exchange of a body with its environment. Here, we describe the global energy exchange of an ideal gas in the Coutte flow in a thermodynamic-like manner. We derive a fundamental relation…

统计力学 · 物理学 2023-07-31 Karol Makuch , Konrad Giżyński , Robert Hołyst , Anna Maciołek , Paweł J. Żuk

We discovered an out-of-equilibrium transition in the ideal gas between two walls, divided by an inner, adiabatic, movable wall. The system is driven out-of-equilibrium by supplying energy directly into the volume of the gas. At critical…

统计力学 · 物理学 2025-02-06 Yirui Zhang , Marek Litniewski , Karol Makuch , Pawel J. Zuk , Anna Maciolek , Robert Holyst

For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…

统计力学 · 物理学 2010-02-08 Eliran Boksenbojm , Bram Wynants , Christopher Jarzynski

We studied planar compressible flows of ideal gas as models of a non-equilibrium thermodynamic system. We demonstrate that internal energy $U(S^{*},V,N)$ of such systems in stationary and non-stationary states is the function of only three…

统计力学 · 物理学 2024-03-04 Konrad Giżyński , Karol Makuch , Jan Paczesny , Paweł Żuk , Anna Maciołek , Robert Hołyst

The second law of thermodynamics dictates that heat flows spontaneously from a high-temperature entity to a lower-temperature one. Yet, recent advances have demonstrated that quantum correlations between a system and its thermal environment…

Anomalous heat transfer (AHT), a process by which heat spontaneously flows from a cold system into a hot one, superficially contradicts the Clausius statement of the second law of thermodynamics. Here we provide a full classification of…

量子物理 · 物理学 2024-12-31 Teng Ma , Jing-Ning Zhang , Yuan-Sheng Wang , Hong-Yi Xie , Man-Hong Yung

The status of heat and work in nonequilibrium thermodynamics is quite confusing and non-unique at present with conflicting interpretations even after a long history of the first law in terms of exchange heat and work, and is far from…

化学物理 · 物理学 2012-06-05 P. D. Gujrati

We explore the properties of the equilibrium space of van der Waals thermodynamic systems. We use an invariant representation of the fundamental equation by using the law of corresponding states, which allows us to perform a general…

统计力学 · 物理学 2022-04-06 Hernando Quevedo , Maria N. Quevedo , Alberto Sanchez

In this work, we investigate the heat flow of two interacting quantum systems on the perspective of noncommutativity phase-space effects and show that by controlling the new constants introduced in the quantum theory, due to a deformed…

量子物理 · 物理学 2020-12-25 Jonas F. G. Santos

Recent research on the thermodynamic arrow of time, at the microscopic scale, has questioned the universality of its direction. Theoretical studies showed that quantum correlations can be used to revert the natural heat flow (from the hot…

量子物理 · 物理学 2018-06-13 Ivan Henao , Roberto M. Serra

Originally formulated for macroscopic machines, the laws of thermodynamics were recently shown to hold for quantum systems coupled to ideal sources of work (external classical fields) and heat (systems at equilibrium). Ongoing efforts have…

量子物理 · 物理学 2023-06-29 Cyril Elouard , Camille Lombard Latune

The second law of thermodynamics is a fundamental law of Nature. It is almost universally associated with the Clausius inequality that lower bounds a change in entropy by the ratio of supplied heat and temperature. However, this result…

量子气体 · 物理学 2020-05-11 Daniel Mayer , Eric Lutz , Artur Widera

We present a dynamic van der Waals theory. It is useful to study phase separation when the temperature varies in space. We show that if heat flow is applied to liquid suspending a gas droplet at zero gravity, a convective flow occurs such…

软凝聚态物质 · 物理学 2009-11-11 Akira Onuki

An experimentally inspired model is constructed and rigorously solved from the Hamiltonian level where a dc circular spontaneous flow exists in absence of a magnetic field, irrespective of presence of dissipation causing otherwise proper…

等离子体物理 · 物理学 2007-05-23 V. Capek , J. Bok

Isoenergetic thermalization amongst $n$ bodies is a well-known irreversible process, bringing the bodies to a common temperature $T_F$ and leading to a rise in the total entropy of the bodies. We express this change in entropy using the…

统计力学 · 物理学 2024-11-07 Vansh Narang , Renuka Rai , Ramandeep S. Johal
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