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Pnictogen-based solar absorbers have gained prominence as promising nontoxic and stable alternatives to lead-halide perovskites (LHPs), but are severely limited by carrier localization, preventing their performance from approaching those of…

Ag(I)-Bi(III)-based semiconductors have gained substantial attention as nontoxic, stable alternatives to lead-halide perovskites for optoelectronics, but are widely limited by carrier localization, which severely restricts diffusion…

Understanding the nature of electrical conductivity, superconductivity and magnetism between layers of oxides is of immense importance for the design of electronic devices employing oxide heterostructures. We demonstrate that resonant…

We report on an element-selective study of the fate of charge carriers in photoexcited inorganic CsPbBr3 and CsPb(ClBr)3 perovskite nanocrystals (NCs) in toluene solutions using time-resolved X-ray absorption spectroscopy with 80 ps time…

Charge carrier mobilities are critical parameters in halide perovskite solar cells, governing their average carrier velocity under an applied electric field and overall efficiency. Recent advances in first-principles calculations of…

材料科学 · 物理学 2025-05-27 Junwen Yin , Olle Hellman , Samuel Poncé

Halide perovskites are known for their rich phase diagram and superior performance in diverse optoelectronics applications. The latter property is often attributed to the long electron-hole recombination time, whose underlying physical…

Antimony Selenide (Sb$_2$Se$_3$) is an attractive candidate of photovoltaics with not yet satisfying efficiency. Beside defects, polaron formation originated from lattice distortion was proposed to account for trapping free carriers, and…

材料科学 · 物理学 2024-10-08 Yijie Shi , Xi Wang , Zhong Wang , Zheng Zhang , Fuyong Hua , Chao Chen , Chunlong Hu , Jiang Tang , Wenxi Liang

Hot-carrier cooling (HCC) in metal halide perovskites in the high-density regime is significantly slower compared to conventional semiconductors. This effect is commonly attributed to a hot-phonon bottleneck but the influence of the lattice…

Layered halide perovskites have emerged as potential alternatives to three-dimensional halide perovskites due to their improved stability and larger material phase space, allowing fine-tuning of structural, electronic, and optical…

Antimony sulfide (Sb2S3) and selenide (Sb2Se3) are emerging earth-abundant absorbers for photovoltaic applications. Solar cell performance depends strongly on charge carrier transport properties but these remain poorly understood in Sb2X3.…

材料科学 · 物理学 2023-02-20 Xinwei Wang , Alex M. Ganose , Seán R. Kavanagh , Aron Walsh

The development of next generation perovskite-based optoelectronic devices relies critically on the understanding of the interaction between charge carriers and the polar lattice in out-of-equilibrium conditions. While it has become…

We present an experimental and theoretical viewpoint on the electronic carrier mobilities of typical hybrid organic-inorganic perovskites (HOIPs). While these mobilities are often quoted as high, a review of them shows that although…

材料科学 · 物理学 2018-07-17 Thomas M. Brenner , David A. Egger , Andrew M. Rappe , Leeor Kronik , Gary Hodes , David Cahen

We analyze the quantum transport properties of MAPbI3 within a tight-binding model. Charge carriers are strongly scattered by the Fr\"ohlich interaction with longitudinal optical phonon modes. This limits their mobilities at room…

All inorganic halide perovskites offer promising optoelectronic properties at low cost, but their structural softness and thermal instability limit applications. Density functional theory using the FP-LAPW method (WIEN2k) was used to study…

材料科学 · 物理学 2026-04-28 Sikander Azam , Asif Zaman , Qaiser Rafiq , Amin Ur Rahman , Saleem Ayaz Khan

Mixed anion halide-chalcogenide materials have attracted considerable attention due to their exceptional optoelectronic properties, making them promising candidates for various applications. Among these, CuBiSeCl_2 has recently been…

材料科学 · 物理学 2025-05-15 Yuzhou Hao , Junwei Che , Xiaoying Wang , Xuejie Li , Turab Lookman , Jun Sun , Xiangdong Ding , Zhibin Gao

The protection of halide perovskites is important for the performance and stability of emergent perovskite-based optoelectronic technologies. In this work, we investigate the potential inorganic protective coating materials ZnO, SrZrO3, and…

材料科学 · 物理学 2022-02-22 Azimatu Fangnon , Marc Dvorak , Ville Havu , Milica Todorovic , Jingrui Li , Patrick Rinke

The family of hybrid organic-inorganic lead-halide perovskites are the subject of intense interest for optoelectronic applications, from light-emitting diodes to photovoltaics to X-ray detectors. Due to the inert nature of most organic…

With the rapid advancement of photovoltaic science, there has been an increasing focus on the development of environment-friendly and structurally advanced perovskite solar cells (PSCs). In this context, this study investigates an…

材料科学 · 物理学 2025-08-20 Md. Meraz Hasan , Pallab Chakraborty , Fahim Tanvir , Subah Tahsin , Mostafizur Rahaman

The use of stibnite (Sb2S3) as sensitizers in the solid-state sensitized solar cells received considerable research interest during the transition of the millennium. However, the use of perovskite diminished the research in the field and…

应用物理 · 物理学 2021-05-25 Sumanshu Agarwal , Harekrishna Yadav , Kundan Kumar

As the race towards higher efficiency for inorganic/organic hybrid perovskite solar cells (PSCs) is becoming highly competitive, a design scheme to maximize carrier transport towards higher power efficiency has been urgently demanded. Here,…

材料科学 · 物理学 2018-01-30 Chang Woo Myung , Jeonghun Yun , Geunsik Lee , Kwang S. Kim
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