相关论文: On the equilibrium limit of liquid stability in pr…
This work extends the Cahn--Larch\'e thermodynamic framework to binary alloys in which two coherent solid phases coexist with an incoherent liquid and investigates how coherency strain energy modifies classical eutectic and peritectic…
We study the hydrodynamic limit for the isothermal dynamics of an anharmonic chain under hyperbolic space-time scaling under varying tension. The temperature is kept constant by a contact with a heat bath, realised via a stochastic…
The thermodynamic stability of the hard-sphere gas has been examined, using the formalism of scaled particle theory [SPT], and by applying explicitly the conditions of stability required by both the second and third laws of thermodynamics.…
Experiments show that isochoric (constant-volume) conditions enhance supercooling stability relative to isobaric (constant-pressure) conditions. Here, combining Helmholtz equilibrium thermodynamics with a first-order perturbation…
A fluid occupying a mechanically isolated vessel with walls kept at spatially non-uniform temperature is in the long run expected to reach the spatially inhomogeneous steady state. Irrespective of the initial conditions the velocity field…
A number of crystal structures of water have been `superheated' in Monte Carlo simulations. Two well known models for water were considered; namely the TIP4P model and the SPC/E model. By comparing the fluid-solid coexistence temperature to…
A concentration-saturated helium mixture at the melting pressure consists of two liquid phases and one or two solid phases. The equilibrium system is univariant, whose properties depend uniquely on temperature. Four coexisting phases can…
We study the hydrodynamic limit for the isothermal dynamics of an anharmonic chain under hyperbolic space-time scaling and with nonvanishing viscosity. The temperature is kept constant by a contact with a heat bath, realised via a…
In this paper the motion of two-phase, incompressible, viscous fluids with surface tension is investigated. Three cases are considered: (1) the case of heat-conducting fluids, (2) the case of isothermal fluids, and (3) the case of Stokes…
The hydrodynamics for a gas of hard-spheres which sometimes experience inelastic collisions resulting in the loss of a fixed, velocity-independent, amount of energy $\Delta $ is investigated with the goal of understanding the coupling…
The stability-limit conjecture (SLC) proposes that the liquid spinodal of water returns to positive pressure in the supercooled region, and that the apparent divergence of water's thermodynamic response functions as temperature decreases…
We present a non-linear elastic model of a coherent transition with discontinuous volume change in an isotropic solid. The model reproduces the anomalous thermodynamics typical of coherent equilibrium including intrinsic hysteresis (for a…
Glass-to-glass and liquid-to-liquid phase transitions were observed many years ago in bulk and confined water with or without applied pressure. It is shown that they result from the competition of two-liquid phases separated by an enthalpy…
We study the existence and properties of the non-equilibrium steady state which arises by putting two copies of systems at different temperatures into a thermal contact. We solve the problem for the relativistic systems that are described…
Pole-skipping offers compelling evidence for the hydrodynamic origin of chaotic behavior in strongly coupled quantum systems. We demonstrate that the cumulative effect of higher-order corrections to the hydrodynamic diffusive mode, captured…
We review the available experimental information on the thermodynamic properties of supercooled ordinary and heavy water and demonstrate the possibility of modeling these thermodynamic properties on a theoretical basis. We show that by…
We consider a chain of particles connected by an-harmonic springs, with a boundary force (tension) acting on the last particle, while the first particle is kept pinned at a point. The particles are in contact with stochastic heat baths,…
A fluid in a pore can form diverse heterogeneous structures. We combine a capillary description with the cubic-plus-association equation of state to study the thermodynamic stability of droplets, bubbles and films of water at 358 K in a…
We provide a very simple proof for the existence of the thermodynamic limit for the quenched specific pressure for classical and quantum disordered systems on a $d$-dimensional lattice, including spin glasses. We develop a method which…
Classical thermodynamics treats temperature as a state variable characterizing systems in equilibrium with idealized infinite reservoirs. We argue that this framing, while computationally exact, obscures an essential physical reality: any…