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Singlet fission (SF) is a photophysical process where a singlet excitation generates two triplet excited states, enhancing exciton multiplication potentially useful for solar energy conversion. Since SF typically outcompetes radiative…

化学物理 · 物理学 2025-12-24 Sumanta Paul , Oleksandr Yampolskyy , Zehua Wu , Klaus Müllen , Thomas Basché

Singlet fission (SF), the spontaneous down-conversion of a singlet exciton into two triplet excitons residing on neighboring molecules, is a promising route to improving organic photovoltaic (OPV) device efficiencies by harvesting two…

材料科学 · 物理学 2018-05-23 Xiaopeng Wang , Xingyu Liu , Cameron Cook , Bohdan Schatschneider , Noa Marom

Singlet fission is a spin-allowed exciton multiplication process in organic semiconductors that converts one spin-singlet exciton to two triplet excitons. It offers the potential to enhance solar energy conversion by circumventing the…

Singlet fission (SF) can potentially break the Shockley-Queisser efficiency limit in single-junction solar cells by splitting one photo-excited singlet exciton (S1) into two triplets (2T1) in organic semiconductors. A dark multi-exciton…

化学物理 · 物理学 2015-12-08 Rui Wang , Chunfeng Zhang , Bo Zhang , Yunlong Liu , Xiaoyong Wang , Min Xiao

Singlet exciton fission (SF), the conversion of one spin-singlet exciton (S1) into two spin-triplet excitons (T1), could provide a means to overcome the Shockley-Queisser limit in photovoltaics. SF as measured by the decay of S1 has been…

Singlet fission is a process whereby two triplet excitons can be produced from one photon, potentially increasing the efficiency of photovoltaic devices. Endothermic singlet fission is desired for maximum energy conversion efficiency, and…

Singlet Fission (SF) into two triplets offers exciting avenues for high-efficiency photovoltaics and optically initializable qubits. While the chemical space of SF chromophores is ever-expanding, the mechanistic details of…

Singlet fission (SF) is an electronic transition that in the last decade has been under the spotlight for its applications in optoelectronics, from photovoltaics to spintronics. Despite considerable experimental and theoretical…

量子物理 · 物理学 2024-11-12 Francesco Campaioli , Alice Pagano , Daniel Jaschke , Simone Montangero

Endothermic singlet fission (SF), an exciton multiplication process that produces a pair of high-energy triplet excitons (T1T1), is appealing for photovoltaic or photoelectrochemical applications, as it allows the conversion of entropy into…

Singlet fission is a form of multiple exciton generation which occurs in organic chromophores when a high energy singlet exciton separates into two lower energy triplet excitons, each with approximately half the singlet energy. Since this…

Singlet fission (SF) process, where a singlet exciton decays into a pair of spin one exciton states which are in the total spin singlet state, is one of the possible channels for multiple exciton generation (MEG). In chiral single-wall…

介观与纳米尺度物理 · 物理学 2017-08-02 Andrei Kryjevski , Deyan Mihaylov , Brendan Gifford , Dmitri Kilin

Singlet exciton fission (SEF) is initiated by ultrafast internal conversion of a singlet exciton into a correlated triplet pair (TT)1. The `reaction coordinates' for ultrafast SEF even in archetypal systems such as pentacene thin film…

化学物理 · 物理学 2023-05-29 Atandrita Bhattacharyya , Amitav Sahu , Sanjoy Patra , Vivek Tiwari

Singlet fission (SF), an exciton multiplication process occurring in organic semiconductors, offers a way to break the Shockley-Queisser limit in single-bandgap photovoltaics (PV). If the triplet excitons generated by SF can be transferred…

A theory of singlet fission (SF) in carotenoid dimers is applied to explain the SF in lycopene H-aggregates observed after high energy photoexcitation. The explanation proposed here is that a high energy, delocalized bright $^1B_u^+$ state…

化学物理 · 物理学 2023-08-31 William Barford

Singlet exciton fission has the potential to increase the efficiency of crystalline silicon solar cells beyond the conventional single junction limit. Perhaps the largest obstacle to achieving this enhancement is uncertainty about energy…

Singlet fission may boost photovoltaic efficiency [by transforming a singlet exciton into two triplet excitons and thereby doubling the number of excited charge carriers. The primary step of singlet fission is the ultrafast creation of the…

Singlet fission, an exciton multiplication process in organic semiconductors which converts one singlet exciton into two triplet excitons is a promising way to reduce thermalization losses in conventional solar cells. One way to harvest…

应用物理 · 物理学 2018-10-09 Moritz H. Futscher , Akshay Rao , Bruno Ehrler

One way for solar cell efficiencies to overcome the Shockley-Queisser limit is downconversion of high-energy photons using singlet fission (SF) in polyacenes like tetracene (Tc). SF enables generation of multiple excitons from the…

应用物理 · 物理学 2018-01-31 S. W. Tabernig , B. Daiber , T. Wang , B. Ehrler

Singlet fission is a photoconversion process that generates a doubly excited, maximally spin entangled pair state. This state has applications to quantum information and computing that are only beginning to be realized. In this article, we…

化学物理 · 物理学 2020-11-11 Kori Smyser , Joel Eaves

Singlet fission (SF) is a potential pathway for significant enhancement of efficiency in organic solar cells (OSC). In this paper, we study singlet fission in a pair of polyene molecules in two different stacking arrangements employing…

化学物理 · 物理学 2017-08-23 Suryoday Prodhan , S. Ramasesha
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