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Hydrogen embrittlement remains a critical challenge in structural and electronic applications of copper (Cu) but its mechanism is still not fully understood. In this study, we combine density functional theory (DFT) and bond-order potential…

材料科学 · 物理学 2026-03-17 Vasileios Fotopoulos , Alexander L. Shluger

Metallic dopants have the potential to increase the mechanical strength of polycrystalline metals. These elements are expected to aggregate in regions of lower coordination, such as grain boundaries. At the grain boundaries, they can have a…

材料科学 · 物理学 2024-07-18 Vasileios Fotopoulos , Jack Strand , Manuel Petersmann , Alexander L. Shluger

Hydrogen atoms absorbed by metals in the hydrogen-containing environments can lead to the premature fracture of the metal components used in load-bearing conditions. Since metals used in practice are mostly polycrystalline, grain boundaries…

The mechanical properties of Cu-Ti alloys have been characterized extensively through experimental studies. However, a detailed understanding of why the strength of Cu increases after a small fraction of Ti atoms is added to the alloy is…

材料科学 · 物理学 2024-07-15 Vasileios Fotopoulos , Corey S. O'Hern , Mark D. Shattuck , Alexander L. Shluger

Hydrogen embrittlement (HE) poses a significant challenge in the mechanical integrity of iron and its alloys. This study explores the influence of hydrogen atoms on two distinct grain boundaries (GBs), $\Sigma37$ and $\Sigma3$, in…

材料科学 · 物理学 2024-07-04 Aynour Khosravi , Jun Song , Normand Mousseau

Grain boundary (GB) segregation of solute atoms plays an important role in the microstructure and macroscopic mechanical properties of materials. The study of GB segregation of solute atoms using computational simulation has become one of…

材料科学 · 物理学 2023-05-29 Zhihui Zhang , Liang Zhang , Xuan Zhang , Xiaoxu Huang

Atomistic calculations were carried out to investigate the mechanical properties of Pd crystals as a combined function of structural defects, hydrogen concentration and high temperature. These factors are found to individually induce…

材料科学 · 物理学 2015-05-29 Hieu H. Pham , A. Amine Benzerga , Tahir Cagin

Light elements play an important role in influencing the macroscale properties of engineering alloys through grain boundary (GB) segregation phenomena. However, the scarcity and scattered nature of ab initio datasets for light elements in…

材料科学 · 物理学 2026-05-05 Han Lin Mai , Xiang-Yuan Cui , Tilmann Hickel , Simon P. Ringer , Jörg Neugebauer

Revealing statistics of H-defect interactions provides insights into significant ductility loss due to the particular strain partitioning in H-charged structural alloys. Experimental investigation of these interactions is extremely…

材料科学 · 物理学 2025-01-22 Matthew J. Melfi , S. Mohadeseh Taheri-Mousavi

The effect of interstitial hydrogen on the elastic properties of $\alpha$-iron is investigated using \textit{ab initio} density functional theory. We find that while the overall strength properties are reduced by H, the effects are mainly…

材料科学 · 物理学 2012-09-14 D. Psiachos , T. Hammerschmidt , R. Drautz

When metal surfaces are exposed to hydrogen ion irradiation, the light ions are expected to penetrate deep into the material and dissolve in the matrix. However, these atoms are seen to cause significant modification of surfaces, indicating…

First-principles calculations were carried out to study the segregation behavior of Mg, and Cu and their effect on the energy and mechanical properties of different Al grain boundaries (GBs). Four symmetrical tilt GBs were selected for…

材料科学 · 物理学 2023-05-29 Xuan Zhang , Liang Zhang , Zhihui Zhang , Xiaoxu Huang

Zn induced liquid metal embrittlement (LME) is a major concern in particular for advanced high strength steels, which often contain a significant amount of austenite compared to established steel grades. Using density functional theory…

材料科学 · 物理学 2024-01-12 Ujjal Saikia , Mira Todorova , Tilmann Hickel

Hydrogen-enhanced decohesion (HEDE) is one of the many mechanisms of hydrogen embrittlement, a phenomenon that severely impacts structural materials such as iron and iron alloys. Grain boundaries (GBs) play a critical role in this…

材料科学 · 物理学 2024-07-03 Abril Azócar Guzmán , Rebecca Janisch

Molecular dynamics simulations using empirical force fields (EFFs) are crucial for gaining fundamental insights into atomic structure and long timescale dynamics of Au nanoclusters with far-reaching applications in energy and devices. This…

Segregation of alloying elements and impurities at grain boundaries (GBs) critically influences material behavior by affecting cohesion. In this study, we present an ab initio high-throughput evaluation of segregation energies and cohesive…

材料科学 · 物理学 2025-03-19 Han Lin Mai , Xiang-Yuan Cui , Tilmann Hickel , Jörg Neugebauer , Simon Ringer

Solute segregation at grain boundaries (GBs) of polycrystals strongly impacts the mechanical properties of metals including strength, fracture, embrittlement, and corrosion. However, the complexity of GB structures and the large chemical…

材料科学 · 物理学 2024-12-24 Hao Wu , Xin Li , Wang Gao , Qing Jiang

It was recently reported that segregation of Zr to grain boundaries (GB) in nanocrystalline Cu can lead to the formation of disordered intergranular films [1,2]. In this study we employ atomistic computer simulations to study how the…

材料科学 · 物理学 2018-02-23 Valery Borovikov , Mikhail I. Mendelev , Alexander H. King

Hybrid Monte Carlo (MC)/molecular dynamics (MD) simulations are conducted to study the microstructures of nanocrystalline (nc) Cu/Ag alloys with various Ag concentrations. When the Ag concentration is below 50 Ag atoms/nm!, an increase in…

材料科学 · 物理学 2017-04-05 A. Li , I. Szlufarska

The core structure of dislocations is critical to their mobility, cross slip, and other plastic behaviors. Atomistic simulation of the core structure is limited by the size of first-principles density functional theory (DFT) calculation and…

材料科学 · 物理学 2022-09-13 Fenglin Deng , Hongyu Wu , Ri He , Peijun Yang , Zhicheng Zhong
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